☣️ UN 2880 • CLASS 5

UN 2880 — Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water

Placard: Oxidizer. ERG Guide 140. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 2880 Quick Details

UN 2880
Product name: Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water
DOT Class: 5
Placard type: Oxidizer
ERG Guide: 140 (check current ERG)
Initial isolation: ERG 140: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions; evacuate 800m if tank/rail car involved in fire

Common Hazards of UN 2880

  • These substances will accelerate burning when involved in a fire.
  • Some may decompose explosively when heated or involved in a fire.
  • May explode from heat or contamination.
  • Some will react explosively with hydrocarbons (fuels).
  • May ignite combustibles (wood, paper, oil, clothing, etc.).
  • Containers may explode when heated.
  • Runoff may create fire or explosion hazard.
  • Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or

Chemical Identity & Physical Properties

Also known asCalcium hypochlorite hydrateHydrated calcium hypochloriteHTHCalcium oxychloride hydrateChlorinated lime hydrated
CAS Number7778-54-3
AppearanceWhite to grayish-white granular solid or powder with a strong chlorine odor. Solid at room temperature, hygroscopic.
Flash PointNot applicable (oxidizer solid)
Boiling PointNot applicable (decomposes above 100C/212F)
Vapor DensityNot applicable (solid)
Water ReactivityReacts with water releasing heat and chlorine gas; avoid large amounts of water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2880

Extinguishing Media

Dry chemical, sand only; do not use water or foam directly on material

PPE Requirements

⚠️ Level B minimum; SCBA required; chemical-resistant suit; avoid skin/eye contact with dust or solution

Isolation & Evacuation

ERG 140: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions; evacuate 800m if tank/rail car involved in fire
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 140).

First Actions for a UN 2880 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters
  • Consider initial downwind evacuation for at least 100 meters (330 feet).
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📋 Copy & Share Field Card

UN 2880 — Calcium hypochlorite, hydrated mixture,
HAZMAT RADIO NOTE — UN 2880 Product: Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water Class 5 / Oxidizer / ERG 140 PPE: Level B minimum; SCBA required; chemical-resistant suit; avoid skin/eye contact with dust or solution ISOLATION: ERG 140: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions; evacuate 800m if tank/rail car involved in fire ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2880 — Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water Class: 5 | Placard: Oxidizer | ERG Guide: 140 Appearance: White to grayish-white granular solid or powder with a strong chlorine odor. Solid at room temperature, hygroscopic. Water Reactivity: Reacts with water releasing heat and chlorine gas; avoid large amounts of water Extinguishing: Dry chemical, sand only; do not use water or foam directly on material PPE: Level B minimum; SCBA required; chemical-resistant suit; avoid skin/eye contact with dust or solution Isolation: ERG 140: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions; evacuate 800m if tank/rail car involved in fire — Key Hazards — • These substances will accelerate burning when involved in a fire. • Some may decompose explosively when heated or involved in a fire. • May explode from heat or contamination. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Ventilate closed spaces before entering, but only if properly trained and equipped. SOURCE: allfirefighter.com/hazmat/un/2880 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN2880 Calcium hypochlorite, hydrated mixture, with not less than 5.5% but not more than 16% water Cls5 ERG140 | allfirefighter.com/hazmat/un/2880SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/2880

Related UN Numbers in Class 5

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2880

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum; SCBA required; chemical-resistant suit; avoid skin/eye contact with dust or solution

Water reactivity: Reacts with water releasing heat and chlorine gas; avoid large amounts of water. Recommended extinguishing: Dry chemical, sand only; do not use water or foam directly on material.

ERG Guide 140 recommendation: ERG 140: isolate spill 25m all directions; if tank/rail car involved in fire, isolate 800m all directions; evacuate 800m if tank/rail car involved in fire

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 140 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.