☣️ UN 2310 • CLASS 3

UN 2310 — Pentane-2,4-dione

Placard: Flammable. ERG Guide 131. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.

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⚠️ This page is a quick-reference aid. For real incidents: stage upwind, isolate, deny entry, request Hazmat early, and consult the current ERG + SOP/SOG.

UN 2310 is Pentane-2,4-dione, a toxic flammable beta-diketone liquid assigned to ERG Guide 131. It combines vapor fire risk with toxic skin/eye exposure.

Hazard overview: TOXIC and FLAMMABLE beta-diketone liquid; inhalation, ingestion or skin contact may cause injury. Vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back.

Response guidance: For a UN 2310 incident, verify the product with shipping papers, container markings, SDS and ERG Guide 131. Establish incident command, isolate the area, stay upwind, control ignition or incompatibility hazards, prevent runoff, dust or vapor spread and base entry/fire-control actions on monitoring and local SOP.

Firefighter training notes: Training for UN 2310 should emphasize vapor travel, sewer flashback, foam selection, container cooling, ignition control, toxic exposure where applicable and runoff containment. Use ERG 131, SDS and local SOP.

Regulatory context: Pentane-2,4-dione is regulated as a hazardous material for transportation and emergency response purposes. Storage, workplace exposure, emergency planning, spill reporting, waste handling and environmental requirements vary by exact product, concentration, quantity and jurisdiction. Verify current requirements through shipping papers, SDS, container markings and applicable DOT, OSHA, EPA, NFPA, state or local authority guidance.

Storage & handling: Pentane-2,4-dione should be stored in approved flammable/toxic-liquid containers with ventilation, bonding/grounding where required, spill containment and separation from heat, ignition sources, oxidizers and incompatible materials.

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UN 2310 Quick Details

UN 2310
Product name: Pentane-2,4-dione
DOT Class: 3
Placard type: Flammable
ERG Guide: 131 (check current ERG)
Initial isolation: ERG 131: Isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate

Common Hazards of UN 2310

  • TOXIC and FLAMMABLE beta-diketone liquid; inhalation, ingestion or skin contact may cause injury.
  • Vapors may ignite and form explosive mixtures with air.
  • Vapors are heavier than air and may travel to ignition sources and flash back.
  • Skin and eye contact can irritate or burn tissue; contaminated clothing can extend exposure.
  • Runoff to sewers may create fire, explosion and toxic contamination hazards.
  • Fire may produce irritating and/or toxic gases.
  • Containers may rupture or explode when heated.

Chemical Identity & Physical Properties

Clear to pale yellow liquid with a pleasant, sweet odor. Highly volatile at room temperature.

Also known asAcetylacetone2,4-PentanedioneDiacetylmethaneAcetoacetone
CAS Number123-54-6
AppearanceClear to pale yellow liquid with a pleasant, sweet odor. Highly volatile at room temperature.
Flash Point34°C (93°F)
Boiling Point138°C (280°F)
Vapor Density3.5 (heavier than air)
Water ReactivitySoluble in water; no violent reaction but may hydrolyze slowly in water
Chemical details are general reference only. Always verify with current SDS, ERG, and SOP/SOG.

Fireground Response Guidance — UN 2310

Extinguishing Media

Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff.

PPE Requirements

⚠️ Level B minimum; SCBA required in confined spaces or high concentrations; chemical-resistant gloves and suit due to skin absorption hazard

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Isolation & Evacuation

ERG 131: Isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate
Always confirm protective actions with the current edition of the Emergency Response Guidebook (ERG Guide 131).

