UN 3358 — Refrigerating machines, containing flammable, non-poisonous, liquefied gas
Placard: Flammable Gas. ERG Guide 115. Training/quick-reference only — use current ERG + SOP/SOG for incident-specific actions.
UN 3358 applies to refrigeration units or machinery containing flammable, non-poisonous liquefied gas refrigerants.
Hazard overview: If the sealed system leaks, flammable vapor can collect in low areas and ignite. Liquefied gas contact may cause frostbite.
Response guidance: Isolate the area, remove ignition sources, ventilate if safe and cool exposed machinery from a distance. Do not enter confined areas without SCBA.
UN 3358 Quick Details
Common Hazards of UN 3358
- EXTREMELY FLAMMABLE.
- Will be easily ignited by heat, sparks or flames.
- Will form explosive mixtures with air.
- Vapors from liquefied gas are initially heavier than air and spread along ground.
- Vapors may travel to source of ignition and flash back.
- Cylinders exposed to fire may vent and release flammable gas through pressure relief devices.
- Containers may explode when heated.
- Ruptured cylinders may rocket.
Chemical Identity & Physical Properties
Complete refrigeration units or machines containing flammable, non-toxic liquefied gases such as hydrocarbons (propane, isobutane) or ammonia refrigerants. Typically metal enclosures with compressor, condenser, and evaporator components.
| Also known as | Refrigerating machinesRefrigeration equipment containing flammable gasRefrigerant-containing appliancesCooling units with flammable refrigerant |
| Appearance | Complete refrigeration units or machines containing flammable, non-toxic liquefied gases such as hydrocarbons (propane, isobutane) or ammonia refrigerants. Typically metal enclosures with compressor, condenser, and evaporator components. |
| Flash Point | Not applicable (pressurized liquefied gas within sealed system) |
| Boiling Point | Varies by refrigerant: typically -42C to -12C (-44F to 10F) for common flammable refrigerants |
| Vapor Density | Heavier than air (most flammable refrigerants 1.5-2.0 relative to air) |
| Water Reactivity | No significant reaction with water |
Fireground Response Guidance — UN 3358
Extinguishing Media
PPE Requirements
Use SCBA for leaks or fire. Wear thermal and cold-protection gloves if liquefied refrigerant contact is possible.
Isolation & Evacuation
First Actions for a UN 3358 Incident
- CALL 911. Then call the emergency response telephone number on the shipping paper, if available.
- Keep unauthorized personnel away.
- Stay upwind, uphill and/or upstream.
- Many gases are heavier than air and may collect in low or confined areas.
- Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
- Consider initial downwind evacuation for at least 800 meters (1/2 mile).
📋 Copy & Share Field Card
UN 3358 — Refrigerating machines, containing flammUse for: Quick radio or face-to-face size-up. Short, structured, field-ready.
Use for: Incident command briefing, staging area whiteboard, or pre-entry team brief.
Use for: Quick text to command or incoming units. Fits in a single SMS.