☣️ UN 3159 • CLASS 2

1,1,1,2-Tetrafluoroethane

Placard: Non-Flammable Gas. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 3159
Class: 2
Placard type: Non-Flammable Gas
ERG: Guide 126 (check current ERG)
Isolation: ERG 126: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m all directions
Chemical & Response Details
Also known asR-134aHFC-134aNorfluraneFreon 134a1,1,1,2-Tetrafluoroethane
CAS Number811-97-2
AppearanceColorless, odorless liquefied gas. Shipped as a liquefied compressed gas under its own vapor pressure.
Flash PointNot applicable (non-flammable gas)
Boiling Point-26C (-15F)
Vapor Density3.6 (heavier than air)
Water ReactivityNo significant reaction; low water solubility
ExtinguishingNot applicable (non-flammable); ventilate area, water spray to disperse vapors
PPE⚠️ Level B minimum; SCBA if confined space or leak; insulated gloves for liquefied gas exposure
IsolationERG 126: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m all directions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
  • Some may burn but none ignite readily.
  • Containers may explode when heated.
  • Ruptured cylinders may rocket.
  • Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.
  • Vapors from liquefied gas are initially heavier than air and spread along ground.
  • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
  • Fire may produce irritating, corrosive and/or toxic gases.
First actions (field-minded)
  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Many gases are heavier than air and will spread along the ground and collect in low or confined areas
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
  • Consider initial downwind evacuation for at least 500 meters (1/3 mile).
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UN 3159 — 1,1,1,2-Tetrafluoroethane
HAZMAT RADIO NOTE — UN 3159 Product: 1,1,1,2-Tetrafluoroethane Class 2 / Non-Flammable Gas / ERG 126 PPE: Level B minimum; SCBA if confined space or leak; insulated gloves for liquefied gas exposure ISOLATION: ERG 126: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3159 — 1,1,1,2-Tetrafluoroethane Class: 2 | Placard: Non-Flammable Gas | ERG Guide: 126 Appearance: Colorless, odorless liquefied gas. Shipped as a liquefied compressed gas under its own vapor pressure. Water Reactivity: No significant reaction; low water solubility Extinguishing: Not applicable (non-flammable); ventilate area, water spray to disperse vapors PPE: Level B minimum; SCBA if confined space or leak; insulated gloves for liquefied gas exposure Isolation: ERG 126: isolate 100m all directions; if tank/rail car involved in fire, isolate 800m all directions — Key Hazards — • Some may burn but none ignite readily. • Containers may explode when heated. • Ruptured cylinders may rocket. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Many gases are heavier than air and will spread along the ground and collect in low or confined areas SOURCE: allfirefighter.com/hazmat/un/3159 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN3159 1,1,1,2-Tetrafluoroethane Cls2 ERG126 | allfirefighter.com/hazmat/un/3159SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3159
Related UN numbers (same class)
Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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FAQ

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket. Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum; SCBA if confined space or leak; insulated gloves for liquefied gas exposure

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 126 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.