☣️ UN 1013 • CLASS 2

UN 1013 — Carbon dioxide, compressed

Placard: Non-Flammable Gas. ERG Guide 120. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Carbon dioxide, compressed, is a colorless, odorless gas at room temperature, classified as a compressed gas under the DOT class 2. It is widely used in industrial processes, food and beverage production, and medical applications. First responders may encounter carbon dioxide, compressed, in various scenarios, including transportation accidents, industrial leaks, or medical emergencies. The scale of production and transport of carbon dioxide, compressed, is significant, with millions of tons being produced and transported annually. As a result, first responders must be prepared to handle emergencies involving this substance. Carbon dioxide, compressed, is a critical component in many industrial processes, and its release can have significant consequences. The widespread use of carbon dioxide, compressed, in various industries increases the likelihood of first responders encountering it during emergency situations.

Hazard overview: Carbon dioxide vapors can cause dizziness or asphyxiation without warning, and the gas can spread along the ground, making it a hazardous substance in confined areas. Prolonged exposure to high concentrations can also cause respiratory problems.

Response guidance: In the event of a spill or leak, first responders should ensure adequate ventilation and treat the area as a simple asphyxiant in confined spaces. The correct suppression agent for carbon dioxide, compressed, is not applicable, as the substance is non-flammable. However, ventilation can be used to disperse the gas, and combustible materials should be avoided. Decontamination procedures should be followed, and CHEMTREC should be contacted in the event of a spill or leak. First responders should also be aware of the potential for carbon dioxide, compressed, to accumulate in low-lying areas or confined spaces, increasing the risk of asphyxiation.

Firefighter training notes: First responders should receive training on the hazards associated with carbon dioxide, compressed, including its ability to displace oxygen and cause asphyxiation. A known tactical error for this chemical class is the failure to recognize the potential for carbon dioxide, compressed, to accumulate in low-lying areas or confined spaces, increasing the risk of asphyxiation. ICS position needs and mutual aid criteria should also be established to ensure a coordinated response to emergencies involving carbon dioxide, compressed. First responders should be aware of the potential for carbon dioxide, compressed, to be involved in a wide range of emergency scenarios, from industrial accidents to medical emergencies.

Regulatory context: Carbon dioxide, compressed, is classified as a DOT class 2 substance, with a packing group not applicable. The OSHA PEL/TLV for carbon dioxide, compressed, is 5,000 ppm (0.5%) as an 8-hour TWA, and the substance is subject to various regulations and guidelines, including those related to transportation, storage, and handling. First responders should be aware of the regulatory requirements for carbon dioxide, compressed, and follow established procedures for handling and responding to emergencies involving this substance.

Storage & handling: Carbon dioxide, compressed, should be stored in a well-ventilated area, away from incompatible materials such as heat sources or ignition sources. The temperature limit for storage is not established, but the substance should be kept away from heat sources or ignition sources. The top 3 incompatible materials for carbon dioxide, compressed, are heat sources, ignition sources, and oxidizable materials. The ventilation standard for storage is to provide adequate ventilation to prevent the accumulation of carbon dioxide, compressed, in low-lying areas or confined spaces.

Advertisement

UN 1013 Quick Details

UN 1013
Product name: Carbon dioxide, compressed
DOT Class: 2
Placard type: Non-Flammable Gas
ERG Guide: 120 (check current ERG)
Initial isolation: ERG 120: No evacuation distances listed for non-fire scenarios; ensure adequate ventilation; treat as simple asphyxiant in confined spaces

Common Hazards of UN 1013

  • Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.
  • Vapors from liquefied gas are initially heavier than air and spread along ground.
  • Contact with gas, liquefied gas or cryogenic liquids may cause burns, severe injury and/or frostbite.
  • Non-flammable gases.
  • Containers may explode when heated.
  • Ruptured cylinders may rocket.

Chemical Identity & Physical Properties

Carbon dioxide, compressed, is a colorless, odorless gas at room temperature, with a boiling point of -78.5C (-109.3F) at atmospheric pressure and a vapor density of 1.5, which is heavier than air. The substance is shipped as a liquefied compressed gas and has a specific gravity of approximately 1.5, which is heavier than air. The physical properties of carbon dioxide, compressed, make it a significant hazard in the presence of confined spaces or inadequate ventilation.

