☣️ UN 2058 • CLASS 3

UN 2058 — Valeraldehyde

Placard: Flammable. ERG Guide 129. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2058 is Valeraldehyde, a Class 3 flammable liquid assigned to ERG Guide 129. Vapors can travel to ignition sources and flash back, especially in drains or confined spaces.

Hazard overview: FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.

Response guidance: For a UN 2058 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 129. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2058 should emphasize exposure routes, air monitoring, PPE selection, fire behavior, decontamination, runoff containment and ERG/SDS verification. Use ERG 129, SDS and local SOP.

Regulatory context: Valeraldehyde is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Valeraldehyde should be stored in approved flammable-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

Advertisement

UN 2058 Quick Details

UN 2058
Product name: Valeraldehyde
DOT Class: 3
Placard type: Flammable
ERG Guide: 129 (check current ERG)
Initial isolation: ERG 129: small spill isolate 30m all directions; large spill isolate 150m, evacuate 800m downwind if fire

Common Hazards of UN 2058

  • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
  • Runoff to sewers may create fire or explosion hazards.
  • Containers may rupture or explode when heated.
  • Fire may produce irritating and/or toxic smoke.
  • Specific solvent or hydrocarbon exposure hazards should be confirmed from SDS.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a pungent, disagreeable odor. Less dense than water and only slightly soluble in water.

Also known asPentanalValeric aldehyden-ValeraldehydeAmyl aldehyden-Pentanal
CAS Number110-62-3
AppearanceColorless to pale yellow liquid with a pungent, disagreeable odor. Less dense than water and only slightly soluble in water.
Flash Point-1C (30F)
Boiling Point103C (217F)
Vapor Density3.0 (heavier than air)
Water ReactivityNo significant reaction; slightly soluble in water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2058

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff.

PPE Requirements

⚠️ Level B minimum for spill response; SCBA and chemical-resistant suit for fire or large releases

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Isolation & Evacuation

ERG 129: small spill isolate 30m all directions; large spill isolate 150m, evacuate 800m downwind if fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 129).

First Actions for a UN 2058 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers, basements and low areas.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, gas accumulation, cylinder heating or unknown product identity.
  • Use ERG Guide 129, shipping papers, SDS, air monitoring and incident command for protective actions.
Advertisement

📋 Copy & Share Field Card

UN 2058 — Valeraldehyde
HAZMAT RADIO NOTE — UN 2058 Product: Valeraldehyde Class 3 / Flammable / ERG 129 PPE: Level B minimum for spill response; SCBA and chemical-resistant suit for fire or large releases ISOLATION: ERG 129: small spill isolate 30m all directions; large spill isolate 150m, evacuate 800m downwind if fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2058 — Valeraldehyde Class: 3 | Placard: Flammable | ERG Guide: 129 Appearance: Colorless to pale yellow liquid with a pungent, disagreeable odor. Less dense than water and only slightly soluble in water. Water Reactivity: No significant reaction; slightly soluble in water Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff. PPE: Level B minimum for spill response; SCBA and chemical-resistant suit for fire or large releases Isolation: ERG 129: small spill isolate 30m all directions; large spill isolate 150m, evacuate 800m downwind if fire — Key Hazards — • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources and flash back. • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/valeraldehyde-un-2058 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2058 Valeraldehyde Cls3 ERG129 | allfirefighter.com/hazmat/un/valeraldehyde-un-2058SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/valeraldehyde-un-2058

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 2058

UN 2058 is Valeraldehyde, a hazardous material assigned to ERG Guide 129.

Yes. It is a flammable liquid and vapors may form explosive mixtures with air.

ERG Guide 129 applies to UN 2058 for initial isolation, protective actions and first response guidance.

FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Heavy flammable vapors can travel through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.