☣️ UN 3083 • CLASS 2
Perchloryl fluoride
Placard: Toxic Gas. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 3083
Class: 2
Placard type: Toxic Gas
ERG: Guide 124 (check current ERG)
Isolation: ERG 124: initial isolate 100m all directions; protective action distance 0.3 km day / 0.8 km night for small spills, 1.1 km day / 3.2 km night for large spills
Chemical & Response Details
| Also known as | Chlorine oxyfluoridePerchlorofluorideChlorine fluoride oxideTrioxychlorofluoride |
| CAS Number | 7616-94-6 |
| Appearance | Colorless gas with a characteristic sweet odor. Shipped as a liquefied compressed gas under pressure. |
| Flash Point | Not applicable (nonflammable gas) |
| Boiling Point | -46.8C (-52.2F) |
| Vapor Density | 3.6 (heavier than air) |
| Water Reactivity | Hydrolyzes slowly in water forming hydrofluoric and perchloric acids; corrosive products |
| Extinguishing | Nonflammable; use water spray to reduce vapors, do not direct water at source |
| PPE | ⚠️ Level A minimum for initial response; full chemical protective suit with SCBA required; material is highly toxic by inhalation |
| Isolation | ERG 124: initial isolate 100m all directions; protective action distance 0.3 km day / 0.8 km night for small spills, 1.1 km day / 3.2 km night for large spills |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- TOXIC and/or CORROSIVE; may be fatal if inhaled or absorbed through skin.
- Fire will produce irritating, corrosive and/or toxic gases.
- Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
- Runoff from fire control or dilution water may cause environmental contamination.
- Substance does not burn but will support combustion.
- Vapors from liquefied gas are initially heavier than air and spread along ground.
- These are strong oxidizers and will react vigorously or explosively with many materials including fuels.
- May ignite combustibles (wood, paper, oil, clothing, etc.).
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Many gases are heavier than air and will spread along the ground and collect in low or confined areas
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
- See Table 1 - Initial Isolation and Protective Action Distances.
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UN 3083 — Perchloryl fluoride HAZMAT RADIO NOTE — UN 3083
Product: Perchloryl fluoride
Class 2 / Toxic Gas / ERG 124
PPE: Level A minimum for initial response; full chemical protective suit with SCBA required; material is highly toxic by inhalation
ISOLATION: ERG 124: initial isolate 100m all directions; protective action distance 0.3 km day / 0.8 km night for small spills, 1.1 km day / 3.2 km night for large spills
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3083 — Perchloryl fluoride
Class: 2 | Placard: Toxic Gas | ERG Guide: 124
Appearance: Colorless gas with a characteristic sweet odor. Shipped as a liquefied compressed gas under pressure.
Water Reactivity: Hydrolyzes slowly in water forming hydrofluoric and perchloric acids; corrosive products
Extinguishing: Nonflammable; use water spray to reduce vapors, do not direct water at source
PPE: Level A minimum for initial response; full chemical protective suit with SCBA required; material is highly toxic by inhalation
Isolation: ERG 124: initial isolate 100m all directions; protective action distance 0.3 km day / 0.8 km night for small spills, 1.1 km day / 3.2 km night for large spills
— Key Hazards —
• TOXIC and/or CORROSIVE; may be fatal if inhaled or absorbed through skin.
• Fire will produce irritating, corrosive and/or toxic gases.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Many gases are heavier than air and will spread along the ground and collect in low or confined areas
SOURCE: allfirefighter.com/hazmat/un/3083 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3083 Perchloryl fluoride Cls2 ERG124 | ERG 124: initial isolate 100m all directions; protective action distance 0.3 km | allfirefighter.com/hazmat/un/3083SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3083
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FAQ
TOXIC and/or CORROSIVE; may be fatal if inhaled or absorbed through skin. Fire will produce irritating, corrosive and/or toxic gases. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Runoff from fire control or dilution water may cause environmental contamination. Substance does not burn but will support combustion. Vapors from liquefied gas are initially heavier than air and spread along ground. These are strong oxidizers and will react vigorously or explosively with many materials including fuels. May ignite combustibles (wood, paper, oil, clothing, etc.).
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level A minimum for initial response; full chemical protective suit with SCBA required; material is highly toxic by inhalation
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 124 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.