UN 2367 — Methyl valeraldehyde (alpha)
Placard: Flammable. ERG Guide 130. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 2367 is Methyl valeraldehyde (alpha), a flammable liquid assigned to ERG Guide 130. Heavy vapors can travel, collect in low areas and flash back from ignition sources.
Hazard overview: FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
Response guidance: For UN 2367, isolate the area, eliminate ignition sources, keep vapors out of drains and use SCBA in vapor or fire conditions. Cool containers from a protected distance and choose foam, dry chemical or CO2 based on SDS and ERG 130.
Firefighter training notes: Training for UN 2367 should emphasize vapor travel, low-area accumulation, sewer flashback, foam selection, ignition control, container cooling and vapor monitoring. Use ERG 130, SDS and local SOP.
Regulatory context: Methyl valeraldehyde (alpha) is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.
Storage & handling: Methyl valeraldehyde (alpha) should be stored in approved flammable-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.
UN 2367 Quick Details
Common Hazards of UN 2367
- FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air.
- Vapors are heavier than air and may travel to ignition sources and flash back.
- Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
- Liquid may float on water or form a separate layer, spreading fire or contamination.
- Runoff to sewers may create fire or explosion hazards.
- Fire may produce carbon monoxide and irritating/toxic smoke.
- Containers may rupture or explode when heated.
Chemical Identity & Physical Properties
Colorless to pale yellow liquid with a pungent, aldehyde-like odor. Liquid at room temperature.
| Also known as | alpha-Methylvaleraldehyde2-Methylpentanal2-Methylvaleraldehyde2-Methyl-n-valeraldehyde |
| CAS Number | 110-41-8 |
| Appearance | Colorless to pale yellow liquid with a pungent, aldehyde-like odor. Liquid at room temperature. |
| Flash Point | 18°C (64°F) |
| Boiling Point | 117-118°C (243-244°F) |
| Vapor Density | 3.5 (heavier than air) |
| Water Reactivity | No significant reaction with water; slightly soluble |
Fireground Response Guidance — UN 2367
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.
Isolation & Evacuation
First Actions for a UN 2367 Incident
- Call 911 and the emergency response number on the shipping paper, if available.
- Keep unauthorized personnel away and establish incident command.
- Stay upwind, uphill and upstream; keep responders out of low vapor areas.
- Eliminate ignition sources if this can be done safely.
- Avoid breathing vapor, mist or smoke and avoid skin or eye contact.
- Do not touch damaged containers or spilled material without proper training and PPE.
- Ventilate confined spaces only after monitoring and only if properly trained and equipped.
- Use ERG Guide 130, SDS, shipping papers and air monitoring to set isolation, evacuation and entry decisions.
📋 Copy & Share Field Card
UN 2367 — Methyl valeraldehyde (alpha)Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.