☣️ UN 1169 • CLASS 3

UN 1169 — Extracts, aromatic, liquid

Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1169 is Extracts, aromatic, liquid, a Class 3 flammable aromatic hydrocarbon entry assigned to ERG Guide 127. It can produce heavy vapors, flashback hazards and toxic smoke during fire.

Hazard overview: UN 1169 presents flammable vapor, flashback and aromatic hydrocarbon exposure hazards. Vapors may collect in low areas, spilled liquid may float on water, and fire can produce irritating or toxic smoke.

Response guidance: For a UN 1169 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 127. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors or runoff out of sewers and use compatible Class B fire-control agents from a protected position.

Firefighter training notes: Training for UN 1169 should emphasize flammable liquid vapor travel, flashback, sewer vapor explosion risk, foam compatibility, container cooling and atmospheric monitoring. Common errors include standing downwind, allowing runoff into drains and ignoring low-area vapor collection. Use ERG 127, SDS and local SOP.

Regulatory context: Extracts, aromatic, liquid is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Extracts, aromatic, liquid should be stored in tightly closed compatible containers in a cool, dry, well-ventilated flammable-liquid storage area. Keep away from heat, sparks, open flames, oxidizers and incompatible materials, with bonding/grounding, secondary containment and drain protection where required.

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UN 1169 Quick Details

UN 1169
Product name: Extracts, aromatic, liquid
DOT Class: 3
Placard type: Flammable
ERG Guide: 127 (check current ERG)
Initial isolation: ERG 127: Small spill isolate 30m all directions; large spill isolate 100m all directions. If tank/rail car involved in fire, isolate 800m all directions and consider initial evacuation 800m all directions.

Common Hazards of UN 1169

  • FLAMMABLE aromatic hydrocarbon liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may collect in low, confined or sewer areas.
  • Liquid may float on water and spread fire across surfaces.
  • Vapor exposure may cause dizziness, headache or respiratory irritation.
  • Fire may produce irritating or toxic smoke.
  • Runoff to sewer may create fire, explosion or environmental hazards.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Clear to amber-colored liquid with a characteristic aromatic, petroleum-like odor. Liquid at room temperature, consisting of mixed aromatic hydrocarbons extracted from petroleum fractions.

Also known asAromatic extractsAromatic solvent extractsLiquid aromatic hydrocarbonsAromatic petroleum extractsMixed aromatic solvents
AppearanceClear to amber-colored liquid with a characteristic aromatic, petroleum-like odor. Liquid at room temperature, consisting of mixed aromatic hydrocarbons extracted from petroleum fractions.
Flash PointTypically 23°C to 60°C (73°F to 140°F) depending on specific composition
Boiling PointWide range typically 110°C to 200°C (230°F to 392°F) depending on mixture
Vapor DensityGreater than 3 (heavier than air)
Water ReactivityInsoluble in water; floats on water surface. No significant reaction with water.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1169

Extinguishing Media

Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers.

PPE Requirements

⚠️ Level B minimum for spill response; SCBA and chemical-resistant suit. Level C may be acceptable with appropriate air monitoring showing vapors below IDLH.

Use positive-pressure SCBA for fire, heavy vapor or confined-space exposure. Chemical-resistant gloves, splash protection and protective clothing should be selected using SDS, product concentration and incident command.

Isolation & Evacuation

ERG 127: Small spill isolate 30m all directions; large spill isolate 100m all directions. If tank/rail car involved in fire, isolate 800m all directions and consider initial evacuation 800m all directions.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 127).

First Actions for a UN 1169 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Eliminate ignition sources if it is safe to do so.
  • Do not touch or walk through spilled liquid unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or leak area for at least 50 meters (150 feet) in all directions.
  • For large spills, fire involvement or strong vapor movement, expand isolation and consider downwind evacuation based on monitoring and incident command.
  • Use ERG Guide 127, shipping papers, SDS and local SOP for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1169 — Extracts, aromatic, liquid
HAZMAT RADIO NOTE — UN 1169 Product: Extracts, aromatic, liquid Class 3 / Flammable / ERG 127 PPE: Level B minimum for spill response; SCBA and chemical-resistant suit. Level C may be acceptable with appropriate air monitoring showing vapors below IDLH. ISOLATION: ERG 127: Small spill isolate 30m all directions; large spill isolate 100m all directions. If tank/rail car involved in fire, isolate 800m all directions and consider initial evacuation 800m all directions. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1169 — Extracts, aromatic, liquid Class: 3 | Placard: Flammable | ERG Guide: 127 Appearance: Clear to amber-colored liquid with a characteristic aromatic, petroleum-like odor. Liquid at room temperature, consisting of mixed aromatic hydrocarbons extracted from petroleum fractions. Water Reactivity: Insoluble in water; floats on water surface. No significant reaction with water. Extinguishing: Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers. PPE: Level B minimum for spill response; SCBA and chemical-resistant suit. Level C may be acceptable with appropriate air monitoring showing vapors below IDLH. Isolation: ERG 127: Small spill isolate 30m all directions; large spill isolate 100m all directions. If tank/rail car involved in fire, isolate 800m all directions and consider initial evacuation 800m all directions. — Key Hazards — • FLAMMABLE aromatic hydrocarbon liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may collect in low, confined or sewer areas. • Liquid may float on water and spread fire across surfaces. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/extracts-aromatic-liquid-un-1169 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1169 Extracts, aromatic, liquid Cls3 ERG127 | allfirefighter.com/hazmat/un/extracts-aromatic-liquid-un-1169SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/extracts-aromatic-liquid-un-1169

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1169

UN 1169 is Extracts, aromatic, liquid, a hazardous material assigned to ERG Guide 127.

Yes. It is a flammable liquid and vapors may form explosive mixtures with air.

ERG Guide 127 applies to UN 1169 and should be used for initial isolation, protective actions and first response guidance.

UN 1169 presents flammable vapor, flashback and aromatic hydrocarbon exposure hazards. Vapors may collect in low areas, spilled liquid may float on water, and fire can produce irritating or toxic smoke.

Use positive-pressure SCBA for fire, heavy vapor or confined-space exposure. Chemical-resistant gloves, splash protection and protective clothing should be selected using SDS, product concentration and incident command.

Responders should isolate the area, stay upwind and uphill, eliminate ignition sources when safe, prevent sewer entry, verify the product with SDS and follow ERG Guide 127, incident command and local SOP.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.