☣️ UN 2297 • CLASS 3

UN 2297 — Methylcyclohexanone

Placard: Flammable. ERG Guide 128. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2297 is Methylcyclohexanone, a flammable liquid assigned to ERG Guide 128. Vapors can travel to ignition sources and flash back, especially in drains or confined spaces.

Hazard overview: FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.

Response guidance: For a UN 2297 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 128. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff, dust or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2297 should emphasize vapor travel, sewer flashback, foam selection, container cooling, ignition control, toxic exposure where applicable and runoff containment. Use ERG 128, SDS and local SOP.

Regulatory context: Methylcyclohexanone is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Methylcyclohexanone should be stored in approved flammable/toxic-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

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UN 2297 Quick Details

UN 2297
Product name: Methylcyclohexanone
DOT Class: 3
Placard type: Flammable
ERG Guide: 128 (check current ERG)
Initial isolation: ERG 128: isolate spill 50m all directions; for large spill isolate 150m; if tank/rail car involved in fire isolate 800m

Common Hazards of UN 2297

  • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.
  • Runoff to sewers may create fire or explosion hazards.
  • Containers may rupture or explode when heated.
  • Fire may produce irritating and/or toxic smoke.
  • Specific hydrocarbon, ketone or aromatic exposure hazards should be confirmed from SDS.

Chemical Identity & Physical Properties

Colorless to pale yellow liquid with a mild, ketone-like odor. Oily consistency at room temperature.

Also known as2-Methylcyclohexanoneo-MethylcyclohexanoneHexahydro-o-cresolCyclohexanone, 2-methyl-
CAS Number583-60-8
AppearanceColorless to pale yellow liquid with a mild, ketone-like odor. Oily consistency at room temperature.
Flash Point48C (118F)
Boiling Point165C (329F)
Vapor Density3.9 (heavier than air)
Water ReactivityNo significant reaction; slight solubility in water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2297

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff.

PPE Requirements

⚠️ Level B minimum; SCBA required in confined spaces or fire conditions; chemical-resistant gloves and suit

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Isolation & Evacuation

ERG 128: isolate spill 50m all directions; for large spill isolate 150m; if tank/rail car involved in fire isolate 800m
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 128).

First Actions for a UN 2297 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers, basements and low areas.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, dust generation, water reaction or unknown product identity.
  • Use ERG Guide 128, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2297 — Methylcyclohexanone
HAZMAT RADIO NOTE — UN 2297 Product: Methylcyclohexanone Class 3 / Flammable / ERG 128 PPE: Level B minimum; SCBA required in confined spaces or fire conditions; chemical-resistant gloves and suit ISOLATION: ERG 128: isolate spill 50m all directions; for large spill isolate 150m; if tank/rail car involved in fire isolate 800m ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2297 — Methylcyclohexanone Class: 3 | Placard: Flammable | ERG Guide: 128 Appearance: Colorless to pale yellow liquid with a mild, ketone-like odor. Oily consistency at room temperature. Water Reactivity: No significant reaction; slight solubility in water Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff. PPE: Level B minimum; SCBA required in confined spaces or fire conditions; chemical-resistant gloves and suit Isolation: ERG 128: isolate spill 50m all directions; for large spill isolate 150m; if tank/rail car involved in fire isolate 800m — Key Hazards — • FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources and flash back. • Vapor explosion hazard exists in low areas, drains, sewers and confined spaces. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/methylcyclohexanone-un-2297 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2297 Methylcyclohexanone Cls3 ERG128 | allfirefighter.com/hazmat/un/methylcyclohexanone-un-2297SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/methylcyclohexanone-un-2297

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2297

UN 2297 is Methylcyclohexanone, a hazardous material assigned to ERG Guide 128.

Yes. It is a flammable liquid and vapors may form explosive mixtures with air.

ERG Guide 128 applies to UN 2297 for initial isolation, protective actions and first response guidance.

FLAMMABLE liquid; vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back. Vapor explosion hazard exists in low areas, drains, sewers and confined spaces.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Heavy flammable vapors can travel through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.