☣️ UN 3065 • CLASS 3
UN 3065 — Alcoholic beverages
Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 3065 Quick Details
UN 3065
Product name: Alcoholic beverages
DOT Class: 3
Placard type: Flammable
ERG Guide: 127 (check current ERG)
Initial isolation: ERG 127: Small spills isolate 25m; large spills isolate 50m initial, evacuate 300m downwind if fire
Common Hazards of UN 3065
- HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
- Vapors may form explosive mixtures with air.
- Vapors may travel to source of ignition and flash back.
- Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
- Vapor explosion hazard indoors, outdoors or in sewers.
- Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
- Runoff to sewer may create fire or explosion hazard.
- Containers may explode when heated.
Chemical Identity & Physical Properties
| Also known as | EthanolEthyl alcoholGrain alcoholSpiritsLiquorWineBeer |
| CAS Number | 64-17-5 |
| Appearance | Clear to amber liquid with characteristic alcoholic odor. Varies in ethanol concentration typically from 3-95% by volume depending on beverage type. |
| Flash Point | 13C (55F) for typical spirits; varies with ethanol content |
| Boiling Point | 78C (172F) for pure ethanol; varies with water content |
| Vapor Density | 1.6 (heavier than air) |
| Water Reactivity | Completely miscible with water, no significant reaction |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Fireground Response Guidance — UN 3065
Extinguishing Media
AFFF foam, alcohol-resistant foam, CO2, dry chemical
PPE Requirements
⚠️ Level D for routine handling; Level B with SCBA for large spills or fires
Isolation & Evacuation
ERG 127: Small spills isolate 25m; large spills isolate 50m initial, evacuate 300m downwind if fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 127).
First Actions for a UN 3065 Incident
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
- Consider initial downwind evacuation for at least 300 meters (1000 feet).
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📋 Copy & Share Field Card
UN 3065 — Alcoholic beveragesHAZMAT RADIO NOTE — UN 3065
Product: Alcoholic beverages
Class 3 / Flammable / ERG 127
PPE: Level D for routine handling; Level B with SCBA for large spills or fires
ISOLATION: ERG 127: Small spills isolate 25m; large spills isolate 50m initial, evacuate 300m downwind if fire
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3065 — Alcoholic beverages
Class: 3 | Placard: Flammable | ERG Guide: 127
Appearance: Clear to amber liquid with characteristic alcoholic odor. Varies in ethanol concentration typically from 3-95% by volume depending on beverage type.
Water Reactivity: Completely miscible with water, no significant reaction
Extinguishing: AFFF foam, alcohol-resistant foam, CO2, dry chemical
PPE: Level D for routine handling; Level B with SCBA for large spills or fires
Isolation: ERG 127: Small spills isolate 25m; large spills isolate 50m initial, evacuate 300m downwind if fire
— Key Hazards —
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
• Vapors may form explosive mixtures with air.
• Vapors may travel to source of ignition and flash back.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/3065 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3065 Alcoholic beverages Cls3 ERG127 | ERG 127: Small spills isolate 25m; large spills isolate 50m initial, evacuate 30 | allfirefighter.com/hazmat/un/3065SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions.
Page: https://allfirefighter.com/hazmat/un/3065
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Frequently Asked Questions about UN 3065
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas Vapor explosion hazard indoors, outdoors or in sewers. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level D for routine handling; Level B with SCBA for large spills or fires
Water reactivity: Completely miscible with water, no significant reaction. Recommended extinguishing: AFFF foam, alcohol-resistant foam, CO2, dry chemical.
ERG Guide 127 recommendation: ERG 127: Small spills isolate 25m; large spills isolate 50m initial, evacuate 300m downwind if fire
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 127 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles.
This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.