☣️ UN 3333 • CLASS 7

UN 3333 — Radioactive material, Type A package, special form, fissile

Placard: Radioactive. ERG Guide 165. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3333 is Radioactive material, Type A package, special form, fissile, a fissile radioactive package assigned to ERG Guide 165. Undamaged packages are engineered for containment; damaged packages require radiation authority control.

Hazard overview: RADIOACTIVE fissile package; undamaged packages are designed to maintain shielding, containment and criticality safety. Damaged packages may increase external radiation exposure and create contamination-control concerns. Fissile contents require radiation authority guidance because package geometry, moderation and shielding matter.

Response guidance: For UN 3333, protect life safety first, isolate damaged packages and notify radiation authority. Limit handling, control runoff/debris and use monitoring with ERG 165.

Firefighter training notes: Training for UN 3333 should emphasize package recognition, radiation authority notification, dosimetry/survey use, contamination control, time-distance-shielding and life-safety priority. Use ERG 165 and radiation SOP.

Regulatory context: Radioactive material, Type A package, special form, fissile is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, package type, formulation and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Radioactive material, Type A package, special form, fissile should remain in approved radioactive material packages protected from damage, fire, unauthorized access and contamination spread. Follow radiation authority, carrier and package-certificate requirements.

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UN 3333 Quick Details

UN 3333
Product name: Radioactive material, Type A package, special form, fissile
DOT Class: 7
Placard type: Radioactive
ERG Guide: 165 (check current ERG)
Initial isolation: ERG 165: isolate spill 25m all directions; if package damaged/leaking, isolate 25m and secure area; evacuate immediate area if criticality alarm sounds; no large-scale evacuation needed for intact Type A packages

Common Hazards of UN 3333

  • RADIOACTIVE fissile package; undamaged packages are designed to maintain shielding, containment and criticality safety.
  • Damaged packages may increase external radiation exposure and create contamination-control concerns.
  • Fissile contents require radiation authority guidance because package geometry, moderation and shielding matter.
  • Transport index and package labels may not fully describe radiation level at every point after damage.
  • Some radioactive contents may not be detected by common instruments without proper survey equipment.
  • Fire may damage packaging and create contaminated debris or runoff-control issues.
  • Life safety, rescue and fire control remain priorities while limiting time, maximizing distance and using shielding.

Chemical Identity & Physical Properties

Sealed metal or composite container containing fissile radioactive material in special form (non-dispersible solid capsule). Material varies by isotope; package itself is typically metallic with radiation trefoil markings.

Also known asFissile radioactive material Type AType A fissile package special formRAM Type A fissileRadioactive Type A-F package
AppearanceSealed metal or composite container containing fissile radioactive material in special form (non-dispersible solid capsule). Material varies by isotope; package itself is typically metallic with radiation trefoil markings.
Flash PointNot applicable (non-combustible radioactive package)
Boiling PointNot applicable (sealed radioactive material)
Vapor DensityNot applicable (solid material in sealed container)
Water ReactivityNo significant reaction with water for intact package; damaged packages may expose radioactive material requiring contamination control
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3333

Extinguishing Media

Use agents appropriate for the packaging or surrounding fire. Control runoff/debris as potentially contaminated until surveyed by radiation authority.

PPE Requirements

⚠️ Radiation monitoring required; full turnout gear with SCBA for fire; dosimetry badges mandatory; minimize time near packages, maximize distance, use shielding; Level C minimum for damaged packages

Use PPE for the dominant hazard plus dosimetry and radiation monitoring. For fire, use SCBA and turnout gear; minimize time, maximize distance and use shielding.

Isolation & Evacuation

ERG 165: isolate spill 25m all directions; if package damaged/leaking, isolate 25m and secure area; evacuate immediate area if criticality alarm sounds; no large-scale evacuation needed for intact Type A packages
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 165).

First Actions for a UN 3333 Incident

  • Call 911 and notify the radiation authority according to local procedures.
  • Protect life safety first while minimizing time near damaged packages.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream of smoke, runoff or damaged contents.
  • Do not handle damaged packages or loose contents without proper training and radiation monitoring.
  • Detain potentially contaminated people or equipment for assessment without delaying urgent medical care.
  • Use ERG Guide 165, package labels, shipping papers and radiation monitoring to guide isolation, evacuation and cleanup.
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📋 Copy & Share Field Card

UN 3333 — Radioactive material, Type A package, sp
HAZMAT RADIO NOTE — UN 3333 Product: Radioactive material, Type A package, special form, fissile Class 7 / Radioactive / ERG 165 PPE: Radiation monitoring required; full turnout gear with SCBA for fire; dosimetry badges mandatory; minimize time near packages, maximize distance, use shielding; Level C minimum for damaged packages ISOLATION: ERG 165: isolate spill 25m all directions; if package damaged/leaking, isolate 25m and secure area; evacuate immediate area if criticality alarm sounds; no large-scale evacuation needed for intact Type A packages ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3333 — Radioactive material, Type A package, special form, fissile Class: 7 | Placard: Radioactive | ERG Guide: 165 Appearance: Sealed metal or composite container containing fissile radioactive material in special form (non-dispersible solid capsule). Material varies by isotope; package itself is typically metallic with radiation trefoil markings. Water Reactivity: No significant reaction with water for intact package; damaged packages may expose radioactive material requiring contamination control Extinguishing: Use agents appropriate for the packaging or surrounding fire. Control runoff/debris as potentially contaminated until surveyed by radiation authority. PPE: Radiation monitoring required; full turnout gear with SCBA for fire; dosimetry badges mandatory; minimize time near packages, maximize distance, use shielding; Level C minimum for damaged packages Isolation: ERG 165: isolate spill 25m all directions; if package damaged/leaking, isolate 25m and secure area; evacuate immediate area if criticality alarm sounds; no large-scale evacuation needed for intact Type A packages — Key Hazards — • RADIOACTIVE fissile package; undamaged packages are designed to maintain shielding, containment and criticality safety. • Damaged packages may increase external radiation exposure and create contamination-control concerns. • Fissile contents require radiation authority guidance because package geometry, moderation and shielding matter. — First Actions — • Call 911 and notify the radiation authority according to local procedures. • Protect life safety first while minimizing time near damaged packages. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream of smoke, runoff or damaged contents. SOURCE: allfirefighter.com/hazmat/un/radioactive-material-type-a-un-3333 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3333 Radioactive material, Type A package, special form, fissile Cls7 ERG165 | allfirefighter.com/hazmat/un/radioactive-material-type-a-un-3333SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/radioactive-material-type-a-un-3333

Related UN Numbers in Class 7

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3333

UN 3333 is Radioactive material, Type A package, special form, fissile, assigned to ERG Guide 165.

The radioactive contents are not treated as the fuel; packaging or surrounding materials may burn in a fire.

RADIOACTIVE fissile package; undamaged packages are designed to maintain shielding, containment and criticality safety. Damaged packages may increase external radiation exposure and create contamination-control concerns. Fissile contents require radiation authority guidance because package geometry, moderation and shielding matter.

Use PPE for the dominant hazard plus dosimetry and radiation monitoring. For fire, use SCBA and turnout gear; minimize time, maximize distance and use shielding.

Use agents appropriate for the packaging or surrounding fire. Control runoff/debris as potentially contaminated until surveyed by radiation authority.

Keep life safety first, avoid unnecessary handling, survey damaged packages and prevent contamination spread.

Notify the radiation authority or radiation safety officer according to local procedures and shipping paper information.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.