☣️ UN 3332 • CLASS 7

UN 3332 — Radioactive material, Type A package, special form, non fissile or fissile-excepted

Placard: Radioactive. ERG Guide 164. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3332 is Radioactive material, Type A package, special form, non fissile or fissile-excepted, a Type A special form radioactive package assigned to ERG Guide 164. Package damage and radiation survey drive response.

Hazard overview: RADIOACTIVE Type A special form package; undamaged packages normally present low risk to responders and the public. Special form material is usually sealed or non-dispersible, but damaged packages can increase external radiation exposure. Contamination and internal uptake are less likely than for dispersible contents, but package damage must be surveyed.

Response guidance: For UN 3332, protect life safety first, isolate damaged packages and notify radiation authority. Limit handling, control runoff/debris and use monitoring with ERG 164.

Firefighter training notes: Training for UN 3332 should emphasize package recognition, radiation authority notification, dosimetry/survey use, contamination control, time-distance-shielding and life-safety priority. Use ERG 164 and radiation SOP.

Regulatory context: Radioactive material, Type A package, special form, non fissile or fissile-excepted is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, package type, formulation and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Radioactive material, Type A package, special form, non fissile or fissile-excepted should remain in approved radioactive material packages protected from damage, fire, unauthorized access and contamination spread. Follow radiation authority, carrier and package-certificate requirements.

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UN 3332 Quick Details

UN 3332
Product name: Radioactive material, Type A package, special form, non fissile or fissile-excepted
DOT Class: 7
Placard type: Radioactive
ERG Guide: 164 (check current ERG)
Initial isolation: ERG 164: isolate damaged packages 25m all directions; if contents released, follow ERG guidance for radioactive material exposure zones

Common Hazards of UN 3332

  • RADIOACTIVE Type A special form package; undamaged packages normally present low risk to responders and the public.
  • Special form material is usually sealed or non-dispersible, but damaged packages can increase external radiation exposure.
  • Contamination and internal uptake are less likely than for dispersible contents, but package damage must be surveyed.
  • Radiation levels may vary with label category and package orientation after an incident.
  • Fire may damage packaging and create smoke, debris or runoff requiring radiation authority review.
  • Do not delay lifesaving actions solely because of the radioactive label.
  • Final cleanup should follow radiation authority instructions.

Chemical Identity & Physical Properties

Sealed package containing radioactive material in special form (non-dispersible solid or sealed capsule). Package integrity prevents release under normal transport conditions.

Also known asType A special form radioactive packageNon-fissile radioactive material Type AFissile-excepted Type A packageRAM Type A special form
AppearanceSealed package containing radioactive material in special form (non-dispersible solid or sealed capsule). Package integrity prevents release under normal transport conditions.
Flash PointNot applicable (radioactive material)
Boiling PointNot applicable (sealed package)
Vapor DensityNot applicable (sealed package)
Water ReactivityNo significant reaction (sealed package)
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3332

Extinguishing Media

Use agents appropriate for the packaging or surrounding fire. Control runoff/debris as potentially contaminated until surveyed by radiation authority.

PPE Requirements

⚠️ Standard PPE for intact packages; if damaged: dosimetry required, minimize exposure time and distance, increase shielding as available

Use PPE for the dominant hazard plus dosimetry and radiation monitoring. For fire, use SCBA and turnout gear; minimize time, maximize distance and use shielding.

Isolation & Evacuation

ERG 164: isolate damaged packages 25m all directions; if contents released, follow ERG guidance for radioactive material exposure zones
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 164).

First Actions for a UN 3332 Incident

  • Call 911 and notify the radiation authority according to local procedures.
  • Protect life safety first while minimizing time near damaged packages.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream of smoke, runoff or damaged contents.
  • Do not handle damaged packages or loose contents without proper training and radiation monitoring.
  • Detain potentially contaminated people or equipment for assessment without delaying urgent medical care.
  • Use ERG Guide 164, package labels, shipping papers and radiation monitoring to guide isolation, evacuation and cleanup.
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📋 Copy & Share Field Card

UN 3332 — Radioactive material, Type A package, sp
HAZMAT RADIO NOTE — UN 3332 Product: Radioactive material, Type A package, special form, non fissile or fissile-excepted Class 7 / Radioactive / ERG 164 PPE: Standard PPE for intact packages; if damaged: dosimetry required, minimize exposure time and distance, increase shielding as available ISOLATION: ERG 164: isolate damaged packages 25m all directions; if contents released, follow ERG guidance for radioactive material exposure zones ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3332 — Radioactive material, Type A package, special form, non fissile or fissile-excepted Class: 7 | Placard: Radioactive | ERG Guide: 164 Appearance: Sealed package containing radioactive material in special form (non-dispersible solid or sealed capsule). Package integrity prevents release under normal transport conditions. Water Reactivity: No significant reaction (sealed package) Extinguishing: Use agents appropriate for the packaging or surrounding fire. Control runoff/debris as potentially contaminated until surveyed by radiation authority. PPE: Standard PPE for intact packages; if damaged: dosimetry required, minimize exposure time and distance, increase shielding as available Isolation: ERG 164: isolate damaged packages 25m all directions; if contents released, follow ERG guidance for radioactive material exposure zones — Key Hazards — • RADIOACTIVE Type A special form package; undamaged packages normally present low risk to responders and the public. • Special form material is usually sealed or non-dispersible, but damaged packages can increase external radiation exposure. • Contamination and internal uptake are less likely than for dispersible contents, but package damage must be surveyed. — First Actions — • Call 911 and notify the radiation authority according to local procedures. • Protect life safety first while minimizing time near damaged packages. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream of smoke, runoff or damaged contents. SOURCE: allfirefighter.com/hazmat/un/radioactive-material-type-a-un-3332 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3332 Radioactive material, Type A package, special form, non fissile or fissile-excepted Cls7 ERG164 | allfirefighter.com/hazmat/un/radioactive-material-type-a-un-3332SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/radioactive-material-type-a-un-3332

Related UN Numbers in Class 7

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3332

UN 3332 is Radioactive material, Type A package, special form, non fissile or fissile-excepted, assigned to ERG Guide 164.

The radioactive contents are not treated as the fuel; packaging or surrounding materials may burn in a fire.

RADIOACTIVE Type A special form package; undamaged packages normally present low risk to responders and the public. Special form material is usually sealed or non-dispersible, but damaged packages can increase external radiation exposure. Contamination and internal uptake are less likely than for dispersible contents, but package damage must be surveyed.

Use PPE for the dominant hazard plus dosimetry and radiation monitoring. For fire, use SCBA and turnout gear; minimize time, maximize distance and use shielding.

Use agents appropriate for the packaging or surrounding fire. Control runoff/debris as potentially contaminated until surveyed by radiation authority.

Keep life safety first, avoid unnecessary handling, survey damaged packages and prevent contamination spread.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.