☣️ UN 1974 • CLASS 2

UN 1974 — Chlorodifluorobromomethane

Placard: Non-Flammable Gas. ERG Guide 126. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1974 is Chlorodifluorobromomethane, a non-flammable liquefied compressed refrigerant gas assigned to ERG Guide 126. The main concerns are pressure, oxygen displacement, frostbite and toxic decomposition in fire.

Hazard overview: NON-FLAMMABLE liquefied compressed refrigerant gas; pressure and asphyxiation hazards are primary. Heavy vapor may collect in low or confined areas and displace oxygen. Contact with liquefied gas may cause frostbite or cold burns.

Response guidance: For a UN 1974 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 126. Establish incident command, isolate the area, stay upwind, control ignition or downwind hazards, cool exposed containers from a protected distance when appropriate and base entry decisions on monitoring and local SOP.

Firefighter training notes: Training for UN 1974 should emphasize pressure hazards, oxygen displacement, frostbite, cylinder rupture/rocket risk, ventilation and atmospheric monitoring. Use ERG 126, SDS and local SOP.

Regulatory context: Chlorodifluorobromomethane is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting and waste handling requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Chlorodifluorobromomethane cylinders should be secured in a cool, ventilated area away from heat, physical damage and incompatible materials. Prevent leaks into confined or low areas and follow SDS and refrigerant cylinder requirements.

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UN 1974 Quick Details

UN 1974
Product name: Chlorodifluorobromomethane
DOT Class: 2
Placard type: Non-Flammable Gas
ERG Guide: 126 (check current ERG)
Initial isolation: ERG 126: isolate 100m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider evacuation

Common Hazards of UN 1974

  • NON-FLAMMABLE liquefied compressed refrigerant gas; pressure and asphyxiation hazards are primary.
  • Heavy vapor may collect in low or confined areas and displace oxygen.
  • Contact with liquefied gas may cause frostbite or cold burns.
  • Containers may rupture or rocket when heated.
  • Fire or hot surfaces may decompose refrigerant and produce toxic/corrosive gases such as hydrogen halides.
  • Vapor may cause dizziness or unconsciousness in poorly ventilated spaces.
  • Specific refrigerant hazards should be confirmed from SDS and cylinder markings.

Chemical Identity & Physical Properties

Colorless, nearly odorless liquefied compressed gas. Exists as a liquid under pressure or when cooled below its boiling point.

Also known asHalon 1211BCFBromochlorodifluoromethaneFreon 12B1CBFluorocarbon 1211
CAS Number75-63-8
AppearanceColorless, nearly odorless liquefied compressed gas. Exists as a liquid under pressure or when cooled below its boiling point.
Flash PointNot applicable (non-flammable gas)
Boiling Point-4C (25F)
Vapor Density5.8 (heavier than air)
Water ReactivityNo significant reaction with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1974

Extinguishing Media

Material is not normally the fuel. Use water spray from a protected distance to cool cylinders or containers and use agents appropriate to the surrounding fire.

PPE Requirements

⚠️ Level B minimum; SCBA required in confined spaces or high concentrations; can displace oxygen

Use SCBA and oxygen monitoring in confined or oxygen-deficient areas. Wear face shield, insulated or cryogenic gloves and protective clothing when liquefied or refrigerated gas contact is possible.

Isolation & Evacuation

ERG 126: isolate 100m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 126).

First Actions for a UN 1974 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the release or spill area and expand the perimeter for fire involvement, vapor accumulation, cylinder/tank heating or unknown product identity.
  • Use ERG Guide 126, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 1974 — Chlorodifluorobromomethane
HAZMAT RADIO NOTE — UN 1974 Product: Chlorodifluorobromomethane Class 2 / Non-Flammable Gas / ERG 126 PPE: Level B minimum; SCBA required in confined spaces or high concentrations; can displace oxygen ISOLATION: ERG 126: isolate 100m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1974 — Chlorodifluorobromomethane Class: 2 | Placard: Non-Flammable Gas | ERG Guide: 126 Appearance: Colorless, nearly odorless liquefied compressed gas. Exists as a liquid under pressure or when cooled below its boiling point. Water Reactivity: No significant reaction with water Extinguishing: Material is not normally the fuel. Use water spray from a protected distance to cool cylinders or containers and use agents appropriate to the surrounding fire. PPE: Level B minimum; SCBA required in confined spaces or high concentrations; can displace oxygen Isolation: ERG 126: isolate 100m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and consider evacuation — Key Hazards — • NON-FLAMMABLE liquefied compressed refrigerant gas; pressure and asphyxiation hazards are primary. • Heavy vapor may collect in low or confined areas and displace oxygen. • Contact with liquefied gas may cause frostbite or cold burns. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, smoke, mist or dust and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/chlorodifluorobromomethane-un-1974 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1974 Chlorodifluorobromomethane Cls2 ERG126 | allfirefighter.com/hazmat/un/chlorodifluorobromomethane-un-1974SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/chlorodifluorobromomethane-un-1974

Related UN Numbers in Class 2

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1974

UN 1974 is Chlorodifluorobromomethane, a hazardous material assigned to ERG Guide 126.

No. It is normally non-flammable, but heating or fire may produce toxic/corrosive decomposition products.

ERG Guide 126 applies to UN 1974 for initial isolation, protective actions and first response guidance.

NON-FLAMMABLE liquefied compressed refrigerant gas; pressure and asphyxiation hazards are primary. Heavy vapor may collect in low or confined areas and displace oxygen. Contact with liquefied gas may cause frostbite or cold burns.

Use SCBA and oxygen monitoring in confined or oxygen-deficient areas. Wear face shield, insulated or cryogenic gloves and protective clothing when liquefied or refrigerated gas contact is possible.

Gas can displace oxygen without obvious warning, and liquefied or cryogenic gas can also cause frostbite.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.