☣️ UN 1188 • CLASS 3

UN 1188 — Ethylene glycol monomethyl ether

Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 1188 is Ethylene glycol monomethyl ether, a Class 3 flammable glycol ether liquid assigned to ERG Guide 127. It presents vapor ignition hazards plus possible skin absorption and systemic exposure concerns.

Hazard overview: UN 1188 presents flammable vapor, flashback and glycol ether exposure hazards. Vapors may collect in low areas, and skin contact can be significant for some glycol ethers, so PPE should be selected from SDS and monitoring conditions.

Response guidance: For a UN 1188 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 127. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors or runoff out of sewers and use compatible fire-control agents from a protected position.

Firefighter training notes: Training for UN 1188 should emphasize flammable vapor travel, skin absorption risk, sewer entry prevention, foam compatibility and decontamination. Common errors include relying on odor, using fire-only PPE and overlooking systemic toxicity.

Regulatory context: Ethylene glycol monomethyl ether is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Ethylene glycol monomethyl ether should be stored in tightly closed compatible containers in a cool, dry, well-ventilated flammable-liquid storage area. Keep away from heat, sparks, open flames, oxidizers and incompatible materials, with bonding/grounding, secondary containment and drain protection where required.

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UN 1188 Quick Details

UN 1188
Product name: Ethylene glycol monomethyl ether
DOT Class: 3
Placard type: Flammable
ERG Guide: 127 (check current ERG)
Initial isolation: ERG 127: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation

Common Hazards of UN 1188

  • FLAMMABLE glycol ether liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources or collect in low areas.
  • Some glycol ethers can be absorbed through skin and may cause systemic health effects.
  • Liquid or vapor may irritate eyes, skin and respiratory tissue.
  • Fire may produce irritating or toxic combustion products.
  • Runoff to sewer may create fire, explosion or environmental hazards.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Colorless liquid with a mild, sweet, ether-like odor. Miscible with water and common organic solvents.

Also known as2-MethoxyethanolMethyl cellosolveEGMEMethoxyethanolGlycol monomethyl ether
CAS Number109-86-4
AppearanceColorless liquid with a mild, sweet, ether-like odor. Miscible with water and common organic solvents.
Flash Point39°C (102°F)
Boiling Point124-125°C (255-257°F)
Vapor Density2.6 (heavier than air)
Water ReactivityNo significant reaction; miscible with water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 1188

Extinguishing Media

Use alcohol-resistant foam, dry chemical or CO2 when compatible; water spray may be used from a protected position to cool exposed containers.

PPE Requirements

⚠️ Level B minimum recommended; SCBA and chemical-resistant suit; avoid skin contact as readily absorbed

Use positive-pressure SCBA for fire, vapor or confined-space exposure. Chemical-resistant gloves and splash protection are important because glycol ethers may be absorbed through skin and can cause systemic effects.

Isolation & Evacuation

ERG 127: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 127).

First Actions for a UN 1188 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Eliminate ignition sources if it is safe to do so.
  • Do not touch or walk through spilled liquid unless properly trained and wearing appropriate protective equipment.
  • Avoid breathing vapors and avoid skin or eye contact with liquid.
  • Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
  • Isolate the spill or leak area for at least 50 meters (150 feet) in all directions.
  • For large spills, fire involvement or strong vapor movement, expand isolation and consider downwind evacuation based on monitoring and incident command.
  • Use ERG Guide 127, shipping papers, SDS and local SOP for protective actions and entry decisions.
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📋 Copy & Share Field Card

UN 1188 — Ethylene glycol monomethyl ether
HAZMAT RADIO NOTE — UN 1188 Product: Ethylene glycol monomethyl ether Class 3 / Flammable / ERG 127 PPE: Level B minimum recommended; SCBA and chemical-resistant suit; avoid skin contact as readily absorbed ISOLATION: ERG 127: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 1188 — Ethylene glycol monomethyl ether Class: 3 | Placard: Flammable | ERG Guide: 127 Appearance: Colorless liquid with a mild, sweet, ether-like odor. Miscible with water and common organic solvents. Water Reactivity: No significant reaction; miscible with water Extinguishing: Use alcohol-resistant foam, dry chemical or CO2 when compatible; water spray may be used from a protected position to cool exposed containers. PPE: Level B minimum recommended; SCBA and chemical-resistant suit; avoid skin contact as readily absorbed Isolation: ERG 127: isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m all directions and consider evacuation — Key Hazards — • FLAMMABLE glycol ether liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources or collect in low areas. • Some glycol ethers can be absorbed through skin and may cause systemic health effects. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Eliminate ignition sources if it is safe to do so. SOURCE: allfirefighter.com/hazmat/un/ethylene-glycol-monomethyl-ether-un-1188 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN1188 Ethylene glycol monomethyl ether Cls3 ERG127 | allfirefighter.com/hazmat/un/ethylene-glycol-monomethyl-ether-un-1188SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/ethylene-glycol-monomethyl-ether-un-1188

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 1188

UN 1188 is Ethylene glycol monomethyl ether, a hazardous material assigned to ERG Guide 127.

Yes. It is a flammable liquid and vapors may form explosive mixtures with air.

ERG Guide 127 applies to UN 1188 and should be used for initial isolation, protective actions and first response guidance.

UN 1188 presents flammable vapor, flashback and glycol ether exposure hazards. Vapors may collect in low areas, and skin contact can be significant for some glycol ethers, so PPE should be selected from SDS and monitoring conditions.

Use positive-pressure SCBA for fire, vapor or confined-space exposure. Chemical-resistant gloves and splash protection are important because glycol ethers may be absorbed through skin and can cause systemic effects.

Responders should isolate the area, stay upwind and uphill, eliminate ignition sources when safe, prevent sewer entry, verify the product with SDS and follow ERG Guide 127, incident command and local SOP.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.