☣️ UN 3167 • CLASS 2

UN 3167 — Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid

Placard: Flammable Gas. ERG Guide 115. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.
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UN 3167 Quick Details

UN 3167
Product name: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid
DOT Class: 2
Placard type: Flammable Gas
ERG Guide: 115 (check current ERG)
Initial isolation: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present

Common Hazards of UN 3167

  • EXTREMELY FLAMMABLE.
  • Will be easily ignited by heat, sparks or flames.
  • Will form explosive mixtures with air.
  • Vapors from liquefied gas are initially heavier than air and spread along ground.
  • Vapors may travel to source of ignition and flash back.
  • Cylinders exposed to fire may vent and release flammable gas through pressure relief devices.
  • Containers may explode when heated.
  • Ruptured cylinders may rocket.

Chemical Identity & Physical Properties

Also known asNon-pressurized gas sampleFlammable gas sample NOSGas sample in non-pressurized container
AppearanceGaseous material at room temperature, stored in non-pressurized containers. Color and odor vary depending on specific gas composition.
Flash PointNot applicable (gas)
Boiling PointNot applicable (varies by composition)
Vapor DensityVaries by composition (typically heavier than air)
Water ReactivityNo significant reaction with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3167

Extinguishing Media

Do not use water; use dry chemical, CO2, or inert gas to extinguish

PPE Requirements

⚠️ Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation

Isolation & Evacuation

ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 115).

First Actions for a UN 3167 Incident

  • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Many gases are heavier than air and will spread along the ground and collect in low or confined areas
  • Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
  • Consider initial downwind evacuation for at least 800 meters (1/2 mile).
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📋 Copy & Share Field Card

UN 3167 — Gas sample, non-pressurized, flammable,
HAZMAT RADIO NOTE — UN 3167 Product: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid Class 2 / Flammable Gas / ERG 115 PPE: Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation ISOLATION: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3167 — Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid Class: 2 | Placard: Flammable Gas | ERG Guide: 115 Appearance: Gaseous material at room temperature, stored in non-pressurized containers. Color and odor vary depending on specific gas composition. Water Reactivity: No significant reaction with water Extinguishing: Do not use water; use dry chemical, CO2, or inert gas to extinguish PPE: Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation Isolation: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present — Key Hazards — • EXTREMELY FLAMMABLE. • Will be easily ignited by heat, sparks or flames. • Will form explosive mixtures with air. — First Actions — • CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Many gases are heavier than air and will spread along the ground and collect in low or confined areas SOURCE: allfirefighter.com/hazmat/un/3167 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief. Full chemical + response details.

SMS (short)
UN3167 Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid Cls2 ERG115 | allfirefighter.com/hazmat/un/3167SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS. Includes link to full page.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/3167

Related UN Numbers in Class 2

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3167

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Vapors from liquefied gas are initially heavier than air and spread along ground. Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper Keep unauthorized personnel away. Stay upwind, uphill and/or upstream.

Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation

Water reactivity: No significant reaction with water. Recommended extinguishing: Do not use water; use dry chemical, CO2, or inert gas to extinguish.

ERG Guide 115 recommendation: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present

No. This is a training/quick-reference aid only. Always consult the current ERG Guide 115 and your department SOP/SOG for incident-specific protective actions.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.