☣️ UN 1262 • CLASS 3

Isooctane

Placard: Flammable. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1262
Class: 3
Placard type: Flammable
ERG: Guide 128 (check current ERG)
Isolation: ERG 128: isolate spill 50m all directions; evacuate 800m downwind if large spill or fire
Chemical & Response Details
Also known as2,2,4-TrimethylpentaneIsooctaneTrimethylpentaneiso-Octane
CAS Number540-84-1
AppearanceClear, colorless liquid with a gasoline-like odor. Volatile hydrocarbon that evaporates readily at room temperature.
Flash Point-12°C (10°F)
Boiling Point99°C (210°F)
Vapor Density3.9 (heavier than air)
Water ReactivityNo significant reaction; insoluble in water, floats on surface
ExtinguishingAFFF foam, alcohol-resistant foam, CO2, dry chemical, water spray for cooling
PPE⚠️ Level B minimum with chemical-resistant suit; SCBA required in confined spaces or heavy vapor; boots and gloves resistant to hydrocarbons
IsolationERG 128: isolate spill 50m all directions; evacuate 800m downwind if large spill or fire
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
  • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
  • Vapors may form explosive mixtures with air.
  • Vapors may travel to source of ignition and flash back.
  • Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
  • Vapor explosion hazard indoors, outdoors or in sewers.
  • Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
  • Runoff to sewer may create fire or explosion hazard.
  • Containers may explode when heated.
First actions (field-minded)
  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
  • Consider initial downwind evacuation for at least 300 meters (1000 feet).
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UN 1262 — Isooctane
HAZMAT RADIO NOTE — UN 1262 Product: Isooctane Class 3 / Flammable / ERG 128 PPE: Level B minimum with chemical-resistant suit; SCBA required in confined spaces or heavy vapor; boots and gloves resistant to hydrocarbons ISOLATION: ERG 128: isolate spill 50m all directions; evacuate 800m downwind if large spill or fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1262 — Isooctane Class: 3 | Placard: Flammable | ERG Guide: 128 Appearance: Clear, colorless liquid with a gasoline-like odor. Volatile hydrocarbon that evaporates readily at room temperature. Water Reactivity: No significant reaction; insoluble in water, floats on surface Extinguishing: AFFF foam, alcohol-resistant foam, CO2, dry chemical, water spray for cooling PPE: Level B minimum with chemical-resistant suit; SCBA required in confined spaces or heavy vapor; boots and gloves resistant to hydrocarbons Isolation: ERG 128: isolate spill 50m all directions; evacuate 800m downwind if large spill or fire — Key Hazards — • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors may form explosive mixtures with air. • Vapors may travel to source of ignition and flash back. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Ventilate closed spaces before entering, but only if properly trained and equipped. SOURCE: allfirefighter.com/hazmat/un/1262 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN1262 Isooctane Cls3 ERG128 | ERG 128: isolate spill 50m all directions; evacuate 800m downwind if large spill | allfirefighter.com/hazmat/un/1262SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1262
Related UN numbers (same class)
Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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FAQ

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum with chemical-resistant suit; SCBA required in confined spaces or heavy vapor; boots and gloves resistant to hydrocarbons

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 128 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.