☣️ UN 1897 • CLASS 6

UN 1897 — Tetrachloroethylene

Placard: Toxic. ERG Guide 160. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1897 is Tetrachloroethylene, a toxic halogenated liquid assigned to ERG Guide 160. Heavy vapor can collect in low or confined spaces and liquid may sink in water.

Hazard overview: UN 1897 presents toxic vapor, low-area accumulation, dense-liquid contamination and toxic decomposition hazards in fire. Heating may produce phosgene-type and hydrogen halide gases.

Response guidance: For a UN 1897 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 160. Establish incident command, isolate the area, stay upwind, prevent incompatible contact, control runoff and choose entry or fire-control actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1897 should emphasize toxic solvent vapor behavior, low-area accumulation, skin exposure, decomposition gas hazards, air monitoring and runoff containment. Use ERG 160, SDS and local SOP.

Regulatory context: Tetrachloroethylene is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Tetrachloroethylene should be stored in tightly closed compatible containers in a cool, well-ventilated toxic-solvent area away from heat, ignition sources where applicable, strong oxidizers, reactive metals where incompatible and drains.

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UN 1897 Quick Details

UN 1897
Product name: Tetrachloroethylene
DOT Class: 6
Placard type: Toxic
ERG Guide: 160 (check current ERG)
Initial isolation: ERG 160: isolate spill area minimum 25m in all directions; for large spills isolate 50m and evacuate downwind

Common Hazards of UN 1897

  • TOXIC halogenated liquid; inhalation, ingestion or skin contact may cause serious injury.
  • Vapors are heavier than air and may collect in low or confined areas, causing dizziness or asphyxiation risk.
  • Liquid is denser than water and may sink, spreading contamination below the surface.
  • Usually non-flammable or not readily flammable, but heating or fire may produce phosgene-type and hydrogen halide gases.
  • Skin and eye contact may irritate or burn depending on concentration and exposure.
  • Runoff may carry toxic chlorinated solvent contamination.
  • Containers may rupture or fail when heated.

Chemical Identity & Physical Properties

Colorless, non-flammable liquid with a sweet, ether-like or chloroform-like odor. Denser than water and will sink.

Also known asPerchloroethylenePCEPercTetrachloroetheneEthylene tetrachloridePercleneTetracap
CAS Number127-18-4
AppearanceColorless, non-flammable liquid with a sweet, ether-like or chloroform-like odor. Denser than water and will sink.
Flash PointNot applicable (non-flammable)
Boiling Point121°C (250°F)
Vapor Density5.8 (much heavier than air)
Water ReactivityNo significant reaction with water; low solubility
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1897

Extinguishing Media

Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers only when runoff and contamination can be controlled.

PPE Requirements

⚠️ Level B minimum with SCBA; butyl or viton gloves recommended; vapor protection essential in confined spaces

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS to prevent solvent skin contact.

Isolation & Evacuation

ERG 160: isolate spill area minimum 25m in all directions; for large spills isolate 50m and evacuate downwind
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 160).

First Actions for a UN 1897 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust, mist or spray and avoid skin or eye contact.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement, water reaction or unknown concentration is present.
  • Use ERG Guide 160, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1897 — Tetrachloroethylene
HAZMAT RADIO NOTE — UN 1897 Product: Tetrachloroethylene Class 6 / Toxic / ERG 160 PPE: Level B minimum with SCBA; butyl or viton gloves recommended; vapor protection essential in confined spaces ISOLATION: ERG 160: isolate spill area minimum 25m in all directions; for large spills isolate 50m and evacuate downwind ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1897 — Tetrachloroethylene Class: 6 | Placard: Toxic | ERG Guide: 160 Appearance: Colorless, non-flammable liquid with a sweet, ether-like or chloroform-like odor. Denser than water and will sink. Water Reactivity: No significant reaction with water; low solubility Extinguishing: Use extinguishing agents appropriate for the surrounding fire and SDS. Water spray may cool containers only when runoff and contamination can be controlled. PPE: Level B minimum with SCBA; butyl or viton gloves recommended; vapor protection essential in confined spaces Isolation: ERG 160: isolate spill area minimum 25m in all directions; for large spills isolate 50m and evacuate downwind — Key Hazards — • TOXIC halogenated liquid; inhalation, ingestion or skin contact may cause serious injury. • Vapors are heavier than air and may collect in low or confined areas, causing dizziness or asphyxiation risk. • Liquid is denser than water and may sink, spreading contamination below the surface. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust, mist or spray and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/tetrachloroethylene-un-1897 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1897 Tetrachloroethylene Cls6 ERG160 | allfirefighter.com/hazmat/un/tetrachloroethylene-un-1897SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/tetrachloroethylene-un-1897

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1897

UN 1897 is Tetrachloroethylene, a hazardous material assigned to ERG Guide 160.

No. It is generally non-flammable or not readily flammable, but fire may produce highly toxic decomposition gases.

ERG Guide 160 applies to UN 1897 for initial isolation, protective actions and first response guidance.

UN 1897 presents toxic vapor, low-area accumulation, dense-liquid contamination and toxic decomposition hazards in fire. Heating may produce phosgene-type and hydrogen halide gases.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS to prevent solvent skin contact.

Fire or high heat may produce highly toxic chlorinated decomposition products, including phosgene-type gases and hydrogen halides.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.