☣️ UN 2431 • CLASS 6

UN 2431 — Anisidines

Placard: Toxic. ERG Guide 153. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2431 is Anisidines, a toxic aromatic amine entry assigned to ERG Guide 153. Skin absorption and contaminated clothing are major response concerns.

Hazard overview: TOXIC aromatic amine; inhalation, ingestion or skin absorption may cause severe injury. Skin absorption and contaminated clothing are major exposure concerns. Combustible material: may burn but does not ignite readily.

Response guidance: For UN 2431, isolate the area, avoid skin contact and use SCBA where dust, vapor, mist or fire is present. Contain toxic/corrosive runoff and verify exact product controls with SDS and ERG 153.

Firefighter training notes: Training for UN 2431 should emphasize toxic/corrosive exposure routes, skin absorption, SCBA use, decontamination, runoff containment and SDS verification. Use ERG 153, SDS and local SOP.

Regulatory context: Anisidines is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Anisidines should be stored in tightly closed compatible containers in a secure toxic/corrosive-material area with ventilation, secondary containment, restricted access and SDS-based segregation.

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UN 2431 Quick Details

UN 2431
Product name: Anisidines
DOT Class: 6
Placard type: Toxic
ERG Guide: 153 (check current ERG)
Initial isolation: ERG 153: isolate spill 25m all directions; large spill isolate 50m; evacuate 300m downwind if tank/rail car involved in fire

Common Hazards of UN 2431

  • TOXIC aromatic amine; inhalation, ingestion or skin absorption may cause severe injury.
  • Skin absorption and contaminated clothing are major exposure concerns.
  • Combustible material: may burn but does not ignite readily.
  • Exposure may cause systemic blood/oxygen-carrying effects depending on dose and isomer.
  • Fire may produce nitrogen oxides and toxic aromatic amine smoke.
  • Runoff may carry toxic contamination.
  • Avoid dust, vapor or liquid contact and control decontamination waste.

Chemical Identity & Physical Properties

Colorless to pale yellow or reddish oily liquid or crystalline solid, depending on isomer. Aromatic amine odor. Darkens on exposure to air and light.

Also known asAminoanisoleMethoxyanilineMethyl aminophenol etherAnisidine isomers
AppearanceColorless to pale yellow or reddish oily liquid or crystalline solid, depending on isomer. Aromatic amine odor. Darkens on exposure to air and light.
Flash Point118-141C (244-286F) depending on isomer
Boiling Point224-254C (435-489F) depending on isomer
Vapor Density4.2-4.3 (heavier than air)
Water ReactivityNo significant reaction with water; slightly soluble
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2431

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from protection and contain toxic/corrosive runoff.

PPE Requirements

⚠️ Level B minimum with SCBA; full chemical protective suit if contact likely; aromatic amines absorb readily through skin

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and clothing; avoid skin contact.

Isolation & Evacuation

ERG 153: isolate spill 25m all directions; large spill isolate 50m; evacuate 300m downwind if tank/rail car involved in fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 153).

First Actions for a UN 2431 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated dust, liquid, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 153, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2431 — Anisidines
HAZMAT RADIO NOTE — UN 2431 Product: Anisidines Class 6 / Toxic / ERG 153 PPE: Level B minimum with SCBA; full chemical protective suit if contact likely; aromatic amines absorb readily through skin ISOLATION: ERG 153: isolate spill 25m all directions; large spill isolate 50m; evacuate 300m downwind if tank/rail car involved in fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2431 — Anisidines Class: 6 | Placard: Toxic | ERG Guide: 153 Appearance: Colorless to pale yellow or reddish oily liquid or crystalline solid, depending on isomer. Aromatic amine odor. Darkens on exposure to air and light. Water Reactivity: No significant reaction with water; slightly soluble Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from protection and contain toxic/corrosive runoff. PPE: Level B minimum with SCBA; full chemical protective suit if contact likely; aromatic amines absorb readily through skin Isolation: ERG 153: isolate spill 25m all directions; large spill isolate 50m; evacuate 300m downwind if tank/rail car involved in fire — Key Hazards — • TOXIC aromatic amine; inhalation, ingestion or skin absorption may cause severe injury. • Skin absorption and contaminated clothing are major exposure concerns. • Combustible material: may burn but does not ignite readily. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/anisidines-un-2431 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2431 Anisidines Cls6 ERG153 | allfirefighter.com/hazmat/un/anisidines-un-2431SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/anisidines-un-2431

Related UN Numbers in Class 6

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2431

UN 2431 is Anisidines, assigned to ERG Guide 153.

It is combustible but does not ignite readily; toxic/corrosive exposure and fire decomposition products are the main hazards.

TOXIC aromatic amine; inhalation, ingestion or skin absorption may cause severe injury. Skin absorption and contaminated clothing are major exposure concerns. Combustible material: may burn but does not ignite readily.

Use positive-pressure SCBA for dust, vapor, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and clothing; avoid skin contact.

Use dry chemical, CO2, foam or water spray as compatible with the product and fire size. Cool containers from protection and contain toxic/corrosive runoff.

Toxic or corrosive material can contaminate clothing, tools and runoff, extending exposure beyond the original spill area.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.