☣️ UN 0499 • CLASS 1

Propellant, solid

Placard: Explosive 1.3C. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
Advertisement
Quick details
UN 0499
Class: 1
Placard type: Explosive 1.3C
ERG: Guide 112 (check current ERG)
Isolation: ERG 112: Initial isolation 500m in all directions; if fire or container involved in fire, evacuate 1600m radius; risk of intense heat and fragment projection rather than mass explosion
Chemical & Response Details
Also known asSolid rocket propellantComposite propellantSolid fuel rocket motorSolid propellant grain
AppearanceSolid material, typically rubbery or hard composition ranging from gray to black in color. Often formulated as composite mixtures of oxidizers (ammonium perchlorate) and fuel binders (HTPB, PBAN). No distinct odor unless burning.
Flash PointNot applicable (solid energetic material)
Boiling PointNot applicable (decomposes/deflagrates)
Vapor DensityNot applicable (solid)
Water ReactivityNo significant reaction with water; components may be water-reactive depending on formulation
ExtinguishingDo not use water or foam; use dry chemical, sand, or smother with inert material; water may intensify burning
PPE⚠️ Level A or B minimum with SCBA required; structural firefighting gear inadequate for close proximity; protect from radiant heat and potential fragment projection
IsolationERG 112: Initial isolation 500m in all directions; if fire or container involved in fire, evacuate 1600m radius; risk of intense heat and fragment projection rather than mass explosion
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
  • Fire and burning hazard — not mass explosion.
  • Intense heat and possible fragment projection.
  • May deflagrate and initiate other materials.
  • Smoke and toxic combustion products.
First actions (field-minded)
  • CALL 911. Then call emergency response telephone number on shipping paper.
  • Isolate area; stage upwind — fire and fragment hazard.
  • Request Hazmat + law enforcement.
  • Control ignition sources; deny entry.
  • Consult current ERG Guide 112 and follow SOP/SOG.
Advertisement
📋 Copy & Share
UN 0499 — Propellant, solid
HAZMAT RADIO NOTE — UN 0499 Product: Propellant, solid Class 1 / Explosive 1.3C / ERG 112 PPE: Level A or B minimum with SCBA required; structural firefighting gear inadequate for close proximity; protect from radiant heat and potential fragment projection ISOLATION: ERG 112: Initial isolation 500m in all directions; if fire or container involved in fire, evacuate 1600m radius; risk of intense heat and fragment projection rather than mass explosion ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 0499 — Propellant, solid Class: 1 | Placard: Explosive 1.3C | ERG Guide: 112 Appearance: Solid material, typically rubbery or hard composition ranging from gray to black in color. Often formulated as composite mixtures of oxidizers (ammonium perchlorate) and fuel binders (HTPB, PBAN). No distinct odor unless burning. Water Reactivity: No significant reaction with water; components may be water-reactive depending on formulation Extinguishing: Do not use water or foam; use dry chemical, sand, or smother with inert material; water may intensify burning PPE: Level A or B minimum with SCBA required; structural firefighting gear inadequate for close proximity; protect from radiant heat and potential fragment projection Isolation: ERG 112: Initial isolation 500m in all directions; if fire or container involved in fire, evacuate 1600m radius; risk of intense heat and fragment projection rather than mass explosion — Key Hazards — • Fire and burning hazard — not mass explosion. • Intense heat and possible fragment projection. • May deflagrate and initiate other materials. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. • Isolate area; stage upwind — fire and fragment hazard. • Request Hazmat + law enforcement. • Control ignition sources; deny entry. SOURCE: allfirefighter.com/hazmat/un/0499 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN0499 Propellant, solid Cls1 ERG112 | ERG 112: Initial isolation 500m in all directions; if fire or container involved | allfirefighter.com/hazmat/un/0499SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/0499
Related UN numbers (same class)
Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

FAQ

Fire and burning hazard — not mass explosion. Intense heat and possible fragment projection. May deflagrate and initiate other materials. Smoke and toxic combustion products.

CALL 911. Then call emergency response telephone number on shipping paper. Isolate area; stage upwind — fire and fragment hazard. Request Hazmat + law enforcement.

Level A or B minimum with SCBA required; structural firefighting gear inadequate for close proximity; protect from radiant heat and potential fragment projection

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 112 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.