☣️ UN 1127 • CLASS 3

UN 1127 — n-Butyl chloride

Placard: Flammable. ERG Guide 130. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1127 is n-Butyl chloride, a Class 3 flammable liquid assigned to ERG Guide 130. It can generate vapors that ignite easily, travel to ignition sources and flash back.

Hazard overview: UN 1127 presents flammable vapor, flashback and container-heating hazards. Vapors are typically heavier than air and may collect in low, confined or sewer areas where ignition can cause a vapor explosion.

Response guidance: For a UN 1127 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 130. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors out of sewers and use compatible Class B fire-control agents from a protected position.

Firefighter training notes: Training for UN 1127 should emphasize flammable liquid vapor travel, flashback, sewer vapor explosion risk, foam compatibility, container cooling and atmospheric monitoring. Common errors include standing downwind, allowing runoff into drains, ignoring low-area vapor collection and using non-compatible foam. Use ERG 130, SDS and local SOP.

Regulatory context: n-Butyl chloride is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by product, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: n-Butyl chloride should be stored in tightly closed compatible containers in a cool, dry, well-ventilated flammable-liquid storage area. Keep away from heat, sparks, open flames, oxidizers and incompatible materials, with bonding/grounding, secondary containment and drain protection where required.

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UN 1127 Quick Details

UN 1127
Product name: n-Butyl chloride
DOT Class: 3
Placard type: Flammable
ERG Guide: 130 (check current ERG)
Initial isolation: ERG 130: Isolate spill 50m all directions. Evacuate 300m downwind if large spill. If tank/rail car involved in fire, isolate 800m.

Common Hazards of UN 1127

  • HIGHLY FLAMMABLE: will be easily ignited by heat, sparks or flames.
  • Vapors may form explosive mixtures with air.
  • Vapors may travel to an ignition source and flash back.
  • Most vapors are heavier than air and may spread along the ground into low or confined areas.
  • Vapor explosion hazard exists indoors, outdoors or in sewers.
  • Runoff to sewer may create fire or explosion hazard.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Colorless liquid with a sharp, chloroform-like odor. Volatile and highly flammable at room temperature.

Also known as1-ChlorobutaneButyl chloriden-Butyl chloride1-Butyl chlorideChlorobutane
CAS Number109-69-3
AppearanceColorless liquid with a sharp, chloroform-like odor. Volatile and highly flammable at room temperature.
Flash Point-12°C (10°F)
Boiling Point78°C (172°F)
Vapor Density3.2 (heavier than air)
Water ReactivityInsoluble in water; no significant reaction. May float and spread on water surface.
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1127

Extinguishing Media

Use alcohol-resistant foam, AFFF where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers.

PPE Requirements

⚠️ Level B minimum with SCBA required. Full chemical-resistant suit if large spill or confined space.

Use positive-pressure SCBA for fire, heavy vapor or confined-space exposure. Chemical-resistant gloves, splash protection and protective clothing should be selected using SDS, product concentration and incident command.

Isolation & Evacuation

ERG 130: Isolate spill 50m all directions. Evacuate 300m downwind if large spill. If tank/rail car involved in fire, isolate 800m.
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 130).

First Actions for a UN 1127 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Eliminate ignition sources if it is safe to do so.
  • Do not touch or walk through spilled liquid unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or leak area for at least 50 meters (150 feet) in all directions.
  • For large spills or fire involvement, expand isolation and consider downwind evacuation based on vapor movement, monitoring and incident command.
  • Use ERG Guide 130, shipping papers, SDS and local SOP for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1127 — n-Butyl chloride
HAZMAT RADIO NOTE — UN 1127 Product: n-Butyl chloride Class 3 / Flammable / ERG 130 PPE: Level B minimum with SCBA required. Full chemical-resistant suit if large spill or confined space. ISOLATION: ERG 130: Isolate spill 50m all directions. Evacuate 300m downwind if large spill. If tank/rail car involved in fire, isolate 800m. ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1127 — n-Butyl chloride Class: 3 | Placard: Flammable | ERG Guide: 130 Appearance: Colorless liquid with a sharp, chloroform-like odor. Volatile and highly flammable at room temperature. Water Reactivity: Insoluble in water; no significant reaction. May float and spread on water surface. Extinguishing: Use alcohol-resistant foam, AFFF where compatible, dry chemical or CO2 for Class B fires; water spray may be used to cool exposed containers. PPE: Level B minimum with SCBA required. Full chemical-resistant suit if large spill or confined space. Isolation: ERG 130: Isolate spill 50m all directions. Evacuate 300m downwind if large spill. If tank/rail car involved in fire, isolate 800m. — Key Hazards — • HIGHLY FLAMMABLE: will be easily ignited by heat, sparks or flames. • Vapors may form explosive mixtures with air. • Vapors may travel to an ignition source and flash back. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/n-butyl-chloride-un-1127 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1127 n-Butyl chloride Cls3 ERG130 | allfirefighter.com/hazmat/un/n-butyl-chloride-un-1127SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/n-butyl-chloride-un-1127

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1127

UN 1127 is n-Butyl chloride, a hazardous material assigned to ERG Guide 130.

Yes. It is a flammable liquid and vapors may form explosive mixtures with air.

ERG Guide 130 applies to UN 1127 and should be used for initial isolation, protective actions and first response guidance.

UN 1127 presents flammable vapor, flashback and container-heating hazards. Vapors are typically heavier than air and may collect in low, confined or sewer areas where ignition can cause a vapor explosion.

Use positive-pressure SCBA for fire, heavy vapor or confined-space exposure. Chemical-resistant gloves, splash protection and protective clothing should be selected using SDS, product concentration and incident command.

Responders should isolate the area, stay upwind and uphill, eliminate ignition sources when safe, prevent sewer entry, verify the product with SDS and follow ERG Guide 130, incident command and local SOP.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.