☣️ UN 1914 • CLASS 3

UN 1914 — Butyl propionates

Placard: Flammable. ERG Guide 130. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1914 is Butyl propionates, a Class 3 flammable liquid assigned to ERG Guide 130. Vapors can travel along the ground, flash back and create explosion hazards in drains or confined spaces.

Hazard overview: UN 1914 presents flammable vapor, flashback, sewer vapor explosion, container rupture and toxic smoke hazards. Control ignition sources and keep runoff out of drains.

Response guidance: For a UN 1914 incident, responders should verify the product with shipping papers, package markings, SDS and ERG Guide 130. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff or vapor spread and choose entry/fire-control actions based on monitoring, SDS and local SOP.

Firefighter training notes: Training for UN 1914 should emphasize vapor travel, flashback, sewer explosion, foam selection, container cooling, ignition control and toxic exposure where applicable. Use ERG 130, SDS and local SOP.

Regulatory context: Butyl propionates is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Butyl propionates should be stored in approved flammable/toxic-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

Advertisement

UN 1914 Quick Details

UN 1914
Product name: Butyl propionates
DOT Class: 3
Placard type: Flammable
ERG Guide: 130 (check current ERG)
Initial isolation: ERG 130: Isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation for 800m

Common Hazards of UN 1914

  • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
  • Runoff to sewers may create fire or explosion hazards.
  • Containers may rupture or explode when heated.
  • Fire may produce irritating and/or toxic smoke.
  • Specific toxicity and solvent hazards should be confirmed from SDS.

Chemical Identity & Physical Properties

Colorless liquid with a fruity, apple-like odor. Liquid at room temperature with low viscosity.

Also known asn-Butyl propanoateButyl propanoatePropanoic acid butyl esterPropionic acid n-butyl ester
CAS Number590-01-2
AppearanceColorless liquid with a fruity, apple-like odor. Liquid at room temperature with low viscosity.
Flash Point32°C (90°F)
Boiling Point146°C (295°F)
Vapor Density4.5 (heavier than air)
Water ReactivityNo significant reaction; insoluble in water, floats on surface
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1914

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid.

PPE Requirements

⚠️ Level B minimum with SCBA; chemical-resistant gloves and suit recommended for spill response

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Isolation & Evacuation

ERG 130: Isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation for 800m
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 130).

First Actions for a UN 1914 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, fumes, dust, mist, smoke or gas and avoid skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers and low areas.
  • Do not touch or walk through spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or leak area and expand the perimeter if vapor, dust, fire involvement, gas accumulation or unknown concentration is present.
  • Use ERG Guide 130, shipping papers, SDS, air monitoring and incident command for protective actions.
Advertisement

📋 Copy & Share Field Card

UN 1914 — Butyl propionates
HAZMAT RADIO NOTE — UN 1914 Product: Butyl propionates Class 3 / Flammable / ERG 130 PPE: Level B minimum with SCBA; chemical-resistant gloves and suit recommended for spill response ISOLATION: ERG 130: Isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation for 800m ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1914 — Butyl propionates Class: 3 | Placard: Flammable | ERG Guide: 130 Appearance: Colorless liquid with a fruity, apple-like odor. Liquid at room temperature with low viscosity. Water Reactivity: No significant reaction; insoluble in water, floats on surface Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid. PPE: Level B minimum with SCBA; chemical-resistant gloves and suit recommended for spill response Isolation: ERG 130: Isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation for 800m — Key Hazards — • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources and flash back. • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, fumes, dust, mist, smoke or gas and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/butyl-propionates-un-1914 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1914 Butyl propionates Cls3 ERG130 | allfirefighter.com/hazmat/un/butyl-propionates-un-1914SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/butyl-propionates-un-1914

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 1914

UN 1914 is Butyl propionates, a hazardous material assigned to ERG Guide 130.

Yes. It is a flammable liquid and vapors may form explosive mixtures with air.

ERG Guide 130 applies to UN 1914 for initial isolation, protective actions and first response guidance.

UN 1914 presents flammable vapor, flashback, sewer vapor explosion, container rupture and toxic smoke hazards. Control ignition sources and keep runoff out of drains.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Heavy flammable vapors can travel through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.