☣️ UN 1838 • CLASS 6
Titanium tetrachloride
Placard: Toxic. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1838
Class: 6
Placard type: Toxic
ERG: Guide 137 (check current ERG)
Isolation: ERG 137: Initial isolation 60m in all directions. Protect persons downwind. If tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation.
Chemical & Response Details
| Also known as | TetrachlorotitaniumTitanic chlorideTitanium(IV) chlorideTiCl4 |
| CAS Number | 7550-45-0 |
| Appearance | Colorless to pale yellow fuming liquid with a pungent, acrid odor. Fumes heavily in moist air, producing dense white clouds of hydrochloric acid and titanium oxychloride. |
| Flash Point | Not applicable (non-flammable) |
| Boiling Point | 136C (277F) |
| Vapor Density | 6.6 (much heavier than air) |
| Water Reactivity | Reacts violently with water, generating substantial heat and releasing dense, corrosive hydrochloric acid fumes. Do not use water directly on material. |
| Extinguishing | Dry chemical, CO2, dry sand, soda ash. Do not use water or foam. Use water spray only to cool surrounding containers from a distance. |
| PPE | ⚠️ Level A recommended; full encapsulating suit with SCBA required due to corrosive vapor generation. Butyl or Viton gloves. Avoid all skin and eye contact. |
| Isolation | ERG 137: Initial isolation 60m in all directions. Protect persons downwind. If tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation. |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance
- Fire will produce irritating, corrosive and/or toxic gases.
- Reaction with water may generate much heat that will increase the concentration of fumes in the air.
- Contact with molten substance may cause severe burns to skin and eyes.
- Runoff from fire control or dilution water may cause environmental contamination.
- EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 1838 — Titanium tetrachloride HAZMAT RADIO NOTE — UN 1838
Product: Titanium tetrachloride
Class 6 / Toxic / ERG 137
PPE: Level A recommended; full encapsulating suit with SCBA required due to corrosive vapor generation. Butyl or Viton gloves. Avoid all skin and eye contact.
ISOLATION: ERG 137: Initial isolation 60m in all directions. Protect persons downwind. If tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation.
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 1838 — Titanium tetrachloride
Class: 6 | Placard: Toxic | ERG Guide: 137
Appearance: Colorless to pale yellow fuming liquid with a pungent, acrid odor. Fumes heavily in moist air, producing dense white clouds of hydrochloric acid and titanium oxychloride.
Water Reactivity: Reacts violently with water, generating substantial heat and releasing dense, corrosive hydrochloric acid fumes. Do not use water directly on material.
Extinguishing: Dry chemical, CO2, dry sand, soda ash. Do not use water or foam. Use water spray only to cool surrounding containers from a distance.
PPE: Level A recommended; full encapsulating suit with SCBA required due to corrosive vapor generation. Butyl or Viton gloves. Avoid all skin and eye contact.
Isolation: ERG 137: Initial isolation 60m in all directions. Protect persons downwind. If tank/rail car involved in fire, isolate 800m in all directions and consider initial evacuation.
— Key Hazards —
• CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance
• Fire will produce irritating, corrosive and/or toxic gases.
• Reaction with water may generate much heat that will increase the concentration of fumes in the air.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/1838 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN1838 Titanium tetrachloride Cls6 ERG137 | ERG 137: Initial isolation 60m in all directions. Protect persons downwind. If t | allfirefighter.com/hazmat/un/1838SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1838
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FAQ
CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause environmental contamination. EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level A recommended; full encapsulating suit with SCBA required due to corrosive vapor generation. Butyl or Viton gloves. Avoid all skin and eye contact.
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 137 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.