☣️ UN 1279 • CLASS 3

UN 1279 — Dichloropropane

Placard: Flammable. ERG Guide 130. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1279 is Dichloropropane, a flammable chlorinated liquid assigned to ERG Guide 130. It presents vapor fire, flashback and toxic fire-product concerns during spills or container fires.

Hazard overview: UN 1279 presents flammable vapor, flashback and chlorinated-solvent hazards. Fire can produce corrosive or toxic decomposition products, and vapors may collect in low or sewer areas where ignition can cause explosion.

Response guidance: For a UN 1279 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 130. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors or runoff out of sewers and use compatible fire-control agents from a protected position.

Firefighter training notes: Training for UN 1279 should emphasize flammable liquid vapor travel, flashback, sewer vapor explosion risk, foam compatibility, container cooling and atmospheric monitoring. Common errors include standing downwind, allowing runoff into drains and ignoring low-area vapor collection. Use ERG 130, SDS and local SOP.

Regulatory context: Dichloropropane is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Dichloropropane should be stored in tightly closed compatible containers in a cool, dry, well-ventilated flammable-liquid storage area. Keep away from heat, sparks, open flames, oxidizers and incompatible materials, with bonding/grounding, secondary containment and drain protection where required.

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UN 1279 Quick Details

UN 1279
Product name: Dichloropropane
DOT Class: 3
Placard type: Flammable
ERG Guide: 130 (check current ERG)
Initial isolation: ERG 130: isolate 50m in all directions initially; for large spills isolate 150m and evacuate 800m downwind if needed

Common Hazards of UN 1279

  • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may collect in low, confined or sewer areas.
  • Liquid or vapor may irritate eyes, skin and respiratory tissue.
  • Fire may produce irritating, corrosive and/or toxic gases.
  • Runoff to sewer may create fire, explosion or environmental hazards.
  • Containers may rupture or explode when heated.
  • Specific chronic toxicity concerns should be verified from SDS.

Chemical Identity & Physical Properties

Colorless liquid with a chloroform-like or sweet odor. Highly volatile at room temperature with penetrating odor detectable at low concentrations.

Also known asPropylene dichlorideDichloropropaneα,β-DichloropropanePDCPropylene chloride
CAS Number78-87-5
AppearanceColorless liquid with a chloroform-like or sweet odor. Highly volatile at room temperature with penetrating odor detectable at low concentrations.
Flash Point16°C (60°F)
Boiling Point96°C (205°F)
Vapor Density3.9 (heavier than air)
Water ReactivityNo significant reaction with water; insoluble and forms separate layer
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1279

Extinguishing Media

Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers.

PPE Requirements

⚠️ Level B minimum with SCBA required; chemical-resistant gloves and suit for liquid contact; avoid all skin contact

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because liquid and vapor can injure tissue.

Isolation & Evacuation

ERG 130: isolate 50m in all directions initially; for large spills isolate 150m and evacuate 800m downwind if needed
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 130).

First Actions for a UN 1279 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Eliminate ignition sources if it is safe to do so.
  • Do not touch or walk through spilled liquid unless properly trained and wearing appropriate protective equipment.
  • Avoid breathing vapors and avoid skin or eye contact with liquid.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or leak area for at least 50 meters (150 feet) in all directions.
  • For large spills, fire involvement or strong vapor movement, expand isolation and consider downwind evacuation based on monitoring and incident command.
  • Use ERG Guide 130, shipping papers, SDS and local SOP for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1279 — Dichloropropane
HAZMAT RADIO NOTE — UN 1279 Product: Dichloropropane Class 3 / Flammable / ERG 130 PPE: Level B minimum with SCBA required; chemical-resistant gloves and suit for liquid contact; avoid all skin contact ISOLATION: ERG 130: isolate 50m in all directions initially; for large spills isolate 150m and evacuate 800m downwind if needed ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1279 — Dichloropropane Class: 3 | Placard: Flammable | ERG Guide: 130 Appearance: Colorless liquid with a chloroform-like or sweet odor. Highly volatile at room temperature with penetrating odor detectable at low concentrations. Water Reactivity: No significant reaction with water; insoluble and forms separate layer Extinguishing: Use AFFF or alcohol-resistant foam where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers. PPE: Level B minimum with SCBA required; chemical-resistant gloves and suit for liquid contact; avoid all skin contact Isolation: ERG 130: isolate 50m in all directions initially; for large spills isolate 150m and evacuate 800m downwind if needed — Key Hazards — • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may collect in low, confined or sewer areas. • Liquid or vapor may irritate eyes, skin and respiratory tissue. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/dichloropropane-un-1279 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1279 Dichloropropane Cls3 ERG130 | allfirefighter.com/hazmat/un/dichloropropane-un-1279SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/dichloropropane-un-1279

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1279

UN 1279 is Dichloropropane, a hazardous material assigned to ERG Guide 130.

Yes. It is flammable and vapors may form explosive mixtures with air.

ERG Guide 130 applies to UN 1279 for initial isolation, protective actions and first response guidance.

UN 1279 presents flammable vapor, flashback and chlorinated-solvent hazards. Fire can produce corrosive or toxic decomposition products, and vapors may collect in low or sewer areas where ignition can cause explosion.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Chemical-resistant gloves, eye/face protection and protective clothing should be selected from SDS because liquid and vapor can injure tissue.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.