☣️ UN 1179 • CLASS 3

UN 1179 — Ethyl butyl ether

Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

Ethyl butyl ether is a highly flammable liquid with a sweet, ether-like odor. It is commonly used as a solvent and can be hazardous if not handled properly.

Hazard overview: The substance is highly flammable and can be easily ignited by heat, sparks, or flames. Vapors may form explosive mixtures with air, posing a significant risk to people and the environment.

Response guidance: In case of a spill, it is essential to isolate the area and prevent ignition sources. Emergency responders should wear Level B minimum protective equipment, including SCBA and full protective clothing.

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UN 1179 Quick Details

UN 1179
Product name: Ethyl butyl ether
DOT Class: 3
Placard type: Flammable
ERG Guide: 127 (check current ERG)
Initial isolation: ERG 127: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions

Common Hazards of UN 1179

  • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
  • Vapors may form explosive mixtures with air.
  • Vapors may travel to source of ignition and flash back.
  • Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas
  • Vapor explosion hazard indoors, outdoors or in sewers.
  • Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
  • Runoff to sewer may create fire or explosion hazard.
  • Containers may explode when heated.

Chemical Identity & Physical Properties

Ethyl butyl ether is a colorless liquid with a sweet, ether-like odor, lighter than water and volatile at room temperature.

Also known asButyl ethyl ether1-ButoxyethaneEther, butyl ethylBEE
CAS Number628-81-9
AppearanceColorless liquid with a sweet, ether-like odor. Lighter than water and volatile at room temperature.
Flash Point-7C (19F)
Boiling Point92C (198F)
Vapor Density3.5 (heavier than air)
Water ReactivityInsoluble in water; no significant reaction
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1179

Extinguishing Media

Alcohol-resistant foam, CO2, dry chemical, water spray for cooling

PPE Requirements

⚠️ Level B minimum with SCBA; full protective clothing for fire or large spills

Level B minimum protective equipment, including SCBA and full protective clothing, is required when handling Ethyl butyl ether.

Isolation & Evacuation

ERG 127: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 127).

First Actions for a UN 1179 Incident

  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Ventilate closed spaces before entering, but only if properly trained and equipped.
  • Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
  • Consider initial downwind evacuation for at least 300 meters (1000 feet).
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📋 Copy & Share Field Card

UN 1179 — Ethyl butyl ether
HAZMAT RADIO NOTE — UN 1179 Product: Ethyl butyl ether Class 3 / Flammable / ERG 127 PPE: Level B minimum with SCBA; full protective clothing for fire or large spills ISOLATION: ERG 127: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1179 — Ethyl butyl ether Class: 3 | Placard: Flammable | ERG Guide: 127 Appearance: Colorless liquid with a sweet, ether-like odor. Lighter than water and volatile at room temperature. Water Reactivity: Insoluble in water; no significant reaction Extinguishing: Alcohol-resistant foam, CO2, dry chemical, water spray for cooling PPE: Level B minimum with SCBA; full protective clothing for fire or large spills Isolation: ERG 127: isolate spill 50m all directions; if tank/rail car involved in fire, isolate 800m all directions — Key Hazards — • HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Vapors may form explosive mixtures with air. • Vapors may travel to source of ignition and flash back. — First Actions — • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Ventilate closed spaces before entering, but only if properly trained and equipped. • Isolate spill or leak area for at least 50 meters (150 feet) in all directions. SOURCE: allfirefighter.com/hazmat/un/1179 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1179 Ethyl butyl ether Cls3 ERG127 | ERG 127: isolate spill 50m all directions; if tank/rail car involved in fire, is | allfirefighter.com/hazmat/un/1179SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/ethyl-butyl-ether-un-1179

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1179

No, UN 1179 is insoluble in water.

Isolate the spill 50m in all directions.

Alcohol-resistant foam, CO2, dry chemical, or water spray can be used to extinguish UN 1179 fires.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.