☣️ UN 2350 • CLASS 3

UN 2350 — Butyl methyl ether

Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

🚒☣️
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2350 is Butyl methyl ether, a volatile flammable ether assigned to ERG Guide 127. Heavy vapor, flashback and possible peroxide concerns should be checked against the SDS.

Hazard overview: HIGHLY FLAMMABLE ether liquid; vapors may ignite easily and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Ether vapors can accumulate in drains, basements and confined areas.

Response guidance: For UN 2350, isolate the area, eliminate ignition sources, keep vapors out of drains and use SCBA in vapor or fire conditions. Cool containers from a protected distance and select foam/dry chemical/CO2 based on the SDS.

Firefighter training notes: Training for UN 2350 should emphasize vapor travel, low-area accumulation, sewer flashback, foam selection, ignition control, container cooling and vapor monitoring. Use ERG 127, SDS and local SOP.

Regulatory context: Butyl methyl ether is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Butyl methyl ether should be stored in approved flammable-liquid containers with ventilation and ignition control. Track age/inhibitor or peroxide status where required by SDS and facility SOP.

Advertisement

UN 2350 Quick Details

UN 2350
Product name: Butyl methyl ether
DOT Class: 3
Placard type: Flammable
ERG Guide: 127 (check current ERG)
Initial isolation: ERG 127: Small spill isolate 30m all directions; large spill isolate 150m, downwind evacuate 300m

Common Hazards of UN 2350

  • HIGHLY FLAMMABLE ether liquid; vapors may ignite easily and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Ether vapors can accumulate in drains, basements and confined areas.
  • Some ethers may form explosive peroxides during storage; verify age, inhibitor status and SDS.
  • Runoff to sewers may create fire or explosion hazards.
  • Fire may produce irritating and/or toxic smoke.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Colorless liquid with a mild, sweet ether-like odor. Highly volatile at room temperature.

Also known as1-MethoxybutaneMethyl butyl etherMethyl n-butyl etherMTBE (not tert-butyl)n-Butyl methyl ether
CAS Number628-28-4
AppearanceColorless liquid with a mild, sweet ether-like odor. Highly volatile at room temperature.
Flash Point-10°C (14°F)
Boiling Point70°C (158°F)
Vapor Density3.0 (heavier than air)
Water ReactivityNo significant reaction; slightly soluble in water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2350

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid.

PPE Requirements

⚠️ Level B minimum with SCBA; nitrile or butyl rubber gloves; chemical splash goggles and face shield

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.

Isolation & Evacuation

ERG 127: Small spill isolate 30m all directions; large spill isolate 150m, downwind evacuate 300m
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 127).

First Actions for a UN 2350 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; keep responders out of low vapor areas.
  • Eliminate ignition sources if this can be done safely.
  • Avoid breathing vapor, mist or smoke and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 127, SDS, shipping papers and air monitoring to set isolation, evacuation and entry decisions.
Advertisement

📋 Copy & Share Field Card

UN 2350 — Butyl methyl ether
HAZMAT RADIO NOTE — UN 2350 Product: Butyl methyl ether Class 3 / Flammable / ERG 127 PPE: Level B minimum with SCBA; nitrile or butyl rubber gloves; chemical splash goggles and face shield ISOLATION: ERG 127: Small spill isolate 30m all directions; large spill isolate 150m, downwind evacuate 300m ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2350 — Butyl methyl ether Class: 3 | Placard: Flammable | ERG Guide: 127 Appearance: Colorless liquid with a mild, sweet ether-like odor. Highly volatile at room temperature. Water Reactivity: No significant reaction; slightly soluble in water Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid. PPE: Level B minimum with SCBA; nitrile or butyl rubber gloves; chemical splash goggles and face shield Isolation: ERG 127: Small spill isolate 30m all directions; large spill isolate 150m, downwind evacuate 300m — Key Hazards — • HIGHLY FLAMMABLE ether liquid; vapors may ignite easily and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources and flash back. • Ether vapors can accumulate in drains, basements and confined areas. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; keep responders out of low vapor areas. • Eliminate ignition sources if this can be done safely. SOURCE: allfirefighter.com/hazmat/un/butyl-methyl-ether-un-2350 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2350 Butyl methyl ether Cls3 ERG127 | allfirefighter.com/hazmat/un/butyl-methyl-ether-un-2350SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/butyl-methyl-ether-un-2350

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
Advertisement

Frequently Asked Questions about UN 2350

UN 2350 is Butyl methyl ether, assigned to ERG Guide 127.

Yes. Butyl methyl ether is a flammable liquid and its vapors may form explosive mixtures with air.

HIGHLY FLAMMABLE ether liquid; vapors may ignite easily and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Ether vapors can accumulate in drains, basements and confined areas.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid.

Heavy flammable vapors can move through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.