☣️ UN 1723 • CLASS 3
UN 1723 — Allyl iodide
Placard: Flammable. ERG Guide 132. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 1723 Quick Details
UN 1723
Product name: Allyl iodide
DOT Class: 3
Placard type: Flammable
ERG Guide: 132 (check current ERG)
Initial isolation: ERG 132: isolate spill 50m all directions; for large spills isolate 150m downwind; evacuate immediate area if fire
Common Hazards of UN 1723
- Flammable/combustible material.
- May be ignited by heat, sparks or flames.
- Vapors may form explosive mixtures with air.
- Vapors may travel to source of ignition and flash back.
- Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
- Vapor explosion hazard indoors, outdoors or in sewers.
- Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
- Runoff to sewer may create fire or explosion hazard.
Chemical Identity & Physical Properties
| Also known as | 3-Iodopropene3-Iodo-1-propeneIodoallylAllyl monoiodide1-Propene, 3-iodo- |
| CAS Number | 556-56-9 |
| Appearance | Colorless to pale yellow liquid with a pungent, acrid odor. Darkens on exposure to light and air. Denser than water. |
| Flash Point | -3C (27F) |
| Boiling Point | 103C (217F) |
| Vapor Density | 5.8 (heavier than air) |
| Water Reactivity | Slightly soluble in water with no significant reaction; hydrolyzes slowly |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 1723
Extinguishing Media
Alcohol-resistant foam, dry chemical, CO2; water spray for cooling
PPE Requirements
⚠️ Level B minimum; SCBA required; chemical-resistant gloves and suit due to lachrymator and skin irritant properties
Isolation & Evacuation
ERG 132: isolate spill 50m all directions; for large spills isolate 150m downwind; evacuate immediate area if fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 132).
First Actions for a UN 1723 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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📋 Copy & Share Field Card
UN 1723 — Allyl iodideHAZMAT RADIO NOTE — UN 1723
Product: Allyl iodide
Class 3 / Flammable / ERG 132
PPE: Level B minimum; SCBA required; chemical-resistant gloves and suit due to lachrymator and skin irritant properties
ISOLATION: ERG 132: isolate spill 50m all directions; for large spills isolate 150m downwind; evacuate immediate area if fire
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 1723 — Allyl iodide
Class: 3 | Placard: Flammable | ERG Guide: 132
Appearance: Colorless to pale yellow liquid with a pungent, acrid odor. Darkens on exposure to light and air. Denser than water.
Water Reactivity: Slightly soluble in water with no significant reaction; hydrolyzes slowly
Extinguishing: Alcohol-resistant foam, dry chemical, CO2; water spray for cooling
PPE: Level B minimum; SCBA required; chemical-resistant gloves and suit due to lachrymator and skin irritant properties
Isolation: ERG 132: isolate spill 50m all directions; for large spills isolate 150m downwind; evacuate immediate area if fire
— Key Hazards —
• Flammable/combustible material.
• May be ignited by heat, sparks or flames.
• Vapors may form explosive mixtures with air.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/1723 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN1723 Allyl iodide Cls3 ERG132 | ERG 132: isolate spill 50m all directions; for large spills isolate 150m downwin | allfirefighter.com/hazmat/un/1723SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/1723
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Frequently Asked Questions about UN 1723
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum; SCBA required; chemical-resistant gloves and suit due to lachrymator and skin irritant properties
Water reactivity: Slightly soluble in water with no significant reaction; hydrolyzes slowly. Recommended extinguishing: Alcohol-resistant foam, dry chemical, CO2; water spray for cooling.
ERG Guide 132 recommendation: ERG 132: isolate spill 50m all directions; for large spills isolate 150m downwind; evacuate immediate area if fire
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 132 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.