UN 2335 — Allyl ethyl ether
Placard: Flammable. ERG Guide 131. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 2335 At a Glance
UN 2335 (Allyl ethyl ether) is listed as DOT Class 3 Flammable and is assigned to ERG Guide 131. Use this page to review placard data, common hazards, PPE notes, isolation context, first actions, and related UN numbers.
UN 2335 is Allyl ethyl ether, a volatile flammable ether assigned to ERG Guide 131. Heavy vapor, flashback and possible peroxide concerns should be checked against the SDS.
Hazard overview: HIGHLY FLAMMABLE ether liquid; vapors may ignite easily and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Ether vapors can accumulate in drains, basements and confined areas.
Response guidance: For UN 2335, isolate the area, eliminate ignition sources, keep vapors out of drains and use SCBA in vapor or fire conditions. Cool containers from a protected distance and select foam/dry chemical/CO2 based on the SDS.
Firefighter training notes: Training for UN 2335 should emphasize vapor travel, low-area accumulation, sewer flashback, foam selection, ignition control, container cooling and vapor monitoring. Use ERG 131, SDS and local SOP.
Regulatory context: Allyl ethyl ether is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.
Storage & handling: Allyl ethyl ether should be stored in approved flammable-liquid containers with ventilation and ignition control. Track age/inhibitor or peroxide status where required by SDS and facility SOP.
UN 2335 Quick Details
Common Hazards of UN 2335
- HIGHLY FLAMMABLE ether liquid; vapors may ignite easily and form explosive mixtures with air.
- Vapors are heavier than air and may travel to ignition sources and flash back.
- Ether vapors can accumulate in drains, basements and confined areas.
- Some ethers may form explosive peroxides during storage; verify age, inhibitor status and SDS.
- Runoff to sewers may create fire or explosion hazards.
- Fire may produce irritating and/or toxic smoke.
- Containers may rupture or explode when heated.
Chemical Identity & Physical Properties
Clear, colorless liquid with a pungent, ether-like odor. Highly volatile and exists as a liquid at room temperature.
| Also known as | Allylethyl ether3-EthoxypropeneEther, allyl ethylEthyl allyl ether |
| CAS Number | 557-31-3 |
| Appearance | Clear, colorless liquid with a pungent, ether-like odor. Highly volatile and exists as a liquid at room temperature. |
| Flash Point | -37°C (-35°F) |
| Boiling Point | 66-68°C (151-154°F) |
| Vapor Density | 3.0 (heavier than air) |
| Water Reactivity | No significant reaction; slightly soluble in water |
Fireground Response Guidance — UN 2335
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.
Isolation & Evacuation
First Actions for a UN 2335 Incident
- Call 911 and the emergency response number on the shipping paper, if available.
- Keep unauthorized personnel away and establish incident command.
- Stay upwind, uphill and upstream; keep responders out of low vapor areas.
- Eliminate ignition sources if this can be done safely.
- Avoid breathing vapor, mist or smoke and avoid skin or eye contact.
- Do not touch damaged containers or spilled material without proper training and PPE.
- Ventilate confined spaces only after monitoring and only if properly trained and equipped.
- Use ERG Guide 131, SDS, shipping papers and air monitoring to set isolation, evacuation and entry decisions.
📋 Copy & Share Field Card
UN 2335 — Allyl ethyl etherUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.