UN 2222 — Anisole
Placard: Flammable. ERG Guide 128. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 2222 is Anisole, a flammable liquid assigned to ERG Guide 128. Vapors can travel to ignition sources and flash back, especially in drains or confined spaces.
Hazard overview: FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
Response guidance: For a UN 2222 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 128. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff, dust or vapor spread and base entry/fire-control actions on monitoring and local SOP.
Firefighter training notes: Training for UN 2222 should emphasize vapor travel, sewer flashback, foam selection, container cooling, ignition control and runoff containment. Use ERG 128, SDS and local SOP.
Regulatory context: Anisole is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.
Storage & handling: Anisole should be stored in approved flammable-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.
UN 2222 Quick Details
Common Hazards of UN 2222
- FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air.
- Vapors are heavier than air and may travel to ignition sources and flash back.
- Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
- Runoff to sewers may create fire or explosion hazards.
- Containers may rupture or explode when heated.
- Fire may produce irritating and/or toxic smoke, including chlorinated or aromatic decomposition products where applicable.
- Specific solvent, epoxy, aromatic or chlorinated exposure hazards should be confirmed from SDS.
Chemical Identity & Physical Properties
Clear, colorless to pale yellow liquid with a pleasant, aromatic odor similar to anise. Liquid at room temperature.
| Also known as | MethoxybenzeneMethyl phenyl etherPhenyl methyl etherPhenoxymethane |
| CAS Number | 100-66-3 |
| Appearance | Clear, colorless to pale yellow liquid with a pleasant, aromatic odor similar to anise. Liquid at room temperature. |
| Flash Point | 52°C (126°F) |
| Boiling Point | 154°C (309°F) |
| Vapor Density | 3.7 (heavier than air) |
| Water Reactivity | Insoluble in water; no significant reaction with water |
Fireground Response Guidance — UN 2222
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.
Isolation & Evacuation
First Actions for a UN 2222 Incident
- CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact.
- Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers, basements and low areas.
- Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
- Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
- Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, dust generation, water reaction or unknown product identity.
- Use ERG Guide 128, shipping papers, SDS, air monitoring and incident command for protective actions.
📋 Copy & Share Field Card
UN 2222 — AnisoleUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.