☣️ UN 3167 • CLASS 2

UN 3167 — Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid

Placard: Flammable Gas. ERG Guide 115. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ Verification required: Broad or variable material category; verify exact product, SDS and shipping papers.
⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 3167 is Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid, a flammable gas sample entry assigned to ERG Guide 115. Small non-pressurized samples can still form explosive mixtures.

Hazard overview: Flammable non-pressurized gas sample, n.o.s.; small containers can still release explosive vapor mixtures. Gas may ignite easily by heat, sparks, static or open flame. Vapor density and toxicity vary by sample composition.

Response guidance: For UN 3167, isolate the package or sample container, use monitoring and avoid ignition sources where flammable. Ventilate only if trained and equipped under ERG 115.

Firefighter training notes: Training for UN 3167 should emphasize cylinder/package recognition, vapor density, air monitoring, SCBA use, frostbite/toxicity controls, isolation and source-control limits. Use ERG 115, SDS and local SOP.

Regulatory context: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid is regulated as a hazardous material for transport and emergency response. Storage, reporting, exposure, waste and incident-notification duties depend on quantity, package type, formulation and jurisdiction; verify shipping papers, SDS and authority guidance.

Storage & handling: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid should be stored in secured, compatible cylinders or sample packages away from heat, physical damage and unauthorized access, with ventilation, segregation and emergency planning based on exact gas identity.

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UN 3167 Quick Details

UN 3167
Product name: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid
DOT Class: 2
Placard type: Flammable Gas
ERG Guide: 115 (check current ERG)
Initial isolation: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present

Common Hazards of UN 3167

  • Flammable non-pressurized gas sample, n.o.s.; small containers can still release explosive vapor mixtures.
  • Gas may ignite easily by heat, sparks, static or open flame.
  • Vapor density and toxicity vary by sample composition.
  • Leaking sample containers can contaminate enclosed cabinets, vehicles or laboratories.
  • Fire may produce toxic or irritating gases depending on sample identity.
  • Do not overstate cylinder rocket hazard for non-pressurized samples, but heat can still rupture containers.
  • Exact sample identity must be verified from laboratory documentation and shipping papers.

Chemical Identity & Physical Properties

Gaseous material at room temperature, stored in non-pressurized containers. Color and odor vary depending on specific gas composition.

Also known asNon-pressurized gas sampleFlammable gas sample NOSGas sample in non-pressurized container
AppearanceGaseous material at room temperature, stored in non-pressurized containers. Color and odor vary depending on specific gas composition.
Flash PointNot applicable (gas)
Boiling PointNot applicable (varies by composition)
Vapor DensityVaries by composition (typically heavier than air)
Water ReactivityNo significant reaction with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 3167

Extinguishing Media

Use dry chemical or CO2 for small fires. Remove ignition sources and ventilate only after monitoring; do not disperse gas into occupied areas.

PPE Requirements

⚠️ Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation

Use positive-pressure SCBA and chemical-resistant protection for unknown or toxic sample releases. Use monitoring before ventilation or close handling.

Isolation & Evacuation

ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 115).

First Actions for a UN 3167 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream.
  • Eliminate ignition sources if this can be done safely.
  • Avoid breathing vapor, gas, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Do not touch damaged containers, cylinders, articles or spilled material without proper training and PPE.
  • Prevent contaminated runoff, debris and decontamination waste from spreading.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 115, SDS, shipping papers, markings and monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 3167 — Gas sample, non-pressurized, flammable,
HAZMAT RADIO NOTE — UN 3167 Product: Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid Class 2 / Flammable Gas / ERG 115 PPE: Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation ISOLATION: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 3167 — Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid Class: 2 | Placard: Flammable Gas | ERG Guide: 115 Appearance: Gaseous material at room temperature, stored in non-pressurized containers. Color and odor vary depending on specific gas composition. Water Reactivity: No significant reaction with water Extinguishing: Use dry chemical or CO2 for small fires. Remove ignition sources and ventilate only after monitoring; do not disperse gas into occupied areas. PPE: Level B minimum; SCBA required; avoid all ignition sources; ensure adequate ventilation Isolation: ERG 115: isolate spill or leak area immediately for at least 100m in all directions; evacuate area if large spill or fire present — Key Hazards — • Flammable non-pressurized gas sample, n.o.s.; small containers can still release explosive vapor mixtures. • Gas may ignite easily by heat, sparks, static or open flame. • Vapor density and toxicity vary by sample composition. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream. • Eliminate ignition sources if this can be done safely. SOURCE: allfirefighter.com/hazmat/un/gas-sample-non-pressurized-un-3167 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN3167 Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid Cls2 ERG115 | allfirefighter.com/hazmat/un/gas-sample-non-pressurized-un-3167SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/gas-sample-non-pressurized-un-3167

Related UN Numbers in Class 2

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 3167

UN 3167 is Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid, assigned to ERG Guide 115.

Yes. Gas sample, non-pressurized, flammable, n.o.s., not refrigerated liquid is flammable or contains flammable gas that may form explosive mixtures with air.

Flammable non-pressurized gas sample, n.o.s.; small containers can still release explosive vapor mixtures. Gas may ignite easily by heat, sparks, static or open flame. Vapor density and toxicity vary by sample composition.

Use positive-pressure SCBA and chemical-resistant protection for unknown or toxic sample releases. Use monitoring before ventilation or close handling.

Use dry chemical or CO2 for small fires. Remove ignition sources and ventilate only after monitoring; do not disperse gas into occupied areas.

Gas composition, toxicity, flammability and vapor density vary by sample, so documentation and monitoring are critical.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.