☣️ UN 3152 • CLASS 9
Halogenated monomethyldiphenylmethanes, solid
Placard: Miscellaneous. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 3152
Class: 9
Placard type: Miscellaneous
ERG: Guide 171 (check current ERG)
Isolation: ERG 171: isolate spill area immediately for at least 25m in all directions; if fire, isolate 800m in all directions and consider initial evacuation for 300m
Chemical & Response Details
| Also known as | Halogenated diphenylmethanesChlorinated diphenylmethanesBrominated diphenylmethanesHalogenated benzhydryl compounds |
| Appearance | Solid material, typically white to off-white or pale yellow crystalline powder or granules. May be odorless or have a faint aromatic odor at room temperature. |
| Flash Point | Greater than 93C (200F) - combustible solid |
| Boiling Point | Not applicable (solid, decomposes before boiling) |
| Vapor Density | Not applicable (solid with negligible vapor pressure at room temperature) |
| Water Reactivity | No significant reaction with water; insoluble in water |
| Extinguishing | Dry chemical, CO2, water spray for cooling containers, foam suitable for Class B fires |
| PPE | ⚠️ Level C minimum for handling; Level B with SCBA if heated or involved in fire; heat-resistant gloves if material transported hot |
| Isolation | ERG 171: isolate spill area immediately for at least 25m in all directions; if fire, isolate 800m in all directions and consider initial evacuation for 300m |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- Some may burn but none ignite readily.
- Containers may explode when heated.
- Some may be transported hot.
- For UN3508, Capacitor, asymmetric, be aware of possible short circuiting as this product is transported
- Polymeric beads, expandable (UN2211) may evolve flammable vapours.
- Inhalation of material may be harmful.
- Contact may cause burns to skin and eyes.
- Inhalation of Asbestos dust may have a damaging effect on the lungs.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 3152 — Halogenated monomethyldiphenylmethanes, HAZMAT RADIO NOTE — UN 3152
Product: Halogenated monomethyldiphenylmethanes, solid
Class 9 / Miscellaneous / ERG 171
PPE: Level C minimum for handling; Level B with SCBA if heated or involved in fire; heat-resistant gloves if material transported hot
ISOLATION: ERG 171: isolate spill area immediately for at least 25m in all directions; if fire, isolate 800m in all directions and consider initial evacuation for 300m
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 3152 — Halogenated monomethyldiphenylmethanes, solid
Class: 9 | Placard: Miscellaneous | ERG Guide: 171
Appearance: Solid material, typically white to off-white or pale yellow crystalline powder or granules. May be odorless or have a faint aromatic odor at room temperature.
Water Reactivity: No significant reaction with water; insoluble in water
Extinguishing: Dry chemical, CO2, water spray for cooling containers, foam suitable for Class B fires
PPE: Level C minimum for handling; Level B with SCBA if heated or involved in fire; heat-resistant gloves if material transported hot
Isolation: ERG 171: isolate spill area immediately for at least 25m in all directions; if fire, isolate 800m in all directions and consider initial evacuation for 300m
— Key Hazards —
• Some may burn but none ignite readily.
• Containers may explode when heated.
• Some may be transported hot.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
SOURCE: allfirefighter.com/hazmat/un/3152 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN3152 Halogenated monomethyldiphenylmethanes, solid Cls9 ERG171 | allfirefighter.com/hazmat/un/3152SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3152
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FAQ
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, Capacitor, asymmetric, be aware of possible short circuiting as this product is transported Polymeric beads, expandable (UN2211) may evolve flammable vapours. Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level C minimum for handling; Level B with SCBA if heated or involved in fire; heat-resistant gloves if material transported hot
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 171 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.