UN 1249 — Methyl propyl ketone
Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 1249 is Methyl propyl ketone, a Class 3 flammable ketone liquid assigned to ERG Guide 127. It can produce solvent vapors that travel, ignite and flash back from distant ignition sources.
Hazard overview: UN 1249 presents flammable vapor, flashback and sewer vapor-explosion hazards. Vapors are heavier than air, and exposure may irritate eyes, skin or respiratory tissue in poorly ventilated areas.
Response guidance: For a UN 1249 incident, responders should confirm the product using shipping papers, container markings, SDS and ERG Guide 127. Establish incident command, isolate the area, stay upwind and uphill, remove ignition sources when safe, keep vapors or runoff out of sewers and use compatible fire-control agents from a protected position.
Firefighter training notes: Training for UN 1249 should emphasize flammable liquid vapor travel, flashback, sewer vapor explosion risk, foam compatibility, container cooling and atmospheric monitoring. Common errors include standing downwind, allowing runoff into drains and ignoring low-area vapor collection. Use ERG 127, SDS and local SOP.
Regulatory context: Methyl propyl ketone is regulated as a hazardous material for transportation and emergency response purposes. Transportation, workplace exposure, spill reporting, waste handling, storage and environmental requirements may vary by formulation, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, facility documents and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.
Storage & handling: Methyl propyl ketone should be stored in tightly closed compatible containers in a cool, dry, well-ventilated flammable-liquid storage area. Keep away from heat, sparks, open flames, oxidizers and incompatible materials, with bonding/grounding, secondary containment and drain protection where required.
UN 1249 Quick Details
Common Hazards of UN 1249
- HIGHLY FLAMMABLE ketone liquid; vapors may ignite easily.
- Vapors may form explosive mixtures with air and flash back to the source.
- Vapors are heavier than air and may collect in low, confined or sewer areas.
- Liquid or vapor may irritate eyes, skin and respiratory tissue.
- Runoff to sewer may create fire or explosion hazards.
- Fire may produce irritating or toxic combustion products.
- Containers may rupture or explode when heated.
Chemical Identity & Physical Properties
Colorless liquid with a sweet, acetone-like odor. Volatile and highly flammable at room temperature.
| Also known as | 2-PentanoneEthyl acetoneMethyl n-propyl ketoneMPKPentanone-2 |
| CAS Number | 107-87-9 |
| Appearance | Colorless liquid with a sweet, acetone-like odor. Volatile and highly flammable at room temperature. |
| Flash Point | 7°C (45°F) |
| Boiling Point | 102°C (216°F) |
| Vapor Density | 3.0 (heavier than air) |
| Water Reactivity | No significant reaction; slightly soluble in water |
Fireground Response Guidance — UN 1249
Extinguishing Media
PPE Requirements
Use positive-pressure SCBA for fire, heavy vapor or confined-space exposure. Chemical-resistant gloves, splash protection and protective clothing should be selected using SDS, product concentration and incident command.
Isolation & Evacuation
First Actions for a UN 1249 Incident
- CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Eliminate ignition sources if it is safe to do so.
- Do not touch or walk through spilled liquid unless properly trained and wearing appropriate protective equipment.
- Ventilate closed spaces before entering, but only if properly trained, equipped and authorized by incident command.
- Isolate the spill or leak area for at least 50 meters (150 feet) in all directions.
- For large spills, fire involvement or strong vapor movement, expand isolation and consider downwind evacuation based on monitoring and incident command.
- Use ERG Guide 127, shipping papers, SDS and local SOP for protective actions and entry decisions.
📋 Copy & Share Field Card
UN 1249 — Methyl propyl ketoneUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.