☣️ UN 2059 • CLASS 3

UN 2059 — Nitrocellulose solution, flammable

Placard: Flammable. ERG Guide 127. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2059 is Nitrocellulose solution, flammable, a highly flammable nitrocellulose-in-solvent solution assigned to ERG Guide 127. Drying residue and solvent vapors can create severe fire hazards.

Hazard overview: HIGHLY FLAMMABLE solvent solution containing nitrocellulose; vapors may ignite easily. Vapors can form explosive mixtures with air and flash back to ignition sources. Nitrocellulose residue can burn rapidly if solvent evaporates or solution dries.

Response guidance: For a UN 2059 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 127. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2059 should emphasize flammable vapor travel, sewer flashback, peroxide/drying hazards where applicable, foam selection, container cooling and runoff control. Use ERG 127, SDS and local SOP.

Regulatory context: Nitrocellulose solution, flammable is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Nitrocellulose solution, flammable should be stored in approved flammable-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

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UN 2059 Quick Details

UN 2059
Product name: Nitrocellulose solution, flammable
DOT Class: 3
Placard type: Flammable
ERG Guide: 127 (check current ERG)
Initial isolation: ERG 127: isolate spill area minimum 50m all directions; for large spills isolate 800m downwind; evacuate immediate area if fire involves bulk containers

Common Hazards of UN 2059

  • HIGHLY FLAMMABLE solvent solution containing nitrocellulose; vapors may ignite easily.
  • Vapors can form explosive mixtures with air and flash back to ignition sources.
  • Nitrocellulose residue can burn rapidly if solvent evaporates or solution dries.
  • Containers may rupture or explode when heated.
  • Runoff to sewers may create fire or explosion hazards.
  • Fire may produce nitrogen oxides, carbon monoxide and dense irritating smoke.
  • Drying, contamination or heat may increase fire intensity.

Chemical Identity & Physical Properties

Clear to pale yellow viscous liquid with a characteristic ether-like or solvent odor. The solution contains nitrocellulose dissolved in flammable organic solvents such as alcohols, esters, or ketones.

Also known asCollodionCellulose nitrate solutionNitrocellulose in solventPyroxylin solutionGun cotton solution
AppearanceClear to pale yellow viscous liquid with a characteristic ether-like or solvent odor. The solution contains nitrocellulose dissolved in flammable organic solvents such as alcohols, esters, or ketones.
Flash Point-18C to 13C (0F to 55F) depending on solvent composition
Boiling Point35C to 82C (95F to 180F) depending on solvent mixture
Vapor Density2-3 (heavier than air, varies with solvent)
Water ReactivityNo significant reaction with water, but insoluble and will separate as a layer
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2059

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff.

PPE Requirements

⚠️ Level B minimum with SCBA required; butyl rubber or nitrile gloves; fire-resistant suit for fire conditions; explosive potential requires safe distance

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Isolation & Evacuation

ERG 127: isolate spill area minimum 50m all directions; for large spills isolate 800m downwind; evacuate immediate area if fire involves bulk containers
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 127).

First Actions for a UN 2059 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers, basements and low areas.
  • Do not touch damaged containers or spilled/released material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, gas accumulation, cylinder heating or unknown product identity.
  • Use ERG Guide 127, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2059 — Nitrocellulose solution, flammable
HAZMAT RADIO NOTE — UN 2059 Product: Nitrocellulose solution, flammable Class 3 / Flammable / ERG 127 PPE: Level B minimum with SCBA required; butyl rubber or nitrile gloves; fire-resistant suit for fire conditions; explosive potential requires safe distance ISOLATION: ERG 127: isolate spill area minimum 50m all directions; for large spills isolate 800m downwind; evacuate immediate area if fire involves bulk containers ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2059 — Nitrocellulose solution, flammable Class: 3 | Placard: Flammable | ERG Guide: 127 Appearance: Clear to pale yellow viscous liquid with a characteristic ether-like or solvent odor. The solution contains nitrocellulose dissolved in flammable organic solvents such as alcohols, esters, or ketones. Water Reactivity: No significant reaction with water, but insoluble and will separate as a layer Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff. PPE: Level B minimum with SCBA required; butyl rubber or nitrile gloves; fire-resistant suit for fire conditions; explosive potential requires safe distance Isolation: ERG 127: isolate spill area minimum 50m all directions; for large spills isolate 800m downwind; evacuate immediate area if fire involves bulk containers — Key Hazards — • HIGHLY FLAMMABLE solvent solution containing nitrocellulose; vapors may ignite easily. • Vapors can form explosive mixtures with air and flash back to ignition sources. • Nitrocellulose residue can burn rapidly if solvent evaporates or solution dries. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, gas, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/nitrocellulose-solution-flammable-un-2059 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2059 Nitrocellulose solution, flammable Cls3 ERG127 | allfirefighter.com/hazmat/un/nitrocellulose-solution-flammable-un-2059SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/nitrocellulose-solution-flammable-un-2059

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2059

UN 2059 is Nitrocellulose solution, flammable, a hazardous material assigned to ERG Guide 127.

Yes. It is highly flammable; dried nitrocellulose residue can burn rapidly.

ERG Guide 127 applies to UN 2059 for initial isolation, protective actions and first response guidance.

HIGHLY FLAMMABLE solvent solution containing nitrocellulose; vapors may ignite easily. Vapors can form explosive mixtures with air and flash back to ignition sources. Nitrocellulose residue can burn rapidly if solvent evaporates or solution dries.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Heavy flammable vapors can travel through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.