First Actions for a UN 2310 Incident

  • CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
  • Keep unauthorized personnel away.
  • Stay upwind, uphill and/or upstream.
  • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact.
  • Eliminate ignition sources if safe and keep vapors and runoff out of drains, sewers, basements and low areas.
  • Do not touch damaged containers or spilled material unless properly trained and wearing appropriate protective equipment.
  • Ventilate closed spaces before entering, but only if properly trained, equipped, monitored and authorized by incident command.
  • Isolate the spill or release area and expand the perimeter for fire involvement, vapor spread, dust generation, water reaction or unknown product identity.
  • Use ERG Guide 131, shipping papers, SDS, air monitoring and incident command for protective actions.
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📋 Copy & Share Field Card

UN 2310 — Pentane-2,4-dione
HAZMAT RADIO NOTE — UN 2310 Product: Pentane-2,4-dione Class 3 / Flammable / ERG 131 PPE: Level B minimum; SCBA required in confined spaces or high concentrations; chemical-resistant gloves and suit due to skin absorption hazard ISOLATION: ERG 131: Isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate ACTION: Stage upwind · Isolate · Deny entry · Request HazmatRADIO

Use for: Quick radio or face-to-face size-up. Short, structured, field-ready.

SMS WhatsApp
=== IC HAZMAT BRIEFING === UN 2310 — Pentane-2,4-dione Class: 3 | Placard: Flammable | ERG Guide: 131 Appearance: Clear to pale yellow liquid with a pleasant, sweet odor. Highly volatile at room temperature. Water Reactivity: Soluble in water; no violent reaction but may hydrolyze slowly in water Extinguishing: Use alcohol-resistant foam or AFFF where suitable, dry chemical or CO2. Water spray may cool containers from a protected position, but direct streams may spread burning liquid or contaminated runoff. PPE: Level B minimum; SCBA required in confined spaces or high concentrations; chemical-resistant gloves and suit due to skin absorption hazard Isolation: ERG 131: Isolate spill/leak area immediately for at least 50m in all directions; if tank/rail car involved in fire, isolate 800m in all directions and evacuate — Key Hazards — • TOXIC and FLAMMABLE beta-diketone liquid; inhalation, ingestion or skin contact may cause injury. • Vapors may ignite and form explosive mixtures with air. • Vapors are heavier than air and may travel to ignition sources and flash back. — First Actions — • CALL 911. Then call the emergency response telephone number on the shipping paper, if available. • Keep unauthorized personnel away. • Stay upwind, uphill and/or upstream. • Avoid breathing vapors, dust, mist, smoke or fumes and avoid skin or eye contact. SOURCE: allfirefighter.com/hazmat/un/pentane-2-4-dione-un-2310 | Always use current ERG + SOP/SOGIC BRIEFING

Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.

SMS (short)
UN2310 Pentane-2,4-dione Cls3 ERG131 | allfirefighter.com/hazmat/un/pentane-2-4-dione-un-2310SMS / 160 CHAR

Use for: Quick text to command or incoming units. Fits in a single SMS.

⚠️ Quick-reference only. Always use current ERG + SOP/SOG for incident-specific actions. Page: https://allfirefighter.com/hazmat/un/pentane-2-4-dione-un-2310

Related UN Numbers in Class 3

Discovery block for training / quick reference. Always consult the current ERG + your SOP/SOG for operations.
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Frequently Asked Questions about UN 2310

UN 2310 is Pentane-2,4-dione, a hazardous material assigned to ERG Guide 131.

Yes. It is flammable and toxic; vapors may form explosive mixtures with air.

ERG Guide 131 applies to UN 2310 for initial isolation, protective actions and first response guidance.

TOXIC and FLAMMABLE beta-diketone liquid; inhalation, ingestion or skin contact may cause injury. Vapors may ignite and form explosive mixtures with air. Vapors are heavier than air and may travel to ignition sources and flash back.

Use positive-pressure SCBA for vapor, fire or confined-space exposure. Wear chemical-resistant gloves, eye/face protection, flame-resistant protection as appropriate and PPE selected from SDS.

Heavy flammable vapors can travel through drains or sewers and ignite remotely, causing flashback or vapor explosion.
Sources (high level): DOT/PHMSA marking & class concepts + ERG usage principles. This page does not reproduce ERG guide text—always consult the current ERG for incident-specific protective actions.