☣️ UN 1941 • CLASS 9

Dibromodifluoromethane

Placard: Miscellaneous. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1941
Class: 9
Placard type: Miscellaneous
ERG: Guide 171 (check current ERG)
Isolation: ERG 171: isolate spill/leak area 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions
Chemical & Response Details
Also known asHalon 1202Freon 12-B2DifluorodibromomethaneCBr2F2R-12B2
CAS Number75-61-6
AppearanceColorless liquid with a faint, ether-like odor. Denser than water and non-flammable under normal conditions.
Flash PointNot applicable (non-flammable)
Boiling Point23°C (73°F)
Vapor Density6.8 (much heavier than air)
Water ReactivityNo significant reaction with water; slightly soluble
ExtinguishingDry chemical, CO2, water spray for cooling containers
PPE⚠️ Level B minimum in spill situations; SCBA if confined space or high vapor concentrations; thermal gloves if handling cold liquid
IsolationERG 171: isolate spill/leak area 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
  • Some may burn but none ignite readily.
  • Containers may explode when heated.
  • Some may be transported hot.
  • For UN3508, Capacitor, asymmetric, be aware of possible short circuiting as this product is transported
  • Polymeric beads, expandable (UN2211) may evolve flammable vapours.
  • Inhalation of material may be harmful.
  • Contact may cause burns to skin and eyes.
  • Inhalation of Asbestos dust may have a damaging effect on the lungs.
First actions (field-minded)
  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
  • For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
  • For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 1941 — Dibromodifluoromethane
HAZMAT RADIO NOTE — UN 1941 Product: Dibromodifluoromethane Class 9 / Miscellaneous / ERG 171 PPE: Level B minimum in spill situations; SCBA if confined space or high vapor concentrations; thermal gloves if handling cold liquid ISOLATION: ERG 171: isolate spill/leak area 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1941 — Dibromodifluoromethane Class: 9 | Placard: Miscellaneous | ERG Guide: 171 Appearance: Colorless liquid with a faint, ether-like odor. Denser than water and non-flammable under normal conditions. Water Reactivity: No significant reaction with water; slightly soluble Extinguishing: Dry chemical, CO2, water spray for cooling containers PPE: Level B minimum in spill situations; SCBA if confined space or high vapor concentrations; thermal gloves if handling cold liquid Isolation: ERG 171: isolate spill/leak area 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions — Key Hazards — • Some may burn but none ignite readily. • Containers may explode when heated. • Some may be transported hot. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters SOURCE: allfirefighter.com/hazmat/un/1941 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN1941 Dibromodifluoromethane Cls9 ERG171 | ERG 171: isolate spill/leak area 50m in all directions; if tank/rail car involve | allfirefighter.com/hazmat/un/1941SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1941
Related UN numbers (same class)
Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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FAQ

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, Capacitor, asymmetric, be aware of possible short circuiting as this product is transported Polymeric beads, expandable (UN2211) may evolve flammable vapours. Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum in spill situations; SCBA if confined space or high vapor concentrations; thermal gloves if handling cold liquid

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 171 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.