Also known asCO2carbonic acid gascarbonic anhydridedry ice (solid form)
CAS Number124-38-9
AppearanceColorless, odorless gas at room temperature. Shipped as a liquefied compressed gas. Heavier than air. Solid form (dry ice) sublimes directly to gas.
Flash PointNot applicable (non-flammable gas)
Boiling Point-78.5C (-109.3F) at atmospheric pressure (sublimes)
Vapor Density1.5 (heavier than air)
Water ReactivityNo significant reaction with water; dissolves slightly to form weak carbonic acid
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1013

Extinguishing Media

Not applicable (non-flammable; use ventilation to disperse gas)

PPE Requirements

⚠️ Level D for routine handling; SCBA required in confined spaces or high concentration areas due to asphyxiation risk; insulated gloves for liquefied or solid CO2 to prevent frostbite

The recommended PPE level for carbon dioxide, compressed, is Level D for routine handling, with SCBA required in confined spaces or high concentration areas due to asphyxiation risk. Insulated gloves are also recommended for liquefied or solid carbon dioxide to prevent frostbite. The rationale for this PPE level is to protect first responders from the potential hazards associated with carbon dioxide, compressed, including the risk of asphyxiation and frostbite.

Isolation & Evacuation

ERG 120: No evacuation distances listed for non-fire scenarios; ensure adequate ventilation; treat as simple asphyxiant in confined spaces
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 120).

First Actions for a UN 1013 Incident

  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
  • Consider initial downwind evacuation for at least 100 meters (330 feet).
Advertisement

📋 Copy & Share Field Card

UN 1013 — Carbon dioxide, compressed
HAZMAT RADIO NOTE — UN 1013 Product: Carbon dioxide, compressed Class 2 / Non-Flammable Gas / ERG 120 PPE: Level D for routine handling; SCBA required in confined spaces or high concentration areas due to asphyxiation risk; insulated gloves for liquefied or solid CO2 to prevent frostbite ISOLATION: ERG 120: No evacuation distances listed for non-fire scenarios; ensure adequate ventilation; treat as simple asphyxiant in confined spaces ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1013 — Carbon dioxide, compressed Class: 2 | Placard: Non-Flammable Gas | ERG Guide: 120 Appearance: Colorless, odorless gas at room temperature. Shipped as a liquefied compressed gas. Heavier than air. Solid form (dry ice) sublimes directly to gas. Water Reactivity: No significant reaction with water; dissolves slightly to form weak carbonic acid Extinguishing: Not applicable (non-flammable; use ventilation to disperse gas) PPE: Level D for routine handling; SCBA required in confined spaces or high concentration areas due to asphyxiation risk; insulated gloves for liquefied or solid CO2 to prevent frostbite Isolation: ERG 120: No evacuation distances listed for non-fire scenarios; ensure adequate ventilation; treat as simple asphyxiant in confined spaces — Key Hazards — • Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas. • Vapors from liquefied gas are initially heavier than air and spread along ground. • Contact with gas, liquefied gas or cryogenic liquids may cause burns, severe injury and/or frostbite. — First Actions — • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Ventilate closed spaces before entering, but only if properly trained and equipped. • Isolate spill or leak area for at least 100 meters (330 feet) in all directions. SOURCE: allfirefighter.com/hazmat/un/1013 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1013 Carbon dioxide, compressed Cls2 ERG120 | allfirefighter.com/hazmat/un/1013SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/carbon-dioxide-compressed-un-1013

Related UN Numbers in Class 2

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 1013

No, UN 1013 carbon dioxide, compressed, is not flammable. The substance is a non-flammable gas, but containers may explode when heated.

The recommended PPE level for UN 1013 carbon dioxide, compressed, is Level D for routine handling, with SCBA required in confined spaces or high concentration areas due to asphyxiation risk. Insulated gloves are also recommended for liquefied or solid carbon dioxide to prevent frostbite.

UN 1013 carbon dioxide, compressed, can cause dizziness or asphyxiation without warning, especially when in closed or confined areas. Prolonged exposure to high concentrations of carbon dioxide, compressed, can lead to respiratory problems and other health effects.

UN 1013 carbon dioxide, compressed, is a colorless, odorless gas at room temperature. The substance is shipped as a liquefied compressed gas and has a solid form (dry ice) that sublimes directly to gas.

No extinguishing agents are needed for UN 1013 carbon dioxide, compressed, as the substance is non-flammable. However, ventilation can be used to disperse the gas, and combustible materials should be avoided.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.