☣️ UN 1625 • CLASS 6

UN 1625 — Mercuric nitrate

Placard: Toxic. ERG Guide 141. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1625 is Mercuric nitrate, a toxic mercury nitrate oxidizer assigned to ERG Guide 141. It can intensify fire and create toxic mercury-contaminated dust, smoke or runoff.

Hazard overview: UN 1625 presents oxidizer, mercury toxicity and contamination hazards. Keep fuels, organics and reducing agents away, control dust and contain runoff as toxic oxidizer waste.

Response guidance: For a UN 1625 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 141. Establish incident command, isolate the area, stay upwind, prevent dust or vapor exposure, control runoff and choose entry or cleanup actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1625 should emphasize oxidizer fire acceleration, mercury contamination, dust control, incompatible fuels/organics, runoff containment and decontamination. Use ERG 141, SDS and local SOP.

Regulatory context: Mercuric nitrate is regulated as a toxic mercury hazardous material. Transportation, occupational exposure, spill reporting, waste handling, storage and environmental controls may vary by compound, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Mercuric nitrate should be stored in compatible oxidizer/toxic storage away from fuels, organic materials, reducing agents, heat and contamination. Keep containers closed, dry and clearly labeled, and plan for mercury-contaminated runoff or waste.

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UN 1625 Quick Details

UN 1625
Product name: Mercuric nitrate
DOT Class: 6
Placard type: Toxic
ERG Guide: 141 (check current ERG)
Initial isolation: ERG 141: Isolate spill area at least 25m in all directions. For large spills isolate 50m. Evacuate immediate area if fire involves this material.

Common Hazards of UN 1625

  • TOXIC mercury oxidizer; may intensify fire and accelerate burning of combustible materials.
  • May react dangerously with fuels, organic materials, reducing agents or contamination.
  • Heating or confinement may cause decomposition and pressure buildup.
  • Fire may produce toxic mercury fumes, nitrogen oxides and irritating gases.
  • Runoff may spread toxic mercury contamination and oxidizing material.
  • Containers may rupture or explode when heated.
  • Dust or solution contact may injure eyes, skin and respiratory tissue.

Chemical Identity & Physical Properties

White to colorless crystalline solid or powder. Odorless. Hygroscopic and may appear moist. Highly toxic oxidizing agent.

Also known asMercury(II) nitrateMercury dinitrateMercuric nitrate monohydrateNitric acid mercury(II) salt
CAS Number10045-94-0
AppearanceWhite to colorless crystalline solid or powder. Odorless. Hygroscopic and may appear moist. Highly toxic oxidizing agent.
Flash PointNot applicable (non-combustible oxidizing solid)
Boiling PointDecomposes at approximately 79C (174F) before boiling
Vapor DensityNot applicable (solid)
Water ReactivitySoluble in water forming acidic solution. No violent reaction but releases heat.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1625

Extinguishing Media

Use water spray or flooding water from a protected position when ERG, SDS and incident command confirm it is appropriate for oxidizer fire control. Avoid fuels, organics or contaminated absorbents, and contain runoff as mercury-contaminated oxidizer waste.

PPE Requirements

⚠️ Level B minimum with SCBA. Full face respirator with mercury vapor cartridges. Neoprene or butyl rubber gloves. Prevent skin contact due to extreme toxicity.

Use positive-pressure SCBA for fire, dust, decomposition or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid mercury-contaminated dust, solution and runoff.

Isolation & Evacuation

ERG 141: Isolate spill area at least 25m in all directions. For large spills isolate 50m. Evacuate immediate area if fire involves this material.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 141).

First Actions for a UN 1625 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact.
  • Keep fuels, organics, reducing agents and contaminated absorbents away from the material.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Avoid creating dust clouds or spreading contaminated powder, solution, runoff or debris.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if dust, vapor, fire involvement or unknown concentration is present.
  • Use ERG Guide 141, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1625 — Mercuric nitrate
HAZMAT RADIO NOTE — UN 1625 Product: Mercuric nitrate Class 6 / Toxic / ERG 141 PPE: Level B minimum with SCBA. Full face respirator with mercury vapor cartridges. Neoprene or butyl rubber gloves. Prevent skin contact due to extreme toxicity. ISOLATION: ERG 141: Isolate spill area at least 25m in all directions. For large spills isolate 50m. Evacuate immediate area if fire involves this material. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1625 — Mercuric nitrate Class: 6 | Placard: Toxic | ERG Guide: 141 Appearance: White to colorless crystalline solid or powder. Odorless. Hygroscopic and may appear moist. Highly toxic oxidizing agent. Water Reactivity: Soluble in water forming acidic solution. No violent reaction but releases heat. Extinguishing: Use water spray or flooding water from a protected position when ERG, SDS and incident command confirm it is appropriate for oxidizer fire control. Avoid fuels, organics or contaminated absorbents, and contain runoff as mercury-contaminated oxidizer waste. PPE: Level B minimum with SCBA. Full face respirator with mercury vapor cartridges. Neoprene or butyl rubber gloves. Prevent skin contact due to extreme toxicity. Isolation: ERG 141: Isolate spill area at least 25m in all directions. For large spills isolate 50m. Evacuate immediate area if fire involves this material. — Key Hazards — • TOXIC mercury oxidizer; may intensify fire and accelerate burning of combustible materials. • May react dangerously with fuels, organic materials, reducing agents or contamination. • Heating or confinement may cause decomposition and pressure buildup. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/mercuric-nitrate-un-1625 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1625 Mercuric nitrate Cls6 ERG141 | allfirefighter.com/hazmat/un/mercuric-nitrate-un-1625SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/mercuric-nitrate-un-1625

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1625

UN 1625 is Mercuric nitrate, a hazardous material assigned to ERG Guide 141.

No. It is not a fuel, but it can accelerate burning of other materials as an oxidizer.

ERG Guide 141 applies to UN 1625 for initial isolation, protective actions and first response guidance.

UN 1625 presents oxidizer, mercury toxicity and contamination hazards. Keep fuels, organics and reducing agents away, control dust and contain runoff as toxic oxidizer waste.

Use positive-pressure SCBA for fire, dust, decomposition or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS; avoid mercury-contaminated dust, solution and runoff.

Fuels, organics or reducing agents can react with nitrate oxidizers, while mercury contamination can spread through dust, smoke and runoff.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.