☣️ UN 2719 • CLASS 5
Barium bromate
Placard: Oxidizer. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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Quick details
UN 2719
Class: 5
Placard type: Oxidizer
ERG: Guide 141 (check current ERG)
Isolation: ERG 141: Initial isolation 100m in all directions; protective action distance 300m downwind for large spill; 800m if fire involved
Chemical & Response Details
| Also known as | Bromic acid, barium saltBarium bromate monohydrateBarium dibromate |
| CAS Number | 13967-90-3 |
| Appearance | White crystalline powder or colorless crystals, odorless. Exists as anhydrous or monohydrate form at room temperature. |
| Flash Point | Not applicable (oxidizing solid, non-combustible but accelerates burning) |
| Boiling Point | Decomposes at approximately 260°C (500°F) before boiling |
| Vapor Density | Not applicable (solid oxidizer) |
| Water Reactivity | Soluble in water forming a weak oxidizing solution; no violent reaction but handle carefully |
| Extinguishing | Water spray to keep containers cool; dry chemical or CO2 for surrounding fires; avoid organic materials |
| PPE | ⚠️ Level B minimum with SCBA; full protective clothing; avoid all contact with skin and eyes due to oxidizer and toxicity |
| Isolation | ERG 141: Initial isolation 100m in all directions; protective action distance 300m downwind for large spill; 800m if fire involved |
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.
Common hazards (high level)
- These substances will accelerate burning when involved in a fire.
- May explode from heat or contamination.
- Some may burn rapidly.
- Some will react explosively with hydrocarbons (fuels).
- May ignite combustibles (wood, paper, oil, clothing, etc.).
- Containers may explode when heated.
- Runoff may create fire or explosion hazard.
- Toxic by ingestion.
First actions (field-minded)
- CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Ventilate closed spaces before entering, but only if properly trained and equipped.
- Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
- Consider initial downwind evacuation for at least 100 meters (330 feet).
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UN 2719 — Barium bromate HAZMAT RADIO NOTE — UN 2719
Product: Barium bromate
Class 5 / Oxidizer / ERG 141
PPE: Level B minimum with SCBA; full protective clothing; avoid all contact with skin and eyes due to oxidizer and toxicity
ISOLATION: ERG 141: Initial isolation 100m in all directions; protective action distance 300m downwind for large spill; 800m if fire involved
ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO
Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.
=== IC HAZMAT BRIEFING ===
UN 2719 — Barium bromate
Class: 5 | Placard: Oxidizer | ERG Guide: 141
Appearance: White crystalline powder or colorless crystals, odorless. Exists as anhydrous or monohydrate form at room temperature.
Water Reactivity: Soluble in water forming a weak oxidizing solution; no violent reaction but handle carefully
Extinguishing: Water spray to keep containers cool; dry chemical or CO2 for surrounding fires; avoid organic materials
PPE: Level B minimum with SCBA; full protective clothing; avoid all contact with skin and eyes due to oxidizer and toxicity
Isolation: ERG 141: Initial isolation 100m in all directions; protective action distance 300m downwind for large spill; 800m if fire involved
— Key Hazards —
• These substances will accelerate burning when involved in a fire.
• May explode from heat or contamination.
• Some may burn rapidly.
— First Actions —
• CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
• Keep unauthorized personnel away.
• Stay upwind, uphill and/or upstream.
• Ventilate closed spaces before entering, but only if properly trained and equipped.
SOURCE: allfirefighter.com/hazmat/un/2719 | Always use current ERG + SOP/SOGIC BRIEFING
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.
UN2719 Barium bromate Cls5 ERG141 | ERG 141: Initial isolation 100m in all directions; protective action distance 30 | allfirefighter.com/hazmat/un/2719SMS / 160 CHAR
Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.
⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/2719
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FAQ
These substances will accelerate burning when involved in a fire. May explode from heat or contamination. Some may burn rapidly. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. Toxic by ingestion.
CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.
Level B minimum with SCBA; full protective clothing; avoid all contact with skin and eyes due to oxidizer and toxicity
No. This is a training/quick-reference aid only. Always consult the current ERG Guide 141 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.