☣️ DOT HAZMAT CLASS 5

Oxidizers & Organic Peroxides

Can intensify fire and accelerate burning—cooling and isolation often critical.

🧯☣️
⚠️ Training/quick-reference only. For real incidents, follow your SOP/SOG and the current ERG.
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Common hazards (high level)
  • Intensifies combustion and fire spread
  • Reactivity under heat/contamination
  • Potential for oxygen release / decomposition
How to recognize
  • Placards indicating Oxidizer/Peroxide
  • Unusually intense burning behavior
  • Facility storage areas (pool supply, industrial)
First actions (before Hazmat team)
  • Isolate and keep combustibles away
  • Cool exposures as directed and safe
  • Request Hazmat early
  • Consult ERG for protective actions
  • Avoid contamination/mixing of products
What NOT to do
  • Do not mix chemicals or runoff
  • Do not store combustibles near oxidizers
  • Do not treat as ordinary Class A fire
Common examples
Hydrogen peroxide solutionsPool chemicals (varies)Certain fertilizers (varies)
Popular UN numbers in this class
More UN numbers are discoverable via the Hub lookup. Always consult current ERG + SOP/SOG.
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FAQ

They can supply oxygen or promote rapid oxidation, increasing heat release and spread.

Yes—many are oxidizers and can react dangerously when wet/contaminated; product specifics matter.

Isolation, cooling exposures if appropriate, Hazmat request, and ERG/SOP guidance.
Sources (high level): DOT/PHMSA class & marking concepts, NFPA 704 overview concepts, and ERG usage principles. This guide does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.