☣️ UN 1462 • CLASS 5
Chlorites, inorganic, n.o.s.
Placard: Oxidizer. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 1462
Class: 5
Placard type: Oxidizer
ERG: Guide 143 (check current ERG)
Isolation: ERG 143: isolate 100m in all directions; if tank/railcar involved in fire, isolate 800m in all directions and consider evacuation
Chemical & Response Details
| Also known as | Chlorite saltsMetal chloritesChlorous acid saltsInorganic chlorite compounds |
| Appearance | White to pale yellow crystalline solids or powders, typically odorless. Appearance varies depending on specific metal chlorite compound. |
| Flash Point | Not applicable (oxidizing solid) |
| Boiling Point | Not applicable (decomposes before boiling) |
| Vapor Density | Not applicable (solid) |
| Water Reactivity | Generally soluble in water; aqueous solutions may be unstable and decompose, releasing oxygen and chlorine dioxide gas |
| Extinguishing | No foam or water on large fires; use dry sand, dry chemical, or CO2 for small fires only |
| PPE | ⚠️ Level B minimum with full face SCBA; Level A if confined space or high concentrations suspected; chemical-resistant suit required |
| Isolation | ERG 143: isolate 100m in all directions; if tank/railcar involved in fire, isolate 800m in all directions and consider evacuation |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- May explode from friction, heat or contamination.
- These substances will accelerate burning when involved in a fire.
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Some will react explosively with hydrocarbons (fuels).
- Containers may explode when heated.
- Runoff may create fire or explosion hazard.
- TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe
- Fire may produce irritating and/or toxic gases.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
- For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind
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UN 1462 — Chlorites, inorganic, n.o.s. HAZMAT RADIO NOTE — UN 1462
Product: Chlorites, inorganic, n.o.s.
Class 5 / Oxidizer / ERG 143
PPE: Level B minimum with full face SCBA; Level A if confined space or high concentrations suspected; chemical-resistant suit required
ISOLATION: ERG 143: isolate 100m in all directions; if tank/railcar involved in fire, isolate 800m in all directions and consider evacuation
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 1462 — Chlorites, inorganic, n.o.s.
Class: 5 | Placard: Oxidizer | ERG Guide: 143
Appearance: White to pale yellow crystalline solids or powders, typically odorless. Appearance varies depending on specific metal chlorite compound.
Water Reactivity: Generally soluble in water; aqueous solutions may be unstable and decompose, releasing oxygen and chlorine dioxide gas
Extinguishing: No foam or water on large fires; use dry sand, dry chemical, or CO2 for small fires only
PPE: Level B minimum with full face SCBA; Level A if confined space or high concentrations suspected; chemical-resistant suit required
Isolation: ERG 143: isolate 100m in all directions; if tank/railcar involved in fire, isolate 800m in all directions and consider evacuation
— Key Hazards —
• May explode from friction, heat or contamination.
• These substances will accelerate burning when involved in a fire.
• May ignite combustibles (wood, paper, oil, clothing, etc.).
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/1462 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN1462 Chlorites, inorganic, n.o.s. Cls5 ERG143 | allfirefighter.com/hazmat/un/1462SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/1462
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FAQ
May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard. TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe Fire may produce irritating and/or toxic gases.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum with full face SCBA; Level A if confined space or high concentrations suspected; chemical-resistant suit required
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 143 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.