☣️ UN 2379 • CLASS 3

UN 2379 — 1,3-Dimethylbutylamine

Placard: Flammable. ERG Guide 132. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2379 is 1,3-Dimethylbutylamine, a flammable corrosive amine assigned to ERG Guide 132. Vapor flashback, alkaline burns and toxic/corrosive runoff are key concerns.

Hazard overview: FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air. Liquid and vapor can burn eyes, skin and respiratory tissue. Vapors are heavier than air and may travel to ignition sources and flash back.

Response guidance: For UN 2379, isolate the area, eliminate ignition sources and use SCBA. Prevent vapor entry into drains, contain alkaline/toxic runoff and select foam, dry chemical or CO2 based on SDS and ERG 132.

Firefighter training notes: Training for UN 2379 should emphasize amine/nitrile exposure, corrosive or toxic runoff, SCBA use, sewer flashback, decontamination, foam selection and container cooling. Use ERG 132, SDS and local SOP.

Regulatory context: 1,3-Dimethylbutylamine is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: 1,3-Dimethylbutylamine should be stored in approved flammable/corrosive-liquid containers with ventilation, secondary containment and separation from heat, ignition sources, acids, oxidizers and incompatible materials.

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UN 2379 Quick Details

UN 2379
Product name: 1,3-Dimethylbutylamine
DOT Class: 3
Placard type: Flammable
ERG Guide: 132 (check current ERG)
Initial isolation: ERG 132: Small spill isolate 30m all directions; large spill isolate 150m, downwind 300m; if tank/rail car involved in fire isolate 800m all directions

Common Hazards of UN 2379

  • FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air.
  • Liquid and vapor can burn eyes, skin and respiratory tissue.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Mixing with water may generate heat and spread alkaline/corrosive contamination.
  • Runoff to sewers may create fire, explosion and corrosive contamination hazards.
  • Fire may produce nitrogen oxides and irritating/toxic smoke.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Clear to pale yellow liquid with a strong ammonia-like or fishy odor. Lighter than water and volatile at room temperature.

Also known as1,3-Dimethylbutylamine4-Methyl-2-pentanamine4-Methylpentan-2-amineDimethylbutylamine
CAS Number108-09-8
AppearanceClear to pale yellow liquid with a strong ammonia-like or fishy odor. Lighter than water and volatile at room temperature.
Flash Point-9°C (16°F)
Boiling Point105-108°C (221-226°F)
Vapor Density3.5 (heavier than air)
Water ReactivityNo significant reaction with water, but will form alkaline solutions
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2379

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position; contain alkaline/toxic runoff.

PPE Requirements

⚠️ Level B minimum with SCBA and chemical-resistant suit; vapor hazard requires respiratory protection

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing; avoid skin contact.

Isolation & Evacuation

ERG 132: Small spill isolate 30m all directions; large spill isolate 150m, downwind 300m; if tank/rail car involved in fire isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 132).

First Actions for a UN 2379 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; keep responders out of low vapor areas.
  • Eliminate ignition sources if this can be done safely.
  • Avoid breathing vapor, mist or smoke and avoid skin or eye contact.
  • Prevent alkaline, toxic or corrosive runoff from entering drains and waterways.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 132, SDS, shipping papers and air monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2379 — 1,3-Dimethylbutylamine
HAZMAT RADIO NOTE — UN 2379 Product: 1,3-Dimethylbutylamine Class 3 / Flammable / ERG 132 PPE: Level B minimum with SCBA and chemical-resistant suit; vapor hazard requires respiratory protection ISOLATION: ERG 132: Small spill isolate 30m all directions; large spill isolate 150m, downwind 300m; if tank/rail car involved in fire isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2379 — 1,3-Dimethylbutylamine Class: 3 | Placard: Flammable | ERG Guide: 132 Appearance: Clear to pale yellow liquid with a strong ammonia-like or fishy odor. Lighter than water and volatile at room temperature. Water Reactivity: No significant reaction with water, but will form alkaline solutions Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position; contain alkaline/toxic runoff. PPE: Level B minimum with SCBA and chemical-resistant suit; vapor hazard requires respiratory protection Isolation: ERG 132: Small spill isolate 30m all directions; large spill isolate 150m, downwind 300m; if tank/rail car involved in fire isolate 800m all directions — Key Hazards — • FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air. • Liquid and vapor can burn eyes, skin and respiratory tissue. • Vapors are heavier than air and may travel to ignition sources and flash back. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; keep responders out of low vapor areas. • Eliminate ignition sources if this can be done safely. SOURCE: allfirefighter.com/hazmat/un/dimethylbutylamine-un-2379 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2379 1,3-Dimethylbutylamine Cls3 ERG132 | allfirefighter.com/hazmat/un/dimethylbutylamine-un-2379SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/dimethylbutylamine-un-2379

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2379

UN 2379 is 1,3-Dimethylbutylamine, assigned to ERG Guide 132.

Yes. 1,3-Dimethylbutylamine is flammable or combustible and also corrosive; vapors may form explosive mixtures with air.

FLAMMABLE and CORROSIVE amine liquid; vapors may ignite and form explosive mixtures with air. Liquid and vapor can burn eyes, skin and respiratory tissue. Vapors are heavier than air and may travel to ignition sources and flash back.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, boots, eye/face protection and protective clothing; avoid skin contact.

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position; contain alkaline/toxic runoff.

Runoff may carry flammable liquid plus alkaline, toxic or corrosive contamination into drains or waterways.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.