☣️ UN 1541 • CLASS 6

UN 1541 — Acetone cyanohydrin, stabilized

Placard: Toxic. ERG Guide 156. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1541 is Acetone cyanohydrin, stabilized, a highly toxic cyanohydrin liquid assigned to ERG Guide 156. Water, heat, alkaline contamination or loss of stabilizer can release hydrogen cyanide, making vapor monitoring and exposure control critical.

Hazard overview: UN 1541 presents hydrogen cyanide release, toxic vapor, combustible liquid and contaminated-runoff hazards. Vapors can collect in low areas, and fire or decomposition may produce cyanide and nitrogen oxide gases.

Response guidance: For a UN 1541 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 156. Establish incident command, isolate the area, stay upwind, prevent incompatible contact and choose extinguishing or spill-control actions based on ERG, SDS and local SOP.

Firefighter training notes: Training for UN 1541 should emphasize hydrogen cyanide release, stabilization loss, water/alkali incompatibility, vapor monitoring, decontamination and early hazmat/medical coordination. Use ERG 156, SDS and local SOP.

Regulatory context: Acetone cyanohydrin, stabilized is regulated as a toxic hazardous material. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Acetone cyanohydrin, stabilized should be stored in compatible, secured containers with stabilizer controls maintained, away from heat, alkalis, water contamination and incompatible materials. Storage should include ventilation, cyanide emergency planning and leak control appropriate to the SDS.

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UN 1541 Quick Details

UN 1541
Product name: Acetone cyanohydrin, stabilized
DOT Class: 6
Placard type: Toxic
ERG Guide: 156 (check current ERG)
Initial isolation: ERG 156: Initially isolate 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate initial 800m downwind

Common Hazards of UN 1541

  • HIGHLY TOXIC; may release hydrogen cyanide if heated, decomposing, alkaline-contaminated or in contact with water.
  • Combustible liquid; vapors may form flammable mixtures when heated.
  • Vapors are heavier than air and may collect in low or confined areas.
  • Stabilization may be lost if contaminated, heated or exposed to incompatible conditions.
  • Fire may produce hydrogen cyanide, nitrogen oxides and other toxic gases.
  • Containers may rupture or explode when heated.
  • Runoff and contaminated water may carry cyanide hazards.

Chemical Identity & Physical Properties

Colorless to straw-colored liquid with a faint almond-like odor. Liquid at room temperature, typically stabilized with phosphoric acid to prevent decomposition.

Also known as2-Hydroxy-2-methylpropanenitrile2-MethyllactonitrileACHCyanhydrin acetone2-Cyanopropan-2-ol
CAS Number75-86-5
AppearanceColorless to straw-colored liquid with a faint almond-like odor. Liquid at room temperature, typically stabilized with phosphoric acid to prevent decomposition.
Flash Point74°C (165°F)
Boiling Point95°C (203°F) - decomposes at higher temperatures
Vapor Density2.9 (heavier than air)
Water ReactivityReacts with water releasing hydrogen cyanide gas (HCN), a highly toxic flammable gas. Reaction accelerates with heat or alkaline conditions.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1541

Extinguishing Media

Use alcohol-resistant foam, dry chemical or CO2 when compatible and directed by incident command. Water spray may cool containers from a protected distance, but direct water contact with product or runoff may increase hydrogen cyanide hazards.

PPE Requirements

⚠️ Level A minimum due to HCN hazard; SCBA with full face protection required; chemical-resistant suit; cyanide antidote kit on standby

Use positive-pressure SCBA and chemical protective clothing selected by hazmat specialists for any potential vapor or liquid exposure. Level A may be needed for close entry or unknown concentrations because hydrogen cyanide release and skin absorption are major concerns.

Isolation & Evacuation

ERG 156: Initially isolate 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate initial 800m downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 156).

First Actions for a UN 1541 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust or mist and avoid all skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement or unknown concentration is present.
  • Use ERG Guide 156, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1541 — Acetone cyanohydrin, stabilized
HAZMAT RADIO NOTE — UN 1541 Product: Acetone cyanohydrin, stabilized Class 6 / Toxic / ERG 156 PPE: Level A minimum due to HCN hazard; SCBA with full face protection required; chemical-resistant suit; cyanide antidote kit on standby ISOLATION: ERG 156: Initially isolate 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate initial 800m downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1541 — Acetone cyanohydrin, stabilized Class: 6 | Placard: Toxic | ERG Guide: 156 Appearance: Colorless to straw-colored liquid with a faint almond-like odor. Liquid at room temperature, typically stabilized with phosphoric acid to prevent decomposition. Water Reactivity: Reacts with water releasing hydrogen cyanide gas (HCN), a highly toxic flammable gas. Reaction accelerates with heat or alkaline conditions. Extinguishing: Use alcohol-resistant foam, dry chemical or CO2 when compatible and directed by incident command. Water spray may cool containers from a protected distance, but direct water contact with product or runoff may increase hydrogen cyanide hazards. PPE: Level A minimum due to HCN hazard; SCBA with full face protection required; chemical-resistant suit; cyanide antidote kit on standby Isolation: ERG 156: Initially isolate 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate initial 800m downwind — Key Hazards — • HIGHLY TOXIC; may release hydrogen cyanide if heated, decomposing, alkaline-contaminated or in contact with water. • Combustible liquid; vapors may form flammable mixtures when heated. • Vapors are heavier than air and may collect in low or confined areas. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust or mist and avoid all skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/acetone-cyanohydrin-stabilized-un-1541 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1541 Acetone cyanohydrin, stabilized Cls6 ERG156 | allfirefighter.com/hazmat/un/acetone-cyanohydrin-stabilized-un-1541SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/acetone-cyanohydrin-stabilized-un-1541

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1541

UN 1541 is Acetone cyanohydrin, stabilized, a hazardous material assigned to ERG Guide 156.

It is combustible rather than easily ignited, but toxic hydrogen cyanide release is the dominant emergency concern.

ERG Guide 156 applies to UN 1541 for initial isolation, protective actions and first response guidance.

UN 1541 presents hydrogen cyanide release, toxic vapor, combustible liquid and contaminated-runoff hazards. Vapors can collect in low areas, and fire or decomposition may produce cyanide and nitrogen oxide gases.

Water or alkaline contamination may release hydrogen cyanide, a highly toxic gas. Follow ERG, SDS and incident command before applying water directly to product.

Use positive-pressure SCBA and chemical protective clothing selected by hazmat specialists for any potential vapor or liquid exposure. Level A may be needed for close entry or unknown concentrations because hydrogen cyanide release and skin absorption are major concerns.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.