☣️ UN 3517 • CLASS 2

UN 3517 — Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A)

Placard: Toxic Gas. ERG Guide 173. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3517 is Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A), a Zone A toxic flammable corrosive adsorbed gas entry assigned to ERG Guide 173. Flashback and inhalation lethality drive response.

Hazard overview: Adsorbed gas package containing toxic flammable corrosive gas; release may create an immediate inhalation hazard. Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations. Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas.

Response guidance: For UN 3517, isolate downwind/low areas, treat as a life-threatening gas release and use Level A/SCBA for entry. Verify exact gas with shipping papers and ERG 173.

Firefighter training notes: Training for UN 3517 should emphasize toxic-gas recognition, Zone A isolation, Level A/SCBA entry, air monitoring, source-control limits and decontamination. Use ERG 173, SDS and local SOP.

Regulatory context: Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, package type, gas identity and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) should be stored in secured compatible adsorbed-gas packages away from heat, impact, corrosion, moisture where incompatible and unauthorized access, with ventilation and emergency planning.

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UN 3517 Quick Details

UN 3517
Product name: Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A)
DOT Class: 2
Placard type: Toxic Gas
ERG Guide: 173 (check current ERG)
Initial isolation: ERG 173: Initial isolation 200m all directions; protective action distance 3.7km daytime, 8.0km nighttime for large spills; immediate evacuation of spill area

Common Hazards of UN 3517

  • Adsorbed gas package containing toxic flammable corrosive gas; release may create an immediate inhalation hazard.
  • Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations.
  • Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas.
  • Released gas behavior, odor warning and vapor density depend on the exact gas identity.
  • Flammable gas may form explosive mixtures with air and flash back to the release source.
  • Corrosive gas can burn eyes, skin and respiratory tissue.
  • Fire may produce toxic and corrosive combustion products.
  • Containers exposed to fire may vent, rupture or release toxic gas.

Chemical Identity & Physical Properties

Gas adsorbed onto porous solid material in cylinder. Physical properties depend on specific gas identity. Typically colorless to pale colored gas when released, may have irritating or pungent odor.

Also known asAdsorbed toxic gas N.O.S.Adsorbed poisonous gas flammable corrosiveCompressed toxic gas adsorbedAdsorbed gas Inhalation Hazard Zone A
AppearanceGas adsorbed onto porous solid material in cylinder. Physical properties depend on specific gas identity. Typically colorless to pale colored gas when released, may have irritating or pungent odor.
Flash PointNot applicable (compressed gas)
Boiling PointNot applicable (varies by specific gas composition)
Vapor DensityHeavier than air (typical for toxic corrosive gases)
Water ReactivityMay react with water or moisture producing corrosive and toxic fumes; avoid water contact
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3517

Extinguishing Media

Do not extinguish a leaking gas fire unless flow can be stopped safely. Use dry chemical or CO2 for small fires and cool exposures from protection if safe.

PPE Requirements

⚠️ Level A required; fully encapsulated suit with SCBA; toxic by inhalation Zone A requires maximum protection; avoid any skin or eye contact

Use Level A fully encapsulating chemical protective clothing with positive-pressure SCBA for entry. Zone A toxic gas requires maximum respiratory and skin protection.

Isolation & Evacuation

ERG 173: Initial isolation 200m all directions; protective action distance 3.7km daytime, 8.0km nighttime for large spills; immediate evacuation of spill area
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 173).

First Actions for a UN 3517 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind and avoid low or poorly ventilated areas unless monitoring shows they are safe.
  • Treat the release as a life-threatening inhalation hazard until the gas is identified and monitored.
  • Eliminate ignition sources if this can be done safely.
  • Do not handle leaking cylinders, adsorbed-gas packages or damaged gas articles without proper training and PPE.
  • Ventilate only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 173, shipping papers, markings and air monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 3517 — Adsorbed gas, poisonous, flammable, corr
HAZMAT RADIO NOTE — UN 3517 Product: Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Class 2 / Toxic Gas / ERG 173 PPE: Level A required; fully encapsulated suit with SCBA; toxic by inhalation Zone A requires maximum protection; avoid any skin or eye contact ISOLATION: ERG 173: Initial isolation 200m all directions; protective action distance 3.7km daytime, 8.0km nighttime for large spills; immediate evacuation of spill area ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3517 — Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Class: 2 | Placard: Toxic Gas | ERG Guide: 173 Appearance: Gas adsorbed onto porous solid material in cylinder. Physical properties depend on specific gas identity. Typically colorless to pale colored gas when released, may have irritating or pungent odor. Water Reactivity: May react with water or moisture producing corrosive and toxic fumes; avoid water contact Extinguishing: Do not extinguish a leaking gas fire unless flow can be stopped safely. Use dry chemical or CO2 for small fires and cool exposures from protection if safe. PPE: Level A required; fully encapsulated suit with SCBA; toxic by inhalation Zone A requires maximum protection; avoid any skin or eye contact Isolation: ERG 173: Initial isolation 200m all directions; protective action distance 3.7km daytime, 8.0km nighttime for large spills; immediate evacuation of spill area — Key Hazards — • Adsorbed gas package containing toxic flammable corrosive gas; release may create an immediate inhalation hazard. • Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations. • Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind and avoid low or poorly ventilated areas unless monitoring shows they are safe. • Treat the release as a life-threatening inhalation hazard until the gas is identified and monitored. SOURCE: allfirefighter.com/hazmat/un/adsorbed-gas-poisonous-flammable-un-3517 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3517 Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) Cls2 ERG173 | allfirefighter.com/hazmat/un/adsorbed-gas-poisonous-flammable-un-3517SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/adsorbed-gas-poisonous-flammable-un-3517

Related UN Numbers in Class 2

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3517

UN 3517 is Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A), assigned to ERG Guide 173.

Yes. Adsorbed gas, poisonous, flammable, corrosive, n.o.s. (Inhalation Hazard Zone A) can release flammable gas or vapor that may ignite and flash back.

Adsorbed gas package containing toxic flammable corrosive gas; release may create an immediate inhalation hazard. Inhalation Hazard Zone A entries may be fatal at very low airborne concentrations. Gas is held on a porous solid adsorbent, but damage, heating or valve failure can release free gas.

Use Level A fully encapsulating chemical protective clothing with positive-pressure SCBA for entry. Zone A toxic gas requires maximum respiratory and skin protection.

Do not extinguish a leaking gas fire unless flow can be stopped safely. Use dry chemical or CO2 for small fires and cool exposures from protection if safe.

Adsorption reduces free gas under normal transport, but package damage, heating or valve failure can release toxic gas.

Released gas may form explosive mixtures or ignite, creating flashback and toxic combustion hazards.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.