☣️ UN 1196 • CLASS 3
UN 1196 — Ethyltrichlorosilane
Placard: Flammable. ERG Guide 155. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 1196 Quick Details
UN 1196
Product name: Ethyltrichlorosilane
DOT Class: 3
Placard type: Flammable
ERG Guide: 155 (check current ERG)
Initial isolation: ERG 155: Isolate spill 50m all directions. Evacuate 800m downwind if large spill or fire. Consider initial downwind evacuation 300m.
Common Hazards of UN 1196
- HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
- Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.
- Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
- Vapors may travel to source of ignition and flash back.
- Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
- Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
- Corrosives in contact with metals may evolve flammable hydrogen gas.
- Containers may explode when heated or if contaminated with water.
Chemical Identity & Physical Properties
| Also known as | TrichloroethylsilaneEthylsilicon trichlorideSilane, ethyltrichloro-ETCS |
| CAS Number | 115-21-9 |
| Appearance | Colorless to pale yellow liquid with a pungent, acrid, hydrochloric acid-like odor. Fuming liquid that reacts violently with water. |
| Flash Point | -28C (-18F) |
| Boiling Point | 98-100C (208-212F) |
| Vapor Density | 3.6 (heavier than air) |
| Water Reactivity | Reacts violently with water, producing hydrochloric acid fumes and heat. Do not use water directly on material. |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 1196
Extinguishing Media
Dry chemical, CO2, dry sand. Do not use water or foam directly on spills.
PPE Requirements
⚠️ Level B minimum; full chemical protective suit, SCBA required. Rubber or neoprene gloves and boots. Face shield in addition to respirator.
Isolation & Evacuation
ERG 155: Isolate spill 50m all directions. Evacuate 800m downwind if large spill or fire. Consider initial downwind evacuation 300m.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 155).
First Actions for a UN 1196 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card
UN 1196 — EthyltrichlorosilaneHAZMAT RADIO NOTE — UN 1196
Product: Ethyltrichlorosilane
Class 3 / Flammable / ERG 155
PPE: Level B minimum; full chemical protective suit, SCBA required. Rubber or neoprene gloves and boots. Face shield in addition to respirator.
ISOLATION: ERG 155: Isolate spill 50m all directions. Evacuate 800m downwind if large spill or fire. Consider initial downwind evacuation 300m.
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 1196 — Ethyltrichlorosilane
Class: 3 | Placard: Flammable | ERG Guide: 155
Appearance: Colorless to pale yellow liquid with a pungent, acrid, hydrochloric acid-like odor. Fuming liquid that reacts violently with water.
Water Reactivity: Reacts violently with water, producing hydrochloric acid fumes and heat. Do not use water directly on material.
Extinguishing: Dry chemical, CO2, dry sand. Do not use water or foam directly on spills.
PPE: Level B minimum; full chemical protective suit, SCBA required. Rubber or neoprene gloves and boots. Face shield in addition to respirator.
Isolation: ERG 155: Isolate spill 50m all directions. Evacuate 800m downwind if large spill or fire. Consider initial downwind evacuation 300m.
— Key Hazards —
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
• Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.
• Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/1196 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN1196 Ethyltrichlorosilane Cls3 ERG155 | ERG 155: Isolate spill 50m all directions. Evacuate 800m downwind if large spill | allfirefighter.com/hazmat/un/1196SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/1196
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Frequently Asked Questions about UN 1196
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapors may travel to source of ignition and flash back. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Corrosives in contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum; full chemical protective suit, SCBA required. Rubber or neoprene gloves and boots. Face shield in addition to respirator.
Water reactivity: Reacts violently with water, producing hydrochloric acid fumes and heat. Do not use water directly on material.. Recommended extinguishing: Dry chemical, CO2, dry sand. Do not use water or foam directly on spills..
ERG Guide 155 recommendation: ERG 155: Isolate spill 50m all directions. Evacuate 800m downwind if large spill or fire. Consider initial downwind evacuation 300m.
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 155 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.