☣️ UN 2385 • CLASS 3

UN 2385 — Ethyl isobutyrate

Placard: Flammable. ERG Guide 129. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2385 is Ethyl isobutyrate, a flammable ester liquid assigned to ERG Guide 129. Heavy vapors can travel to ignition sources and flash back.

Hazard overview: FLAMMABLE ester liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.

Response guidance: For UN 2385, isolate the area, eliminate ignition sources, keep vapors out of drains and use SCBA in vapor or fire conditions. Cool containers from a protected distance and choose foam, dry chemical or CO2 using SDS and ERG 129.

Firefighter training notes: Training for UN 2385 should emphasize vapor travel, low-area accumulation, sewer flashback, foam selection, ignition control, container cooling and vapor monitoring. Use ERG 129, SDS and local SOP.

Regulatory context: Ethyl isobutyrate is regulated as a hazardous material for transport and emergency response. Storage, exposure, spill reporting, waste and fire-code duties depend on quantity, concentration and jurisdiction; verify shipping papers, SDS and local authority requirements.

Storage & handling: Ethyl isobutyrate should be stored in approved flammable-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

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UN 2385 Quick Details

UN 2385
Product name: Ethyl isobutyrate
DOT Class: 3
Placard type: Flammable
ERG Guide: 129 (check current ERG)
Initial isolation: ERG 129: Initial isolation 50m all directions; protective action distance 0.3km (spill), 0.8km (fire during day)

Common Hazards of UN 2385

  • FLAMMABLE ester liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
  • Liquid may float on water or form a separate layer, spreading fire or contamination.
  • Runoff to sewers may create fire or explosion hazards.
  • Fire may produce carbon monoxide and irritating/toxic smoke.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Clear, colorless liquid with a fruity, pineapple-like odor. Volatile and less dense than water.

Also known asEthyl 2-methylpropanoateEthyl isobutanoateIsobutyric acid ethyl ester2-Methylpropanoic acid ethyl ester
CAS Number97-62-1
AppearanceClear, colorless liquid with a fruity, pineapple-like odor. Volatile and less dense than water.
Flash Point-18C (0F)
Boiling Point110-112C (230-234F)
Vapor Density4.0 (heavier than air)
Water ReactivityNo significant reaction; insoluble in water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2385

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid.

PPE Requirements

⚠️ Level B minimum; SCBA required in enclosed areas or fire conditions; chemical-resistant gloves and protective clothing

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.

Isolation & Evacuation

ERG 129: Initial isolation 50m all directions; protective action distance 0.3km (spill), 0.8km (fire during day)
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 129).

First Actions for a UN 2385 Incident

  • Call 911 and the emergency response number on the shipping paper, if available.
  • Keep unauthorized personnel away and establish incident command.
  • Stay upwind, uphill and upstream; keep responders out of low vapor areas.
  • Eliminate ignition sources if this can be done safely.
  • Avoid breathing vapor, mist or smoke and avoid skin or eye contact.
  • Do not touch damaged containers or spilled material without proper training and PPE.
  • Ventilate confined spaces only after monitoring and only if properly trained and equipped.
  • Use ERG Guide 129, SDS, shipping papers and air monitoring to set isolation, evacuation and entry decisions.
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📋 Copy & Share Field Card

UN 2385 — Ethyl isobutyrate
HAZMAT RADIO NOTE — UN 2385 Product: Ethyl isobutyrate Class 3 / Flammable / ERG 129 PPE: Level B minimum; SCBA required in enclosed areas or fire conditions; chemical-resistant gloves and protective clothing ISOLATION: ERG 129: Initial isolation 50m all directions; protective action distance 0.3km (spill), 0.8km (fire during day) ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2385 — Ethyl isobutyrate Class: 3 | Placard: Flammable | ERG Guide: 129 Appearance: Clear, colorless liquid with a fruity, pineapple-like odor. Volatile and less dense than water. Water Reactivity: No significant reaction; insoluble in water Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid. PPE: Level B minimum; SCBA required in enclosed areas or fire conditions; chemical-resistant gloves and protective clothing Isolation: ERG 129: Initial isolation 50m all directions; protective action distance 0.3km (spill), 0.8km (fire during day) — Key Hazards — • FLAMMABLE ester liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources and flash back. • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces. — First Actions — • Call 911 and the emergency response number on the shipping paper, if available. • Keep unauthorized personnel away and establish incident command. • Stay upwind, uphill and upstream; keep responders out of low vapor areas. • Eliminate ignition sources if this can be done safely. SOURCE: allfirefighter.com/hazmat/un/ethyl-isobutyrate-un-2385 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2385 Ethyl isobutyrate Cls3 ERG129 | allfirefighter.com/hazmat/un/ethyl-isobutyrate-un-2385SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/ethyl-isobutyrate-un-2385

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2385

UN 2385 is Ethyl isobutyrate, assigned to ERG Guide 129.

Yes. Ethyl isobutyrate is a flammable liquid and its vapors may form explosive mixtures with air.

FLAMMABLE ester liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection and flame-resistant protection as appropriate.

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid.

Heavy flammable vapors can move through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.