☣️ UN 1125 • CLASS 3

UN 1125 — n-Butylamine

Placard: Flammable. ERG Guide 132. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 1125 Quick Details

UN 1125
Product name: n-Butylamine
DOT Class: 3
Placard type: Flammable
ERG Guide: 132 (check current ERG)
Initial isolation: ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions

Common Hazards of UN 1125

  • Flammable/combustible material.
  • May be ignited by heat, sparks or flames.
  • Vapors may form explosive mixtures with air.
  • Vapors may travel to source of ignition and flash back.
  • Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
  • Vapor explosion hazard indoors, outdoors or in sewers.
  • Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
  • Runoff to sewer may create fire or explosion hazard.

Chemical Identity & Physical Properties

Also known as1-butanaminebutylaminemono-n-butylamine1-aminobutanenorvalamine
CAS Number109-73-9
AppearanceColorless to pale yellow liquid with a strong ammonia-like or fishy odor. Highly volatile at room temperature.
Flash Point-12°C (10°F)
Boiling Point78°C (172°F)
Vapor Density2.5 (heavier than air)
Water ReactivitySoluble in water, moderate exothermic reaction with water releasing heat
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1125

Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical; regular foam may not be effective

PPE Requirements

⚠️ Level B minimum; SCBA required; chemical-resistant gloves and suit due to corrosive nature

Isolation & Evacuation

ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 132).

First Actions for a UN 1125 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
  • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
  • For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card

UN 1125 — n-Butylamine
HAZMAT RADIO NOTE — UN 1125 Product: n-Butylamine Class 3 / Flammable / ERG 132 PPE: Level B minimum; SCBA required; chemical-resistant gloves and suit due to corrosive nature ISOLATION: ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1125 — n-Butylamine Class: 3 | Placard: Flammable | ERG Guide: 132 Appearance: Colorless to pale yellow liquid with a strong ammonia-like or fishy odor. Highly volatile at room temperature. Water Reactivity: Soluble in water, moderate exothermic reaction with water releasing heat Extinguishing: Alcohol-resistant foam, CO2, dry chemical; regular foam may not be effective PPE: Level B minimum; SCBA required; chemical-resistant gloves and suit due to corrosive nature Isolation: ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions — Key Hazards — • Flammable/combustible material. • May be ignited by heat, sparks or flames. • Vapors may form explosive mixtures with air. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Ventilate closed spaces before entering, but only if properly trained and equipped. SOURCE: allfirefighter.com/hazmat/un/1125 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN1125 n-Butylamine Cls3 ERG132 | ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, is | allfirefighter.com/hazmat/un/1125SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1125

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1125

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum; SCBA required; chemical-resistant gloves and suit due to corrosive nature

Water reactivity: Soluble in water, moderate exothermic reaction with water releasing heat. Recommended extinguishing: Alcohol-resistant foam, CO2, dry chemical; regular foam may not be effective.

ERG Guide 132 recommendation: ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 132 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.