☣️ UN 1815 • CLASS 3
Propionyl chloride
Placard: Flammable. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1815
Class: 3
Placard type: Flammable
ERG: Guide 155 (check current ERG)
Isolation: ERG 155: Isolate spill 50m in all directions. For large spills, consider initial evacuation 300m downwind. In fire, isolate 800m and evacuate 1600m downwind.
Chemical & Response Details
| Also known as | Propanoyl chloridePropionic acid chloridePropionic chloridePropionyl chloride |
| CAS Number | 79-03-8 |
| Appearance | Clear to pale yellow liquid with a pungent, acrid odor. Fuming in moist air due to reaction with atmospheric moisture. |
| Flash Point | -12C (10F) |
| Boiling Point | 80C (176F) |
| Vapor Density | 3.2 (heavier than air) |
| Water Reactivity | Reacts violently with water, releasing heat and corrosive hydrochloric acid fumes. Do not use water directly on material. |
| Extinguishing | Dry chemical, CO2, or dry sand. Alcohol-resistant foam may be used at a distance. Avoid direct water application. |
| PPE | ⚠️ Level B minimum with SCBA required. Full face protection and chemical-resistant suit needed due to corrosive vapors and liquid. |
| Isolation | ERG 155: Isolate spill 50m in all directions. For large spills, consider initial evacuation 300m downwind. In fire, isolate 800m and evacuate 1600m downwind. |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
- Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.
- Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
- Vapors may travel to source of ignition and flash back.
- Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
- Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
- Corrosives in contact with metals may evolve flammable hydrogen gas.
- Containers may explode when heated or if contaminated with water.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 1815 — Propionyl chloride HAZMAT RADIO NOTE — UN 1815
Product: Propionyl chloride
Class 3 / Flammable / ERG 155
PPE: Level B minimum with SCBA required. Full face protection and chemical-resistant suit needed due to corrosive vapors and liquid.
ISOLATION: ERG 155: Isolate spill 50m in all directions. For large spills, consider initial evacuation 300m downwind. In fire, isolate 800m and evacuate 1600m downwind.
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 1815 — Propionyl chloride
Class: 3 | Placard: Flammable | ERG Guide: 155
Appearance: Clear to pale yellow liquid with a pungent, acrid odor. Fuming in moist air due to reaction with atmospheric moisture.
Water Reactivity: Reacts violently with water, releasing heat and corrosive hydrochloric acid fumes. Do not use water directly on material.
Extinguishing: Dry chemical, CO2, or dry sand. Alcohol-resistant foam may be used at a distance. Avoid direct water application.
PPE: Level B minimum with SCBA required. Full face protection and chemical-resistant suit needed due to corrosive vapors and liquid.
Isolation: ERG 155: Isolate spill 50m in all directions. For large spills, consider initial evacuation 300m downwind. In fire, isolate 800m and evacuate 1600m downwind.
— Key Hazards —
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
• Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.
• Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/1815 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN1815 Propionyl chloride Cls3 ERG155 | ERG 155: Isolate spill 50m in all directions. For large spills, consider initial | allfirefighter.com/hazmat/un/1815SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1815
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FAQ
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapors may travel to source of ignition and flash back. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Corrosives in contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum with SCBA required. Full face protection and chemical-resistant suit needed due to corrosive vapors and liquid.
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 155 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.