☣️ UN 3515 • CLASS 2

UN 3515 — Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A)

Placard: Toxic Gas. ERG Guide 173. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3515 is Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A), a Zone A toxic oxidizing adsorbed gas entry assigned to ERG Guide 173. Exact gas identity controls isolation and compatibility.

Hazard overview: Adsorbed gas package containing toxic oxidizing gas; release may create an immediate inhalation hazard. Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations. Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas.

Response guidance: For UN 3515, isolate downwind/low areas, treat as a life-threatening gas release and use Level A/SCBA for entry. Verify exact gas with shipping papers and ERG 173.

Firefighter training notes: Training for UN 3515 should emphasize toxic-gas recognition, Zone A isolation, Level A/SCBA entry, air monitoring, source-control limits and decontamination. Use ERG 173, SDS and local SOP.

Regulatory context: Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, package type, gas identity and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) should be stored in secured compatible adsorbed-gas packages away from heat, impact, corrosion, moisture where incompatible and unauthorized access, with ventilation and emergency planning.

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UN 3515 Quick Details

UN 3515
Product name: Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A)
DOT Class: 2
Placard type: Toxic Gas
ERG Guide: 173 (check current ERG)
Initial isolation: ERG 173: Initial isolation 100m in all directions; protective action distance 800m downwind (day), 2200m downwind (night); evacuate area immediately if leak or fire

Common Hazards of UN 3515

  • Adsorbed gas package containing toxic oxidizing gas; release may create an immediate inhalation hazard.
  • Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations.
  • Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas.
  • Released gas behavior, odor warning and vapor density depend on the exact gas identity.
  • Oxidizing gas may ignite or greatly intensify combustibles, oils, greases or reducing agents.
  • Water or moisture may form toxic/corrosive products depending on the gas.
  • Runoff or vapor-control water may become toxic and oxidizing.
  • Containers exposed to fire may vent, rupture or release toxic gas.

Chemical Identity & Physical Properties

This is a generic entry for various toxic oxidizing gases adsorbed onto solid porous materials such as activated carbon or molecular sieves. The physical appearance depends on the specific gas and adsorbent used, typically appearing as cylinders or containers filled with granular solid material containing the adsorbed gas.

Also known asAdsorbed toxic gas, oxidizing, n.o.s.Poisonous oxidizing gas adsorbedToxic oxidizing gas on solid adsorbentHazard Zone A oxidizing toxic gas
AppearanceThis is a generic entry for various toxic oxidizing gases adsorbed onto solid porous materials such as activated carbon or molecular sieves. The physical appearance depends on the specific gas and adsorbent used, typically appearing as cylinders or containers filled with granular solid material containing the adsorbed gas.
Flash PointNot applicable (oxidizing gas)
Boiling PointNot applicable (adsorbed gas on solid substrate)
Vapor DensityVaries by specific gas; typically heavier than air when released
Water ReactivityMay react with water depending on specific gas; oxidizing properties may intensify reactions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3515

Extinguishing Media

Use agents for surrounding fire and cool containers from protection if safe. Avoid direct water on reactive gases; contain vapor-control water as toxic/corrosive.

PPE Requirements

⚠️ Level A required for Zone A materials; fully encapsulating suit with SCBA; chemical-resistant gloves and boots; positive pressure respiratory protection mandatory

Use Level A fully encapsulating chemical protective clothing with positive-pressure SCBA for entry. Zone A toxic gas requires maximum respiratory and skin protection.

Isolation & Evacuation

ERG 173: Initial isolation 100m in all directions; protective action distance 800m downwind (day), 2200m downwind (night); evacuate area immediately if leak or fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 173).

First Actions for a UN 3515 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind and avoid low or poorly ventilated areas unless monitoring shows they are safe.
  • Treat the release as a life-threatening inhalation hazard until the gas is identified and monitored.
  • Keep fuels, oils, greases, combustibles and reducing agents away from oxidizing gas.
  • Do not handle leaking cylinders, adsorbed-gas packages or damaged gas articles without proper training and PPE.
  • Ventilate only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 173, shipping papers, markings and air monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 3515 — Adsorbed gas, poisonous, oxidizing, n.o.
HAZMAT RADIO NOTE — UN 3515 Product: Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) Class 2 / Toxic Gas / ERG 173 PPE: Level A required for Zone A materials; fully encapsulating suit with SCBA; chemical-resistant gloves and boots; positive pressure respiratory protection mandatory ISOLATION: ERG 173: Initial isolation 100m in all directions; protective action distance 800m downwind (day), 2200m downwind (night); evacuate area immediately if leak or fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3515 — Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) Class: 2 | Placard: Toxic Gas | ERG Guide: 173 Appearance: This is a generic entry for various toxic oxidizing gases adsorbed onto solid porous materials such as activated carbon or molecular sieves. The physical appearance depends on the specific gas and adsorbent used, typically appearing as cylinders or containers filled with granular solid material containing the adsorbed gas. Water Reactivity: May react with water depending on specific gas; oxidizing properties may intensify reactions Extinguishing: Use agents for surrounding fire and cool containers from protection if safe. Avoid direct water on reactive gases; contain vapor-control water as toxic/corrosive. PPE: Level A required for Zone A materials; fully encapsulating suit with SCBA; chemical-resistant gloves and boots; positive pressure respiratory protection mandatory Isolation: ERG 173: Initial isolation 100m in all directions; protective action distance 800m downwind (day), 2200m downwind (night); evacuate area immediately if leak or fire — Key Hazards — • Adsorbed gas package containing toxic oxidizing gas; release may create an immediate inhalation hazard. • Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations. • Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind and avoid low or poorly ventilated areas unless monitoring shows they are safe. • Treat the release as a life-threatening inhalation hazard until the gas is identified and monitored. SOURCE: allfirefighter.com/hazmat/un/adsorbed-gas-poisonous-oxidizing-un-3515 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3515 Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A) Cls2 ERG173 | allfirefighter.com/hazmat/un/adsorbed-gas-poisonous-oxidizing-un-3515SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/adsorbed-gas-poisonous-oxidizing-un-3515

Related UN Numbers in Class 2

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3515

UN 3515 is Adsorbed gas, poisonous, oxidizing, n.o.s. (Inhalation Hazard Zone A), assigned to ERG Guide 173.

It is not the fuel, but oxidizing properties can intensify fire involving combustibles.

Adsorbed gas package containing toxic oxidizing gas; release may create an immediate inhalation hazard. Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations. Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas.

Use Level A fully encapsulating chemical protective clothing with positive-pressure SCBA for entry. Zone A toxic gas requires maximum respiratory and skin protection.

Use agents for surrounding fire and cool containers from protection if safe. Avoid direct water on reactive gases; contain vapor-control water as toxic/corrosive.

Adsorption reduces free gas under normal transport, but package damage, heating or valve failure can release toxic gas.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.