UN 2614 — Methallyl alcohol
Placard: Flammable. ERG Guide 129. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 2614 is Methallyl alcohol, a flammable alcohol assigned to ERG Guide 129. Water miscibility can spread contaminated flammable runoff.
Hazard overview: FLAMMABLE alcohol liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in drains, sewers, basements and confined areas.
Response guidance: For UN 2614, isolate the area, eliminate ignition sources when flammable vapors are present and use SCBA. Keep vapors out of drains, cool containers from protection and select foam/dry chemical/CO2 from SDS and ERG 129.
Firefighter training notes: Training for UN 2614 should emphasize vapor travel, sewer flashback, foam selection, ignition control, SCBA use, decontamination, container cooling and runoff containment. Use ERG 129, SDS and local SOP.
Regulatory context: Methallyl alcohol is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.
Storage & handling: Methallyl alcohol should be stored in approved compatible containers with ventilation, secondary containment and separation from heat, ignition sources, oxidizers and incompatible materials according to SDS.
UN 2614 Quick Details
Common Hazards of UN 2614
- FLAMMABLE alcohol liquid; vapors may ignite and form explosive mixtures with air.
- Vapors are heavier than air and may travel to ignition sources and flash back.
- Vapor explosion hazard exists in drains, sewers, basements and confined areas.
- Water-miscible liquid may spread through runoff and continue producing flammable vapors.
- Liquid and vapor may irritate eyes, skin and respiratory tract.
- Fire may produce carbon monoxide and irritating/toxic smoke.
- Containers may rupture or explode when heated.
Chemical Identity & Physical Properties
Clear, colorless liquid with a pungent, alcohol-like odor. Liquid at room temperature.
| Also known as | 2-Methyl-2-propen-1-ol2-Methylallyl alcoholIsopropenylcarbinol2-Methylene-1-propanol3-Methyl-3-buten-1-ol |
| CAS Number | 513-42-8 |
| Appearance | Clear, colorless liquid with a pungent, alcohol-like odor. Liquid at room temperature. |
| Flash Point | 33°C (92°F) |
| Boiling Point | 114-115°C (237-239°F) |
| Vapor Density | 2.5 (heavier than air) |
| Water Reactivity | Miscible with water; no violent reaction but may form flammable vapor mixtures |
Fireground Response Guidance — UN 2614
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for vapor, smoke, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.
Isolation & Evacuation
First Actions for a UN 2614 Incident
- Call 911 and the emergency response number on the shipping paper, if available.
- Keep unauthorized personnel away and establish incident command.
- Stay upwind, uphill and upstream.
- Eliminate ignition sources if this can be done safely.
- Avoid breathing vapor, dust, gas, mist, smoke or fumes and avoid skin or eye contact.
- Do not touch damaged containers or spilled material without proper training and PPE.
- Ventilate confined spaces only after monitoring and only if properly trained and equipped.
- Use ERG Guide 129, SDS, shipping papers and monitoring to set isolation, evacuation and entry decisions.
📋 Copy & Share Field Card
UN 2614 — Methallyl alcoholUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.