☣️ UN 1446 • CLASS 5

Barium nitrate

Placard: Oxidizer. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1446
Class: 5
Placard type: Oxidizer
ERG: Guide 141 (check current ERG)
Verify shipping papers and exact product details; use ERG Guide 141 for initial actions and isolation/evacuation guidance.
Chemical & Response Details
Also known asNitric acid, barium saltBarium dinitrateNitrobariteBarium(II) nitrate
CAS Number10022-31-8
AppearanceWhite to transparent crystalline solid or powder, odorless. Soluble in water.
Flash PointNot applicable (oxidizer, non-combustible solid)
Boiling PointDecomposes at 592C (1098F)
Vapor DensityNot applicable (solid)
Water ReactivityDissolves in water, no violent reaction. Solution is toxic.
ExtinguishingWater spray, dry chemical, CO2. Avoid organic materials that could be oxidized.
PPE⚠️ Level B minimum; SCBA and chemical protective clothing; avoid dust inhalation
IsolationERG 141: isolate spill 25-50m; for large spill isolate 100m all directions; evacuate immediate area if fire
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
  • These substances will accelerate burning when involved in a fire.
  • May explode from heat or contamination.
  • Some may burn rapidly.
  • Some will react explosively with hydrocarbons (fuels).
  • May ignite combustibles (wood, paper, oil, clothing, etc.).
  • Containers may explode when heated.
  • Runoff may create fire or explosion hazard.
  • Toxic by ingestion.
First actions (field-minded)
  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
  • Consider initial downwind evacuation for at least 100 meters (330 feet).
Related UN numbers (same class)
This is a discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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MAYDAY / HAZMAT QUICK NOTE
UN 1446 — Barium nitrate
Class: 5 | Placard: Oxidizer
ERG: Guide 141 (check current ERG)
FIRST ACTIONS: use SOP/SOG + ERG; stage upwind; isolate; deny entry; request Hazmat.
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FAQ

These substances will accelerate burning when involved in a fire. May explode from heat or contamination. Some may burn rapidly. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. Toxic by ingestion.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum; SCBA and chemical protective clothing; avoid dust inhalation

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 141 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.