☣️ UN 3077 • CLASS 9

UN 3077 — Environmentally hazardous substance, solid, n.o.s.

Placard: Miscellaneous. ERG Guide 171. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3077 is Environmentally hazardous substance, solid, n.o.s., a broad Class 9 environmental hazard entry assigned to ERG Guide 171. Exact material and runoff behavior must be verified.

Hazard overview: Environmentally hazardous solid, n.o.s.; primary concern is environmental contamination, especially waterways. Dust, granules or broken packages may contaminate soil, drains and runoff. Human toxicity, combustibility and water behavior vary by exact substance.

Response guidance: For UN 3077, isolate the area, avoid skin contact and use SCBA where vapor, dust, mist or fire is present. Contain runoff and verify controls with SDS and ERG 171.

Firefighter training notes: Training for UN 3077 should emphasize exposure routes, SCBA use, vapor/dust monitoring, decontamination, runoff containment and SDS/package verification. Use ERG 171, SDS and local SOP.

Regulatory context: Environmentally hazardous substance, solid, n.o.s. is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, formulation and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Environmentally hazardous substance, solid, n.o.s. should be stored in tightly closed compatible containers with ventilation, secondary containment, restricted access and SDS-based segregation from incompatible materials.

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UN 3077 Quick Details

UN 3077
Product name: Environmentally hazardous substance, solid, n.o.s.
DOT Class: 9
Placard type: Miscellaneous
ERG Guide: 171 (check current ERG)
Initial isolation: ERG 171: Small spills isolate 25m all directions; large spills isolate 50m all directions; no evacuation distances specified for this guide as materials present minimal immediate hazard to people

Common Hazards of UN 3077

  • Environmentally hazardous solid, n.o.s.; primary concern is environmental contamination, especially waterways.
  • Dust, granules or broken packages may contaminate soil, drains and runoff.
  • Human toxicity, combustibility and water behavior vary by exact substance.
  • Some materials may burn or produce toxic smoke if involved in fire.
  • Runoff from fire control may spread pollutant beyond the original spill area.
  • Avoid dust generation and uncontrolled washing into drains.
  • Exact identity must be verified from SDS and shipping papers.

Chemical Identity & Physical Properties

Variable appearance depending on specific substance; typically a solid material at room temperature that poses environmental hazards, particularly to aquatic ecosystems. May be powders, granules, or solid masses with varying colors and no characteristic odor as this is a generic classification.

Also known asEnvironmental hazard solid NOSHazardous to aquatic environment solidMarine pollutant solidEcotoxic substance solid
AppearanceVariable appearance depending on specific substance; typically a solid material at room temperature that poses environmental hazards, particularly to aquatic ecosystems. May be powders, granules, or solid masses with varying colors and no characteristic odor as this is a generic classification.
Flash PointVariable depending on specific substance; many are not readily ignitable
Boiling PointNot applicable (solid at ambient conditions)
Vapor DensityNot applicable (solid material)
Water ReactivityGenerally no violent reaction, but may slowly dissolve or release harmful substances into water causing environmental damage
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3077

Extinguishing Media

Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain contaminated runoff.

PPE Requirements

⚠️ Level D minimum for routine handling; Level C or B if substance identity unknown or airborne exposure possible; nitrile or neoprene gloves recommended; respiratory protection if dust generation occurs

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Isolation & Evacuation

ERG 171: Small spills isolate 25m all directions; large spills isolate 50m all directions; no evacuation distances specified for this guide as materials present minimal immediate hazard to people
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 171).

First Actions for a UN 3077 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Avoid breathing vapor, dust, gas, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Prevent contaminated liquid, dust, runoff and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 171, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 3077 — Environmentally hazardous substance, sol
HAZMAT RADIO NOTE — UN 3077 Product: Environmentally hazardous substance, solid, n.o.s. Class 9 / Miscellaneous / ERG 171 PPE: Level D minimum for routine handling; Level C or B if substance identity unknown or airborne exposure possible; nitrile or neoprene gloves recommended; respiratory protection if dust generation occurs ISOLATION: ERG 171: Small spills isolate 25m all directions; large spills isolate 50m all directions; no evacuation distances specified for this guide as materials present minimal immediate hazard to people ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3077 — Environmentally hazardous substance, solid, n.o.s. Class: 9 | Placard: Miscellaneous | ERG Guide: 171 Appearance: Variable appearance depending on specific substance; typically a solid material at room temperature that poses environmental hazards, particularly to aquatic ecosystems. May be powders, granules, or solid masses with varying colors and no characteristic odor as this is a generic classification. Water Reactivity: Generally no violent reaction, but may slowly dissolve or release harmful substances into water causing environmental damage Extinguishing: Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain contaminated runoff. PPE: Level D minimum for routine handling; Level C or B if substance identity unknown or airborne exposure possible; nitrile or neoprene gloves recommended; respiratory protection if dust generation occurs Isolation: ERG 171: Small spills isolate 25m all directions; large spills isolate 50m all directions; no evacuation distances specified for this guide as materials present minimal immediate hazard to people — Key Hazards — • Environmentally hazardous solid, n.o.s.; primary concern is environmental contamination, especially waterways. • Dust, granules or broken packages may contaminate soil, drains and runoff. • Human toxicity, combustibility and water behavior vary by exact substance. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Avoid breathing vapor, dust, gas, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/environmentally-hazardous-substance-solid-un-3077 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3077 Environmentally hazardous substance, solid, n.o.s. Cls9 ERG171 | allfirefighter.com/hazmat/un/environmentally-hazardous-substance-solid-un-3077SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/environmentally-hazardous-substance-solid-un-3077

Related UN Numbers in Class 9

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3077

UN 3077 is Environmentally hazardous substance, solid, n.o.s., assigned to ERG Guide 171.

Flammability depends on exact formulation or package contents; verify SDS and shipping papers.

Environmentally hazardous solid, n.o.s.; primary concern is environmental contamination, especially waterways. Dust, granules or broken packages may contaminate soil, drains and runoff. Human toxicity, combustibility and water behavior vary by exact substance.

Use positive-pressure SCBA for vapor, dust, mist, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing.

Use dry chemical, CO2, foam or water spray as compatible with fire size. Cool containers from protection and contain contaminated runoff.

The entry covers variable materials, so toxicity, flammability, water behavior and PPE can change.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.