☣️ UN 1158 • CLASS 3
Diisopropylamine
Placard: Flammable. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1158
Class: 3
Placard type: Flammable
ERG: Guide 132 (check current ERG)
Verify shipping papers and exact product details; use ERG Guide 132 for initial actions and isolation/evacuation guidance.
Chemical & Response Details
| Also known as | DIPAN-isopropyl-2-propanaminebis(1-methylethyl)aminedi-iso-propylamine |
| CAS Number | 108-18-9 |
| Appearance | Colorless to pale yellow liquid with a strong, fishy, amine-like odor. Less dense than water and volatile at room temperature. |
| Flash Point | -6C (21F) |
| Boiling Point | 84C (183F) |
| Vapor Density | 3.5 (heavier than air) |
| Water Reactivity | Moderate reaction; forms alkaline solution, may generate heat |
| Extinguishing | Alcohol-resistant foam, CO2, dry chemical; water spray for cooling only |
| PPE | ⚠️ Level B minimum; SCBA and chemical-resistant suit required; amine vapors highly irritating |
| Isolation | ERG 132: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- Flammable/combustible material.
- May be ignited by heat, sparks or flames.
- Vapors may form explosive mixtures with air.
- Vapors may travel to source of ignition and flash back.
- Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
- Vapor explosion hazard indoors, outdoors or in sewers.
- Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
- Runoff to sewer may create fire or explosion hazard.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
Copy / share note
MAYDAY / HAZMAT QUICK NOTE UN 1158 — Diisopropylamine Class: 3 | Placard: Flammable ERG: Guide 132 (check current ERG) FIRST ACTIONS: use SOP/SOG + ERG; stage upwind; isolate; deny entry; request Hazmat.
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FAQ
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum; SCBA and chemical-resistant suit required; amine vapors highly irritating
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 132 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.